Correction to: Formation by silicate–fluoride + phosphate melt immiscibility of REE-rich globular segregations within aplite dikes     

Charles?R.?SternEmail author  Julien?M.?Allaz  Markus?B.?Raschke  G.?Lang?Farmer  M.?Alexandra?Skewes  Jeremy?T.?Ross 《Contributions to Mineralogy and Petrology》2018,173(10):79

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The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations     

Artur?BenisekEmail authorView author&#;s OrcID profile  Edgar?Dachs 《Contributions to Mineralogy and Petrology》2018,173(11):90

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.  相似文献   

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland          下载免费PDF全文

Yong Chen  Jing Duan  Junling An  Huizhi Liu  Ulrich G?rsdorf  Franz H.Berger 《大气和海洋科学快报》2021,14(5):24-29

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.  相似文献   

Carbon costs and benefits of France’s biomass energy production targets     

Aude?ValadeEmail authorView author&#;s OrcID profile  Sebastiaan?Luyssaert  Patrick?Vallet  Sylvestre?Njakou Djomo  Ingride?Jesus Van Der Kellen  Valentin?Bellassen 《Carbon balance and management》2018,13(1):26

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Erratum to: The analysis of 2004 flood on Kozdere Stream in Istanbul     

Hüseyin E. ?elik  Gonca Coskun  H. Kerem Cigizoglu  Necati A??ralio?lu  Abdurrahim Ayd?n  A. ?lker Esin 《Natural Hazards》2012,63(2):1279-1279

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GIS-based assessment of landslide susceptibility on the base of the Weights-of-Evidence model   总被引：4，自引：2，他引：2  

Bettina Neuh?user  Bodo Damm  Birgit Terhorst 《Landslides》2012,9(4):511-528

The major scope of the study is the assessment of landslide susceptibility of Flysch areas including the Penninic Klippen in the Vienna Forest (Lower Austria) by means of Geographical Information System (GIS)-based modelling. A statistical/probabilistic method, referred to as Weights-of-Evidence (WofE), is applied in a GIS environment in order to derive quantitative spatial information on the predisposition to landslides. While previous research in this area concentrated on local geomorphological, pedological and slope stability analyses, the present study is carried out at a regional level. The results of the modelling emphasise the relevance of clay shale zones within the Flysch formations for the occurrence of landslides. Moreover, the distribution of mass movements is closely connected to the fault system and nappe boundaries. An increased frequency of landslides is observed in the proximity to drainage lines, which can change to torrential conditions after heavy rainfall. Furthermore, landslide susceptibility is enhanced on N-W facing slopes, which are exposed to the prevailing direction of wind and rainfall. Both of the latter geofactors indirectly show the major importance of the hydrological conditions, in particular, of precipitation and surface runoff, for the occurrence of mass movements in the study area. Model performance was checked with an independent validation set of landslides, which are not used in the model. An area of 15% of the susceptibility map, classified as highly susceptible, “predicted” 40% of the landslides.  相似文献   

Pressure and temperature dependence of cation distribution in Mg-Mn olivine     

Tadashi Akamatsu  Kiyoshi Fujino  Mineo Kumazawa  Akio Fujimura  Manabu Kato  Hiroshi Sawamoto  Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113

Synthetic (Mg_0.51, Mn_0.49)₂SiO₄ olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (～500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K _D = (Mn/Mg) _M1/(Mn/Mg) _M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction.  相似文献   

High time resolution monitoring of tropospheric temperature with a Radio Acoustic Sounding System (RASS)     

T. Tsuda  Y. Masuda  H. Inuki  K. Takahashi  T. Takami  T. Sato  S. Fukao  S. Kato 《Pure and Applied Geophysics》1989,130(2-3):497-507

We have observed the time-height variation of the temperature field in the upper troposphere using a Radio Acoustic Sounding System (RASS) which consists of the MU radar and a high-power acoustic transmitter. The fast beam steerability of the MU radar has made it possible to measure temperature profiles in a fairly wide height range in the upper troposphere (5–11 km), even under intense wind conditions. Observations were continued for about 32 hr on 24–26 December, 1986 with a time-height resolution of 30 min and 150 m. During the observation period, the tropospheric jet was so intense that the acoustic wavefronts were severely distorted. Using wind velocity profiles observed by the MU radar we have numerically estimated the propagation of acoustic wavefronts, and further determined favorable pointing directions for the MU radar to receive significant backscattering from refractive index fluctuations produced by the acoustic waves. Conventional radiosonde soundings were carried out every 6 hr, which showed a temperature decrease of 4 K/day in the upper troposphere during the observation period. Temperature profiles taken by RASS agree well with the radiosonde results.  相似文献   

Melting relationships in the system Fe-Feo at high pressures: Implications for the composition and formation of the earth's core     

Takumi Kato  A. E. Ringwood 《Physics and Chemistry of Minerals》1989,16(6):524-538

A reconnaissance investigation has been carried out on melting relationships in the system Fe-FeO at pressures up to 25 GPa and temperatures up to 2200° C using an MA-8 apparatus. Limited studies were also made of the Co-CoO and Ni-NiO systems. In the system FeFeO, the rapid exsolution of FeO from liquids during quenching causes some difficulties in interpretation of textures and phase relationships. The Co-CoO and Ni-NiO systems are more tractable experimentally and provide useful analogues to the Fe-FeO system. It was found that the broad field of liquid immiscibility present at ambient pressure in the Co-CoO system had disappeared at 18 GPa, 2200° C and that the system displayed complete miscibility between molten Co and CoO, analogous to the behaviour of the Ni-NiO system at ambient pressure. The phase diagram of the system Fe-FeO at 16 GPa and from 1600–2200° C was constructed from interpretations based on the textures of quenched run products. The solubility of FeO in molten iron is considerably enhanced by high pressures. At 16 GPa, the Fe-FeO eutectic contains about 10–15 mol percent FeO and the eutectic temperature in this iron-rich region of the system occurs at 1700±25° C, some 350° C below the melting point of pure iron at the same pressure. The solubility of FeO in molten Fe increases rapidly as temperature increases from 1700 to 2200° C. A relatively small liquid immiscibility field is present above 1900° C but is believed to be eliminated above 2200° C. This inference is supported by thermodynamic calculations on the positions of key phase boundaries. A single run carried out on an Fe₅₀ FeO₅₀ composition at 25 GPa and 2200° C demonstrated extensive and probably complete miscibility between Fe and FeO liquids under these conditions. The melting point of iron is decreased considerably by solution of FeO at high pressures; moreover, the melting point gradient (dP/dT) of the Fe-FeO eutectic is much smaller than that of pure iron and is also smaller than that of mantle pyrolite under the P, T conditions studied. These characteristics make it possible for melting of metal phase and segregation of the core to proceed within the Earth under conditions where most of the mantle remains below solidus temperatures. Under these conditions, the core would inevitably contain a large proportion of dissolved FeO. It is concluded therefore, that oxygen is likely to be the principal light element in the core. The inner core may not be composed of pure iron, as often proposed. Instead, it may consist of a crystalline oxide solid solution (Ni, Fe)₂O.  相似文献   

Reports     

E. Thorsen  K. Segadal  L. E. B. Stuhr  K. Troland  M. Gr?nning  et al. 《GeoJournal》1990,20(2):176-180

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