Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites     

David T. Adamson PhD  PE  Grayson Uhlir BS  Sharon R. Rauch BA  Tessa Klein BS  Anthony S. Danko PhD  PE 《Ground Water Monitoring & Remediation》2021,41(3):29-40

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.  相似文献   

Scanning electron microscopical and cross sectional analysis of extraterrestrial carbonaceous nanoglobules     

Laurence A. J. GARVIE  Grant BAUMGARDNER  Peter R. BUSECK 《Meteoritics & planetary science》2008,43(5):899-903

Abstract— Carbonaceous nanoglobules are ubiquitous in carbonaceous chondrite (CC) meteorites. The Tagish Lake (C2) meteorite is particularly intriguing in containing an abundance of nanoglobules, with a wider range of forms and sizes than encountered in other CC meteorites. Previous studies by transmission electron microscopy (TEM) have provided a wealth of information on chemistry and structure. In this study low voltage scanning electron microscopy (SEM) was used to characterize the globule forms and external structures. The internal structure of the globules was investigated after sectioning by focused ion beam (FIB) milling. The FIB‐SEM analysis shows that the globules range from solid to hollow. Some hollow globules show a central open core, with adjoining smaller cores. The FIB with an SEM is a valuable tool for the analysis of extraterrestrial materials, even of sub‐micron‐sized “soft” carbonaceous particles. The rapid site‐specific cross‐sectioning capabilities of the FIB allow the preservation of the internal morphology of the nanoglobules, with minimal damage or alteration of the unsectioned areas.  相似文献   

Historical and Modern Fluctuations of Lakes Tanganyika and Rukwa and Their Relationship to Rainfall Variability     

Sharon E. Nicholson 《Climatic change》1999,41(1):53-71

This paper describes the fluctuations of Lakes Tanganyika and Rukwa over the last two centuries. Lake chronologies extending back to the late eighteenth century are derived from reports of European visitors, settlers and explorers and from oral accounts of the local peoples. The historical fluctuations are meshed with the modern record to provide a picture of the lakes' fluctuations until the late twentieth century. The historical fluctuations of the lakes are quite similar. The most important of these are low levels during the first half of the nineteenth century, very high stands in the last decades of the nineteenth century, and, around the turn of the century, a rapid fall to twentieth century levels. This pattern is ubiquitous throughout eastern Africa and is apparent in numerous other lakes, including Victoria, Naivasha, Stefanie, Turkana, Malawi and Chilwa. Driest periods were in the 1920s or earlier and in the 1950s. Lake Tanganyika returned to extremely high stands in the 1960s and has continued to maintain relatively high stands since that time. Lake Rukwa rose to high stands during the 1980s and maintained them for several years. An analysis of rainfall variability shows that these trends are generally explained by variations in catchment rainfall. However, the lakes' responses to rainfall variability are sometimes dissimilar because Lake Rukwa is a closed basin. Our results demonstrate the complexity of the rainfall/lake-level relationships and the need to use water balance relationships in order to interpret the lakes' historical or paleo-fluctuations in terms of rainfall.  相似文献   

Observations of polar patches generated by solar wind Alfvén wave coupling to the dayside magnetosphere     

P. Prikryl  J. W. MacDougall  I. F. Grant  D. P. Steele  G. J. Sofko  R. A. Greenwald 《Annales Geophysicae》1999,17(4):463-489

A long series of polar patches was observed by ionosondes and an all-sky imager during a disturbed period (K_p = 7- and IMF B_z <0). The ionosondes measured electron densities of up to 9 × 10¹¹ m⁻³ in the patch center, an increase above the density minimum between patches by a factor of ≈4.5. Bands of F-region irregularities generated at the equatorward edge of the patches were tracked by HF radars. The backscatter bands were swept northward and eastward across the polar cap in a fan-like formation as the afternoon convection cell expanded due to the IMF B_y > 0. Near the north magnetic pole, an all-sky imager observed the 630-nm emission patches of a distinctly band-like shape drifting northeastward to eastward. The 630-nm emission patches were associated with the density patches and backscatter bands. The patches originated in, or near, the cusp footprint where they were formed by convection bursts (flow channel events, FCEs) structuring the solar EUV-produced photoionization and the particle-produced auroral/cusp ionization by segmenting it into elongated patches. Just equatorward of the cusp footprint Pc5 field line resonances (FLRs) were observed by magnetometers, riometers and VHF/HF radars. The AC electric field associated with the FLRs resulted in a poleward-progressing zonal flow pattern and backscatter bands. The VHF radar Doppler spectra indicated the presence of steep electron density gradients which, through the gradient drift instability, can lead to the generation of the ionospheric irregularities found in patches. The FLRs and FCEs were associated with poleward-progressing DPY currents (Hall currents modulated by the IMF B_y) and riometer absorption enhancements. The temporal and spatial characteristics of the VHF backscatter and associated riometer absorptions closely resembled those of poleward moving auroral forms (PMAFs). In the solar wind, IMP 8 observed large amplitude Alfvén waves that were correlated with Pc5 pulsations observed by the ground magnetometers, riometers and radars. It is concluded that the FLRs and FCEs that produced patches were driven by solar wind Alfvén waves coupling to the dayside magnetosphere. During a period of southward IMF the dawn-dusk electric field associated with the Alfvén waves modulated the subsolar magnetic reconnection into pulses that resulted in convection flow bursts mapping to the ionospheric footprint of the cusp.  相似文献   

The Handbook of Groundwater Engineering,Third Edition          下载免费PDF全文

Grant Ferguson 《Ground water》2017,55(4):485-486

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A multicatchment analysis of headwater and downstream temperature effects from contemporary forest harvesting          下载免费PDF全文

Kevin D. Bladon  Catalina Segura  Nicholas A. Cook  Sharon Bywater‐Reyes  Maryanne Reiter 《水文研究》2018,32(2):293-304

Stream temperature is a key physical water‐quality parameter, controlling many biological, chemical, and physical processes in aquatic ecosystems. Maintenance of cool stream temperatures during summer is critical for high‐quality aquatic habitat. As such, transmission of warm water from small, nonfish‐bearing headwater streams after forest harvesting could cause warming in downstream fish‐bearing stream reaches with negative consequences. In this study, we evaluate (a) the effects of contemporary forest management practices on stream temperature in small, headwater streams, (b) the transmission of thermal signals from headwater reaches after harvesting to downstream fish‐bearing reaches, and (c) the relative role of lithology and forest management practices in influencing differential thermal responses in both the headwater and downstream reaches. We measured summer stream temperatures both preharvest and postharvest at 29 sites—12 upstream sites (4 reference, 8 harvested) and 17 downstream sites (5 reference, 12 harvested)—across 3 paired watershed studies in western Oregon. The 7‐day moving average of daily maximum stream temperature (T_7DAYMAX) was greater during the postharvest period relative to the preharvest period at 7 of the 8 harvested upstream sites. Although the T_7DAYMAX was generally warmer in the downstream direction at most of the stream reaches during both the preharvest and postharvest period, there was no evidence for additional downstream warming related to the harvesting activity. Rather, the T_7DAYMAX cooled rapidly as stream water flowed into forested reaches ~370–1,420 m downstream of harvested areas. Finally, the magnitude of effects of contemporary forest management practices on stream temperature increased with the proportion of catchment underlain by more resistant lithology at both the headwater and downstream sites, reducing the potential for the cooling influence of groundwater.  相似文献   

Conventional Oil—The Forgotten Part of the Water-Energy Nexus     

Jennifer C. McIntosh  Grant Ferguson 《Ground water》2019,57(5):669-677

The impacts of unconventional oil and gas production via high-volume hydraulic fracturing (HVHF) on water resources, such as water use, groundwater and surface water contamination, and disposal of produced waters, have received a great deal of attention over the past decade. Conventional oil and gas production (e.g., enhanced oil recovery [EOR]), which has been occurring for more than a century in some areas of North America, shares the same environmental concerns, but has received comparatively little attention. Here, we compare the amount of produced water versus saltwater disposal (SWD) and injection for EOR in several prolific hydrocarbon producing regions in the United States and Canada. The total volume of saline and fresh to brackish water injected into depleted oil fields and nonproductive formations is greater than the total volume of produced waters in most regions. The addition of fresh to brackish “makeup” water for EOR may account for the net gain of subsurface water. The total amount of water injected and produced for conventional oil and gas production is greater than that associated with HVHF and unconventional oil and gas production by well over a factor of 10. Reservoir pressure increases from EOR and SWD wells are low compared to injection of fluids for HVHF, however, the longer duration of injections could allow for greater solute transport distances and potential for contamination. Attention should be refocused from the subsurface environmental impacts of HVHF to the oil and gas industry as a whole.  相似文献   

Population structure of the sicklefin lemon shark Negaprion acutidens within the Curieuse Marine National Park,Seychelles     

RD Hodgkiss  A Grant  JHR McClelland  R Quatre  B Rademakers  C Sanchez 《African Journal of Marine Science》2017,39(2):225-232

This study produced the first data on population parameters for sicklefin lemon shark Negaprion acutidens at the granitic Seychelles Islands, adding to a limited catalogue of species information. Juveniles at a site in the Curieuse Marine National Park were tagged over two periods, in 2014–2015 and 2015–2016, with measurements of length (precaudal, fork and total) and weight, sex, and state of the umbilical opening recorded. Recapture data were used to calculate growth rates and population size. Mean annual growth rate was 5.40 cm y^–1. A mean size at birth of 62.5 cm TL is in line with previous assessments of the species. Population-size estimates were similar for the two sampling periods (comprising 311 and 255 individuals) and higher than anticipated. Movements to outside the lagoon were recorded for early ages, and this, combined with weight loss and a reduction in condition factor as displayed in several individuals, suggests that the study area alone could not support the large number of sharks pupped yearly.  相似文献   

Improved performance‐based seismic assessment of buildings by utilizing Bayesian statistics          下载免费PDF全文

Omid Esmaili  Lisa Grant Ludwig  Farzin Zareian 《地震工程与结构动力学》2016,45(4):581-597

This paper addresses two important issues of concern to practicing engineers and researchers alike in application of performance‐based seismic assessment (PBSA) methodology on buildings: (i) the number of ground motion records required to exercise PBSA—current practice (FEMA P‐58‐1) requires eleven or more pairs of motions for this purpose, and (ii) the time and effort associated with performing the number of nonlinear response history analyses required to exercise PBSA. We present a method for exercising of PBSA that employs classical linear modal analysis to develop a first estimate (i.e., a priori) of probability distribution of loss, followed by utilizing Bayesian statistics to update this estimate using estimates of loss obtained by utilizing a small number of nonlinear response history analyses of a detailed model of the building (i.e., posterior). The proposed technique is used to assess the distribution of monetary loss of two case studies, a 4‐story reinforced concrete moment‐resisting frame building and a 20‐story steel moment‐resisting frame building, both located in Los Angeles, for a ground motion hazard with 10% probability of exceedance in 50 years. The efficiency of the proposed PBSA method is demonstrated by showing the similarity between the distribution of monetary loss at each story of case study buildings obtained from the traditional/sophisticated PBSA methodology and the proposed PBSA method in this study. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Using meteorological observer data to compare wind erosion during two great droughts in eastern Australia; the World War II Drought (1937–1946) and the Millennium Drought (2001–2010)          下载免费PDF全文

Tadhg O'Loingsigh  Grant H. McTainsh  Katherine Parsons  Craig L. Strong  Phil Shinkfield  Nigel J. Tapper 《地球表面变化过程与地形》2015,40(1):123-130

Australian meteorological observers started using the World Meteorological Organization (WMO) weather coding system in the 1950s. This system is still in use around the world today. However, observing and recording the weather in an organized and systematic manner had been ongoing for over 100 years prior to the adoption of this coding system, and much like Australia, most countries will have historical meteorological records. In this paper we compare the wind erosion of two of the greatest droughts in Australian recorded history; the World War II (WWII) Drought (1937–1945) and the Millennium Drought (2001–2009). To do this we analysed previously unavailable meteorological observer records from the Australian Bureau of Meteorology (ABM). Wind erosion records, mostly in long‐hand written form, were translated to the modern WMO coding system for the WWII Drought and compared with the wind erosion of Australia's recently‐ended Millennium Drought, one of the longest and harshest on record. We quantify wind erosion using Dust Event Days (DED) and a modified version of a published Dust Storm Index (DSI) to show that wind erosion during the WWII Drought was up to 4.6 times higher than during the Millennium Drought. This study has international significance because it demonstrates a methodology for tracking changes in wind erosion over the past 75 years based on observer records available in every country with a history of organized weather observation. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献