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331.
The mineralogy and mineral chemistry of Itokawa dust particles captured during the first and second touchdowns on the MUSES‐C Regio were characterized by synchrotron‐radiation X‐ray diffraction and field‐emission electron microprobe analysis. Olivine and low‐ and high‐Ca pyroxene, plagioclase, and merrillite compositions of the first‐touchdown particles are similar to those of the second‐touchdown particles. The two touchdown sites are separated by approximately 100 meters and therefore the similarity suggests that MUSES‐C Regio is covered with dust particles of uniform mineral chemistry of LL chondrites. Quantitative compositional properties of 48 dust particles, including both first‐ and second‐touchdown samples, indicate that dust particles of MUSES‐C Regio have experienced prolonged thermal metamorphism, but they are not fully equilibrated in terms of chemical composition. This suggests that MUSES‐C particles were heated in a single asteroid at different temperatures. During slow cooling from a peak temperature of approximately 800 °C, chemical compositions of plagioclase and K‐feldspar seem to have been modified: Ab and Or contents changed during cooling, but An did not. This compositional modification is reproduced by a numerical simulation that modeled the cooling process of a 50 km sized Itokawa parent asteroid. After cooling, some particles have been heavily impacted and heated, which resulted in heterogeneous distributions of Na and K within plagioclase crystals. Impact‐induced chemical modification of plagioclase was verified by a comparison to a shock vein in the Kilabo LL6 ordinary chondrite where Na‐K distributions of plagioclase have been disturbed.  相似文献   
332.
Sea ice formation in Quilty Bay, East Antarctica shows a strong relationship with climatic conditions and its spatial variation is established by GPR survey over the sea ice during the austral winters. The study also evaluates the variability of sea ice thickness and extent with local weather parameters between 2010 and 2014. Profiling on sea ice in Quilty Bay shows that sea ice thickness decreases gradually towards east. The overall thickness of sea ice is considerably less at the centre of the bay as compared to the coastal side. Two types of fast ice layers have been delineated from GPR surveys i.e. top layer fast ice which incorporates very low density surface snow and underlying high density fast ice i.e. with melt water pockets. Development of sea ice is influenced by persistent easterly winds, temperature fluctuations and ocean currents. Sea ice reveal average annual cyclic trend in Quilty Bay with maximum development in the year 2013 (157.54 cm) and the minimum development has been observed in the year 2010 (99.04 cm).The cyclic pattern of average sea ice accumulation data show perfect inverse correlation with surface air temperature, with measure of reliability R2 = 0.93. However, moderate (R2 = 0.52) and good (R2 = 0.69) degree of inverse relationship is observed with surface snow and overall sea ice (snow and ice) respectively. With 0.46 °C change in temperature, there is 33% change in sea ice condition in Quilty Bay which may remain same as far as ice extents in the region. Besides this easterly winds play a vital role in controlling the snow/ice distribution patterns as reflected by isopach maps.  相似文献   
333.
Whale carcasses (whale falls) deposited on the deep seafloor are associated with a distinctive biotic community. A fossil whale bone recovered from São Paulo Ridge, South Atlantic Ocean, during cruise YK13–04 Leg 1 of R/V Yokosuka was covered by a ferromanganese (Fe–Mn) crust approximately 9 mm thick. Here, we report an age constraint for this fossil bone on the basis of Os isotopic stratigraphy (187Os/188Os ratio) of the Fe–Mn crust. Major‐ and trace‐element compositions of the crust are similar to those of Fe–Mn crusts of predominantly hydrogenous origin. Rare earth element concentrations in samples of the crust, normalized with respect to Post‐Archean average Australian Shale, exhibit flat patterns with positive Ce and negative Y anomalies. These results indicate that the Fe–Mn crust consists predominantly of hydrogenous components and that it preserves the Os isotope composition of seawater at the time of its deposition. 187Os/188Os ratios of three Fe–Mn crust samples increased from 0.904 to 1.068 in ascending stratigraphic order. The value of 1.068 from the surface slice (0–3 mm depth in the crust) was identical to that of present‐day seawater within error (~1.06). The value of 0.904 from the basal slice (6–9 mm) equaled seawater values from ca. 4–5 Ma. Because it is unknown how long the bone lay on the seafloor before the Fe–Mn crust was deposited, the Os stratigraphic age of ca. 5 Ma is a minimum age of the fossil. This is the first application, to our knowledge, of marine Os isotope stratigraphy for determining the age of a fossil whale bone. Such data may offer valuable insights into the evolution of the whale‐fall biotic community.  相似文献   
334.
The high-pressure and temperature equation of state of majorite solid solution, Mj0.8Py0.2, was determined up to 23 GPa and 773 K with energy-dispersive synchrotron X-ray diffraction at high pressure and high temperature using the single- and double-stage configurations of the multianvil apparatuses, MAX80 and 90. The X-ray diffraction data of the majorite sample were analyzed using the WPPD (whole-powder-pattern decomposition) method to obtain the lattice parameters. A least-squares fitting using the third-order Birch-Murnaghan equation of state yields the isothermal bulk modulus, K T0  = 156 GPa, its pressure derivative, K′ = 4.4(±0.3), and temperature derivative (∂K T /∂T) P = −1.9(±0.3)× 10−2 GPa/K, assuming that the thermal expansion coefficient is similar to that of pyrope-almandine solid solution. Received: 5 October 1998 / Revised, accepted: 24 June 1999  相似文献   
335.
Abstract: Systematic data of rare earth elements (REEs) are presented in order to put some constraints on the origin of hydrothermal fluids responsible for two contrastive skarn deposits in Japan; the Kamioka Zn-Pb and Yoshiwara-Sannotake Cu(-Fe) deposits. Carbon and oxygen isotopic studies have demonstrated that the hydrothermal fluids responsible for the Kamioka Zn-Pb deposits are of meteoric water origin whereas those for the Yoshiwara-Sannotake Cu(-Fe) deposits are of magmatic water origin. The REE abundances of epidote skarn derived from aluminous rocks, garnet and clinopyroxene in calcic exoskarn derived from limestone, and interstitial calcite associated with sulfide minerals were determined for these contrastive skarn deposits by inductively-coupled plasma mass spectrometry (ICP-MS). A significant difference in the REE concentrations is not found between epidote skarn and aluminous original rock (plagioclase-clinopyroxene rock, called Inishi rock) from the Kamioka Zn-Pb deposits, indicating that the REEs are generally immobile during the formation of epidote skarn, and that the REE concentrations of the hydrothermal fluid are considerably low relative to the aluminous original rock. In contrast, the epidote skarn exhibits enrichment of Eu with increasing total REE concentrations relative to the aluminous original rock (quartz diorite) in the Yoshiwara-Sannotake Cu(-Fe) deposits, implying a contribution of magmatic fluid derived from granitoids during the skarn formation. Limestone generally has much lower REE concentrations related to surrounding aluminous rocks, and thus the REE concentrations of garnet and clinopyroxene in calcic exoskarn, originated from limestone, are variable due to the interaction with the hydrothermal fluids. The chondrite-normalized REE patterns of garnet, clinopyroxene, and interstitial calcite exactly provide useful information on origins of hydrothermal fluids. The REE patterns of these minerals from the Kamioka Zn-Pb deposits show lower (Pr/Yb)cn ratios, and negative Ce and Eu anomalies inherited from limestone with the decrease of This suggests that the hydrothermal fluids responsible for the Kamioka Zn-Pb deposits were depleted in REEs, and were not magmatic water in origin, but presumably meteoric one. In striking contrast, the REE patterns of exoskarn minerals and calcite from the Yoshiwara-Sannotake Cu(-Fe) deposits exhibit a positive Eu anomaly, and high (Pr/Yb)cn ratios with the considerable increase of σREE and the disappearance of negative Ce anomaly, implying that the fluids were dominantly of magmatic origin. The REE indices are very likely to be an excellent indicator to origins of the skarn deposits.  相似文献   
336.
Analytical data for five GSJ (Geological Survey of Japan) reference samples, the "Instrumental analysis series" received by October 1998, are compiled. The data reported in publications and personal communications were evaluated statistically, taking into account the analytical method and sample preparation. Based on the selected available data, recommended and preferred values for fourteen major and fifty one minor and trace elements are proposed.  相似文献   
337.
338.
Reponses of structures subjected to severe earthquakes sometimes significantly surpass what was considered in the design. It is important to investigate the failure mechanism and collapse margin of structures beyond design, especially for high-rise buildings. In this study, steel high-rise buildings using either square concrete-filled-tube (CFT) columns or steel tube columns are designed. A detailed three-dimensional (3D) structural model is developed to analyze the seismic behavior of a steel high-rise towards a complete collapse. The effectiveness is verified by both component tests and a full-scale shaking table test. The collapse margin, which is defined as the ratio of PGA between the collapse level to the design major earthquake level (Level 2), is quantified by a series of numerical simulations using incremental dynamic analyses (IDA). The baseline building using CFT columns collapsed with a weak first story mechanism and presented a collapse margin ranging from 10 to 20. The significant variation in the collapse margin was caused by the different characteristics of the input ground motions. The building using equivalent steel columns collapsed earlier due to the significant shortening of the locally buckled columns, exhibiting only 57% of the collapse margin of the baseline building. The influence of reducing the height of the first story was quite significant. The shortened first story not only enlarged the collapse margin by 20%, but also changed the collapse mode.  相似文献   
339.
Igneous rocks are fractured during cooling from magma to form cooling joints, which are typically columnar joints in volcanic rocks, while orthogonal joints are considered typical for plutonic rocks. We performed a 3D study of joint systems in a granitic batholith of the Okueyama granite in western Japan, which has its roof and its internal structures from the roof to 1000 m downward exposed. We used an unmanned aerial vehicle (UAV) to observe the joints in outcrops from various angles. Based on our study, we propose a schematic model for joint systems in a granitic pluton. A granitic pluton has zones of rock columns below the roof and next to the wall. The rock column zone below the roof is as thick as 300 m, and its higher portions form steep cliffs, probably because of increased resistance to weathering. The axes of the rock columns are nearly vertical below the roof and gently plunge next to the walls, with high intersection angles with the wall. The distribution of columnar joints near only the roof and walls suggests that the granite cooled more rapidly near the roof and walls than in the core of the pluton. When the granite was jointed by parallel joints during cooling, the rock slabs between the parallel joints near the roof and the walls are subdivided into columns with polygonal cross-sections. This suggests that the granite was fractured by parallel joints at a temperature immediately below the solidus, after which the rock slabs were subdivided into rock columns during further cooling.  相似文献   
340.
Shock pressure recorded in Yamato (Y)‐790729, classified as L6 type ordinary chondrite, was evaluated based on high‐pressure polymorph assemblages and cathodoluminescence (CL) spectra of maskelynite. The host‐rock of Y‐790729 consists mainly of olivine, low‐Ca pyroxene, plagioclase, metallic Fe‐Ni, and iron‐sulfide with minor amounts of phosphate and chromite. A shock‐melt vein was observed in the hostrock. Ringwoodite, majorite, akimotoite, lingunite, tuite, and xieite occurred in and around the shock‐melt vein. The shock pressure in the shock‐melt vein is about 14–23 GPa based on the phase equilibrium diagrams of high‐pressure polymorphs. Some plagioclase portions in the host‐rock occurred as maskelynite. Sixteen different CL spectra of maskelynite portions were deconvolved using three assigned emission components (centered at 2.95, 3.26, and 3.88 eV). The intensity of emission component at 2.95 eV was selected as a calibrated barometer to estimate shock pressure, and the results indicate pressures of about 11–19 GPa. The difference in pressure between the shock‐melt vein and host‐rock might suggest heterogeneous shock conditions. Assuming an average shock pressure of 18 GPa, the impact velocity of the parent‐body of Y‐790729 is calculated to be ~1.90 km s?1. The parent‐body would be at least ~10 km in size based on the incoherent formation mechanism of ringwoodite in Y‐790729.  相似文献   
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