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81.
Zircon U–Pb ages of two acidic tuff and two turbidite sandstone samples from the Nakanogawa Group, Hidaka Belt, were measured to estimate its depositional age and the development of the Hokkaido Central Belt, northeast Japan. In the northern unit, homogeneous zircons from pelagic acidic tuff from a basal horizon dated to 58–57 Ma, zircons from sandstone from the upper part of the unit dated to 56–54 Ma, and zircons from acidic tuff from the uppermost part dated to 60–56 Ma and 69–63 Ma. Both of the tuff U–Pb ages are significantly older than the youngest radiolarian fossil age (66–48 Ma). Therefore, the maximum depositional age of the turbidite facies in the northern unit is 58 Ma and the younger age limit, estimated from the fossil age, is 48 Ma. In the southern unit, homogeneous zircons from turbidite sandstone dated to 58–57 Ma. Thus the depositional age of this turbidite facies was interpreted to be 66–56 Ma from the fossil age, probably close to 57 Ma. Most of the zircon U–Pb ages from the Nakanogawa Group are younger than 80 Ma, with a major peak at 60 Ma. This result implies that around Hokkaido volcanic activity occurred mainly after 80 Ma. Older zircon ages (120–80 Ma, 180–140 Ma, 340–220 Ma, 1.9 Ga, 2.2 Ga, and 2.7 Ga) give information about the provenance of other rocks in the Hidaka Belt. It is inferred that the Nakanogawa Group comprises protoliths of the upper sequence of the Hidaka Metamorphic Zone, which therefore has the same depositional age as the Nakanogawa Group (66–48 Ma). The depositional ages of the lower sequence of the Hidaka Metamorphic Zone and the Nakanogawa Group are probably the same.  相似文献   
82.
We present a new LA–ICP–MS system for zircon fission‐track (FT) and U–Pb double dating, whereby a femtosecond laser combined with galvanometric optics simultaneously ablates multiple spots to measure average surface U contents. The U contents of zircon measured by LA–ICP–MS and standardized with the NIST SRM610 glass are comparable to those measured by the induced FT method, and have smaller analytical errors. LA–ICP–MS FT dating of seven zircon samples including three IUGS age standards is as accurate as the external detector method, but can give a higher‐precision age depending on the counting statistics of the U content measurement. Double dating of the IUGS age standards gives FT and U–Pb ages that are in agreement. A chip of the Nancy 91500 zircon has a homogeneous U content of 84 ppm, suggesting the possibility of using this zircon as a matrix‐matched U‐standard for FT dating. When using the Nancy 91500 zircon as a U‐standard, a zeta calibration value of 42–43 year cm2 for LA–ICP–MS FT dating is obtained. While this value is strictly valid only for the particular session, it can serve as a reference for other studies.  相似文献   
83.
Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.  相似文献   
84.
The geophysical methods are effective tools for determining changes in physical parameters of the geological environment, as soil or groundwater in the presence of contamination. This work consisted on analyzing the natural electric potential obtained over domestic solid waste ditches with controlled closure dates. The interpretation data suggest the generation of electric potential predominantly through the redox phenomenon, as opposed to the flow potential phenomenon. The statistical data analysis indicates a correlation between residence time of the waste and growing variations of voltage. In addition highlights that eight years are required to achieve the reported values for the area with absence of waste, time estimated for decomposition of most organic matter contained in the buried waste.  相似文献   
85.
By comparing detrital zircon U–Pb age spectra of coeval fore‐arc and back‐/intra‐arc basin sandstones, we identified the overall distributary pattern of terrigenous clastic material within the Cretaceous arc system of SW Japan. Abundant Proterozoic (c. 1500–2500 Ma) detrital grains from the interior of East Asia are present in the Cretaceous intra‐arc basin. However, after a barrier mountain range formed during batholith emplacement, Proterozoic clastics were rarely transported into the fore‐arc domain. Episodic batholith formation in Pacific‐type orogens likely played a major role in controlling terrigenous supply routes between coeval back‐arc and fore‐arc domains. The Cretaceous orogen in Japan thus provides a good template for analysing the tectono‐sedimentary development of other arc‐related basins.  相似文献   
86.
Anomalous and natural concentrations of Cr6+, occasionally exceeding the permitted limit for human consumption (0.05 mg/L), have been detected in groundwater in the northwestern region of the state of São Paulo. As part of a water-rock interaction investigation, this article describes the chemical and mineralogical characterization of rock samples taken from boreholes in the municipality of Urânia, with the objective of identifying Cr-bearing minerals and determining how chromium is associated with these minerals. Rock sample analysis were performed using X-ray Fluorescence, X-ray Diffraction, Scanning Electron Microscopy, electron microprobe and sequential extraction techniques. Chemical analyses indicated that the quartzose sandstones show a geochemical anomaly of chromium, with an average content of 221 ppm, which is higher than the reported chromium content of generic sandstones (35 ppm). Diopside was identified as the primary Cr-bearing mineral potentially subject to weathering processes, with a chromium content of up to 1.2% as Cr2O3. Many of the diopside grains showed dissolution features, confirming the occurrence of weathering. Sequential extraction experiments indicated that 99.3% of the chromium in samples is tightly bonded to minerals, whereas 0.24% is weakly bonded via adsorption. Assuming hypothetically that all adsorbed chromium is released via desorption, the theoretical Cr concentration in water would be one order of magnitude higher than the concentrations of Cr6+ detected in groundwater.  相似文献   
87.
This paper presents the results of a new investigation of the Guarani Aquifer System (SAG) in São Paulo state. New data were acquired about sedimentary framework, flow pattern, and hydrogeochemistry. The flow direction in the north of the state is towards the southwest and not towards the west as expected previously. This is linked to the absence of SAG outcrop in the northeast of São Paulo state. Both the underlying Pirambóia Formation and the overlying Botucatu Formation possess high porosity (18.9% and 19.5%, respectively), which was not modified significantly by diagenetic changes. Investigation of sediments confirmed a zone of chalcedony cement close to the SAG outcrop and a zone of calcite cement in the deep confined zone. The main events in the SAG post-sedimentary history were: (1) adhesion of ferrugineous coatings on grains, (2) infiltration of clays in eodiagenetic stage, (3) regeneration of coatings with formation of smectites, (4) authigenic overgrowth of quartz and K-feldspar in advanced eodiagenetic stage, (5) bitumen cementation of Pirambóia Formation in mesodiagenetic stage, (6) cementation by calcite in mesodiagenetic and telodiagenetic stages in Pirambóia Formation, (7) formation of secondary porosity by dissolution of unstable minerals after appearance of hydraulic gradient and penetration of the meteoric water caused by the uplift of the Serra do Mar coastal range in the Late Cretaceous, (8) authigenesis of kaolinite and amorphous silica in unconfined zone of the SAG and cation exchange coupled with the dissolution of calcite at the transition between unconfined and confined zone, and (9) authigenesis of analcime in the confined SAG zone. The last two processes are still under operation. The deep zone of the SAG comprises an alkaline pH, Na–HCO3 groundwater type with old water and enriched δ13C values (<?3.9), which evolved from a neutral pH, Ca–HCO3 groundwater type with young water and depleted δ13C values (>?18.8) close to the SAG outcrop. This is consistent with a conceptual geochemical model of the SAG, suggesting dissolution of calcite driven by cation exchange, which occurs at a relatively narrow front recently moving downgradient at much slower rate compared to groundwater flow. More depleted values of δ18O in the deep confined zone close to the Paraná River compared to values of relative recent recharged water indicate recharge occur during a period of cold climate. The SAG is a “storage-dominated” type of aquifer which has to be managed properly to avoid its overexploitation.  相似文献   
88.
使用由极密集的临时地震台台网观测的余震到时,阐明了2004年新潟县中部地震主震断层的高分辨率速度结构。评估了速度结构与滑动、应力变化及余震分布的空间关系。根据运动学滑动模型,结合三维地壳结构,计算了断层上静态应力降的分布。具有低余震活动性的高速体十分接近主震的震源,并扩展到了断层的东北侧。该高速体大致与凹凸体重合,其同震滑动量和静态应力降高于周边地区。相比之下,在该高速体的浅外围观测到了负应力降区,沉积厚度向西南方向急剧增加且该区余震活动频繁。我们认为断层破坏区周围围岩的结构非均匀性具有控制主震断层动态破裂过程的显著潜势。  相似文献   
89.
Measuring forest degradation and related forest carbon stock changes is more challenging than measuring deforestation since degradation implies changes in the structure of the forest and does not entail a change in land use, making it less easily detectable through remote sensing. Although we anticipate the use of the IPCC guidance under the United Framework Convention on Climate Change (UNFCCC), there is no one single method for monitoring forest degradation for the case of REDD+ policy. In this review paper we highlight that the choice depends upon a number of factors including the type of degradation, available historical data, capacities and resources, and the potentials and limitations of various measurement and monitoring approaches. Current degradation rates can be measured through field data (i.e. multi-date national forest inventories and permanent sample plot data, commercial forestry data sets, proxy data from domestic markets) and/or remote sensing data (i.e. direct mapping of canopy and forest structural changes or indirect mapping through modelling approaches), with the combination of techniques providing the best options. Developing countries frequently lack consistent historical field data for assessing past forest degradation, and so must rely more on remote sensing approaches mixed with current field assessments of carbon stock changes. Historical degradation estimates will have larger uncertainties as it will be difficult to determine their accuracy. However improving monitoring capacities for systematic forest degradation estimates today will help reduce uncertainties even for historical estimates.  相似文献   
90.
The relaxed eddy accumulation (REA) method is an attractive alternative to the eddy covariance method to measure trace-gas flux, because it allows the use of analyzers with an optimal integration time to reduce the noise. However, the use of an empirical coefficient b results in uncertainties in the REA method. The consistency of b for temperature was investigated using a 1 year dataset obtained at three forest sites in East Asia: a temperate evergreen coniferous forest, a tropical evergreen broadleaf forest, and a cool-temperate deciduous coniferous forest. The observational b ranged from 0.54 to 0.57 under unstable conditions. Although the values for observational b were within narrow ranges among the sites, there were slight site-specific differences. We introduced new expression of b, similarity b, based on scalar similarity using the integral turbulence characteristics to investigate the nature of b. Both the observational and similarity b increased with increasing atmospheric stability under stable conditions, when lower values for the standard deviation of the vertical wind velocity resulted in higher values for b. The variations in b under stable conditions differed among sites. There were no seasonal variations in the observational b at all sites. Consequently, the present study recommends determining the coefficient b for unstable conditions for each site and considering changes in b associated with atmospheric stability in order to minimize errors in the REA method.  相似文献   
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