Thermoluminescence, electron paramagnetic resonance and optical absorption properties of rhodonite, a natural silicate mineral,
have been investigated and compared to those of synthetic crystal, pure and doped. The TL peaks grow linearly for radiation
dose up to 4 kGy, and then saturate. In all the synthetic samples, 140 and 340°C TL peaks are observed; the difference occurs
in their relative intensities, but only 340°C peak grows strongly for high doses. Al2O3 and Al2O3 + CaO-doped synthetic samples presented several decades intenser TL compared to that of synthetic samples doped with other
impurities. A heating rate of 4°C/s has been used in all the TL readings. The EPR spectrum of natural rhodonite mineral has
only one huge signal around g = 2.0 with width extending from 1,000 to 6,000 G. This is due to Mn dipolar interaction, a fact proved by numerical calculation
based on Van Vleck dipolar broadening expression. The optical absorption spectrum is rich in absorption bands in near-UV,
visible and near-IR intervals. Several bands in the region from 540 to 340 nm are interpreted as being due to Mn3+ in distorted octahedral environment. A broad and intense band around 1,040 nm is due to Fe2+. It decays under heating up to 900°C. At this temperature it is reduced by 80% of its original intensity. The pink, natural
rhodonite, heated in air starts becoming black at approximately 600°C. 相似文献
Interplanetary scintillation has observed high-latitude streams which show low speeds (400 km/s) within 0.3 AU and high speeds (700 km/s) beyond 0.3 AU. The foot points of these streams were located in the HeI coronal holes or at their boundaries. Since the IPS measurement is biased by one or several mechanisms, we investigated whether this acceleration phenomena could be caused by bias effects or not. Speed increase of more than 100 km/s is left without being explained by the bias effects. 相似文献
Major gases dissolved in seawater were accurately determined with a shipboard gas chromatographic method. The standard deviations
were 0.28, 0.34 and 0.36% for N2, O2 and Ar, respectively. The method was applied to water from the northwestern North Pacific Ocean collected in May to June
2000. We got 127 duplicate seawater samples from the surface 200 m layer at 11 stations. The O2 concentrations obtained by this method agreed with those given by the Winkler method. All the seawater samples from the surface
200 m, especially those from the upper 30 m, were supersaturated with respect to atmospheric N2 and Ar concentrations. In the topmost 30 m layer, the degrees of supersaturation in the inventory were 2.7–4.3% for N2 (ΔN2) and 1.7–2.6% for Ar (ΔAr), and their ratios, ΔN2/ΔAr, ranged from 1.53 to 1.81. This supersaturation seems to be chiefly due to air bubbles injected into the water and dissolved
due to the water pressure, because the N2/Ar ratio of the air is around 2. The amounts of air bubbles dissolved in the upper 30 m water were relatively large, with
mean value of 0.41 ml/kg or 18.4 μmol/kg. The ΔN2, ΔAr and ΔN2/ΔAr values were all positively well correlated with the wind velocities averaged for the last 24 hours prior to sampling,
allowing the conclusion to be drawn that the weaker the wind velocity, the dissolved gas composition approaches in equilibrium
with the air; while the stronger the wind velocity, it approaches in the air composition.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
Chattonella antiqua (Raphidophyceae), which causes heavy red tides in the Seto Inland Sea, Japan, was placed in axenic clonal culture by micropipette washing. The effects of temperature, salinity, light intensity and pH on growth were monitored. Maximum growth occurred at 25°C, at salinities between 25 and 41‰, under light intensities above 0.04 ly min?1. The pH effect was not significant in the pH range from 7.6 to 8.3. Comparisons of our results with those from field observations suggest that the development of theC. antiqua red tide is strongly temperature dependent. 相似文献
We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO2 (fCO2) in the ocean using spectrophotometric analysis (pH and CO2 profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO2 profiler analyzed in situ fCO2 by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can
be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due
to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium
hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of
pH and CO2 profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good
agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4
± 3 μatm (SE, n = 31). 相似文献
Direct current measurements of the branch current of the Kuroshio intruding into Sagani Bay were carried out during 1989–1990 in order to clarify the frequency characteristics of the eddies in the lee of Izu-Oshima Island, which are well recognized as cold water mass produced by upwelling. Satellite and ADCP (Acoustic Doppler Current Profiler) data indicated that current velocity in the eddy fluctuates with periods of 2–4 days and 6–8 days.When the Kuroshio branch current intruding into Sagami Bay from the western channel is weak and its velocity at the depth of 400 m is approximately 10 cm s–1, the 6–8 day period fluctuation is dominant. On the other hand, when the branch current strongly intrudes from the western channel with a velocity of approximately 20 cm s–1, the 2–4 day period fluctuation dominates. The relationship between the periods and velocities agrees well with theory based on laboratory experiments for a flow of a homogeneous fluid past a circular obstacle. These periods correspond to the time scale of appearance of the eddy caused by the intrusion of the Kuroshio branch current into Sagami Bay and Izu-Oshima Island. 相似文献
Field observation was conducted to monitor phosphate concentrations in groundwater and seawater mixing at two sandy beaches in Futtsu and Miura in Tokyo Bay, Japan. Dissolved phosphate concentrations were measured along transects from fresh groundwater aquifer to seawater adjacent the beaches. The concentrations were often high (up to 46 µM) in fresh groundwater samples (Cl– < 0.2). Coastal seawater, on the other hand, exhibited low phosphate concentrations (1.5 µM or less). Along the transects, phosphate generally displayed non-conservative behavior during mixing of fresh and saline waters in the aquifer; concentrations as high as 100 µM were found around the upper limit of seawater intrusion (Cl– = 2). Laboratory experiments were executed to identify the processes that control the phosphate behavior in the mixing processes. The results revealed that adsorption-desorption processes by the aquifer sand particles could significantly control the phosphate concentrations in the groundwater. Furthermore, the adsorption and/or desorption was found to be a function of salinity; the equilibrium concentration of dissolved phosphate in slurry of sand and water was the highest in freshwater and decreased considerably in saline water. The extreme concentration of phosphate may be caused by release from sand particles coinciding with the rapid change in salinity with tide. 相似文献
Concentrations of 12 trace elements (V, Cr, Mn, Cu, Zn, Se, Rb, Sr, Cd, Cs, Ba, and Hg) were determined in liver and skin tissues of minke whales from various regions within the Antarctic Ocean. Cd concentrations in livers of southern minke whale were apparently higher than those in cetaceans from other regions, while Hg concentrations were lower. There were significant positive correlations between body length and concentrations of Cd and Hg in the liver. The concentrations of all trace elements in the skin were lower than those in other cetaceans reported previously. Significant positive correlations between liver and skin were found for Cr, Mn, Cu, Zn, Rb, Cd, and Cs, implying that the concentrations of these trace elements in the skin reflect those of internal organs. Large interannual variation of the accumulation pattern of trace elements in the skin was observed for the southern minke whales from Area V. There were significant differences in the skin element concentrations among Areas III, IV, and V, especially for males. Also, discriminant analysis between geographically two different groups collected during 1995/1996 austral summer season, based on the concentrations of trace elements in the skin, allowed for a correct classification of 90% of these minke whales. These results suggest that measurement of trace elements in skin samples could provide valuable information on the status of contamination and possible geographic differences in the accumulation levels in southern minke whales. 相似文献
Concentrations of nutrients (NO3, NO2, Si(OH)4, PO4 and dissolved inorganic carbon (DIC) were measured in a series of seawater samples collected over approximately 15 months
in 2005 and 2006 by an automatic water sampler (Remote Access Sampler, RAS) in the Northwestern North Pacific. Seasonal variability
and concentrations of NO3 + NO2 (NOx and Si(OH)4 were comparable to previous shipboard observations, although there were small errors associated with measurements of PO4 and DIC. Concentrations of these nutrients began to decrease in late April. After the end of June, NOx and Si(OH)4 decreased rapidly, with large fluctuations. After October, these nutrients increased again until late spring 2006. The ratio
of the decrease of Si(OH)4 to that of NOx suggests that numbers of biogenic opal-producing creatures, such as diatoms, increased after the end of June. This conclusion
was supported by a rapid increase in biogenic opal flux recorded in a sediment trap at 150 m. The relationship between NOx concentrations at the RAS depth of 35 m and NOx integrated over the upper 100 m was determined using previous shipboard hydrocast data. This relationship was used to estimate
integrated mixed layer NOx concentration from RAS data. Estimated new production based on seasonal drawdown of integrated NOx averaged approximately 156 mg-C m−2day−1 annually, which agrees with previous estimates. Thus, an automatic seawater sampler that documents annual maximum and minimum
nutrient concentrations and episodic events such as storms and spring blooms, which might be missed by an ordinary research
vessel, will contribute to time-series observations of nutrients and, by extension, biological pump activity. 相似文献
Features of El Niño events and their biological impacts in the western North Pacific are reviewed, focusing on interactions between ENSO and the East Asian monsoon. Impacts of El Niño on the climate in the Far East become evident as ‘cool summers and warm winters’. Effects of climate regime shift on ENSO activities, western boundary currents and upper-ocean stratification, as well as their biological consequences are summarized. These have been:
1. In the western equatorial Pacific, an eastward extension of the warm pool associated with El Niño events induces an eastward shift of main fishing grounds of skip jack and big eye tunas.
2. The surface salinity front in the North Equatorial Current region retreats southward, associated with El Niño events. This leads to a southward shift of the spawning ground of Japanese eel, which is responsible for a reduction in the transport of the larval eels to the Kuroshio and Japanese coastal region, causing poor recruitment.
3. Intensification of winter cooling and vertical mixing associated with La Niña (El Niño) events in the northern subtropical region of the western (central) North Pacific reduces surface chlorophyll concentration levels and larval feeding condition for both Japanese sardines and the autumn cohort of Neon squid during winter–early spring. The semi-decadal scale calm winter that occurred during the early 1970s triggered the first sharp increase of sardine stock around Japan.
4. A remarkable weakening of southward intrusion of the Oyashio off the east coast of Japan during 1988–91, resulted in a decrease in chlorophyll concentrations and mesozooplankton biomass in late spring–early summer of the Kuroshio-Oyashio transition region. Changes occurred in the dominant species of small pelagic fish, through successive recruitment failures of Japanese sardine.
Article Outline
1. Introduction
2. Linkage between Asian monsoon and ENSO
2.1. Features of Asian monsoon and its role in ENSO
2.2. Influence of ENSO events on summer and winter climate and hydrographic conditions in the western North Pacific
3. Evidence of biotic impacts of ENSO events in the western and central North Pacific
3.1. Eastward shift or spread of fishing grounds of skipjack, bigeye and albacore
3.2. Decrease of recruitment rate of neon squid and Japanese eel
3.3. Increase of plankton biomass in El Niño winters in the northern subtropical gyre south of Japan
3.4. Bleaching phenomena of corals around the Okinawa Islands
4. Discussion
4.1. Modulation of extra-tropical effect of ENSO by inter-decadal variations
4.2. Effects of ENSO and ocean/climate regime shifts on plankton biomass and population variation of small pelagic fish
5. Conclusion
Acknowledgements
References
1. Introduction
During El Niño events the climate in Northeast Asia is generally cool and wet in summer, and warm and calm in winter (Kurihara and Kimura). In the 1998 summer, near the end of 1997/98 El Niño, the East China Sea and southern part of the Japan Sea were covered with abnormally low saline water. This was the result of the huge amounts of fresh water that were discharge from the Yangtze River and caused poor year classes of Japanese common squid.During the recent cold regime that persisted between 1976/77 and 1987/88 in the North Pacific, Japanese sardine, Sardinops melanostictus, maintained a higher stock level, whereas stocks of anchovy, Engraulis spp., remained low (Kasai; Yasuda and Nakata).To clarify the features of this biological response associated with El Niño events and climate regime shifts, in this paper we provide evidence of several environmental and biological responses in the western and central North Pacific. First, we review the linkage between ENSO and the Asian Monsoon. Second, we present data on the extra-tropical effects of El Niño and La Niña on marine ecosystems and the ocean environment. Finally, we describe the modification of extra-tropical effects of ENSO by interdecadal variations in the ocean and the atmosphere.
2. Linkage between Asian monsoon and ENSO
2.1. Features of Asian monsoon and its role in ENSO
Climate of the western North Pacific is dominated by monsoon winds and precipitation. In summer, the southeast monsoon develops between the Tibetan Low and the North Pacific Subtropical High (Fig. 1a). When the summer monsoon encounters the Japanese mountain range, it produces a considerable amount of precipitation on the Pacific side of Japan. In winter, however, the northwesterly monsoon develops between the Siberian High and the Aleutian Low superimposed on the westerly wind (Fig. 1b). 相似文献
