Complexation of dimethylsulfide with mercuric ion in aqueous solutions     

Gui-Peng Yang  Shizuo Tsunogai  Shuichi Watanabe 《Journal of Oceanography》2006,62(4):473-480

The tendency of dimethylsulfide (DMS) to form complexes with heavy metal ions in aqueous solutions and the factors that influence it have been investigated. Among five heavy metal ions examined (Cu²⁺, Cd²⁺, Zn²⁺, Pb²⁺ and Hg²⁺), only Hg²⁺ bound significantly with DMS in aqueous solutions in which Hg²⁺ concentration was increased to much higher levels than that of natural seawater. The complexation capacity of Hg²⁺ for DMS was influenced by pH and media. The affinity of Hg²⁺ for DMS was generally lower at high than at low pH, presumably due to the competition of hydroxide ion to form hydroxomercury species. In different solutions, the affinity of Hg²⁺ for DMS followed the following sequence: ultra-purified water > 35‰ NaCl solution > seawater. It seems apparent that chloride had a negative impact on the complexation of DMS by Hg²⁺, owing to the competition of chloride with DMS for complexing Hg²⁺. In addition, the affinity of Hg²⁺ for DMS in the bulk seawater appeared to be higher than that in the surface microlayer seawater. The tendency of Hg²⁺ to form complexes with DMS in aqueous solution can be reduced by the presence of 2 mM amino-acid such as glycine, alanine, serine and cysteine, as these ligands give stable mercury complexes. However, the presence of 2 mM acetate in experimental solutions had no significant effect on the complexation of Hg²⁺ with DMS, even though this ligand has a relatively strong complexing capacity for Hg²⁺. Although mercury ions appeared to have a strong affinity for DMS, the concentration of mercury in seawater is too low to produce a great effect on the distribution of DMS in oceans.  相似文献   

Lead-210 in the Japan Sea     

Yoshiyuki Nozaki  Shizuo Tsunogai  Masakichi Nishimura 《Journal of Oceanography》1973,29(6):251-256

This is the first detailed study on the distribution of lead-210 in the Japan Sea water. The content of lead-210 ranged from 9.3±2.1 dph/l in the surface water to 3.4+-0.8 dph/l in the deep water—a quite low content as compared to that in the deep water of the North Pacific. Vertical profiles show that the content of lead-210 abruptly decreases below the seasonal thermocline (10–20 m in depth) and nearly uniform in the deep water. It is suggested that a significant amount of air-borne lead-210 deposited over the Japan Sea is transported along with the Tsushima Current to the open ocean. The budget of lead-210 is calculated by using a simple box-model and the mean residence time of lead-210 in the Japan Sea is estimated to be 15 yr.  相似文献   

Biological effect on removal of Th-234, Po-210 and Pb-210 from surface water in Funka Bay,Japan     

Noriyuki Tanaka  Yoichiro Takeda  Shizuo Tsunogai 《Geochimica et cosmochimica acta》1983,47(10):1783-1790

Vertical and temporal variations in the radioactivities of Th-234, Pb-210 and Po-210 were measured at a station in Funka Bay from April 1979 to February 1980. The inventory of Th-234 showed a minimum in early spring, when a spring bloom of phytoplankton was observed, then a steady increase to a maximum value in late summer, just before open sea water invaded the bay and a secondary phytoplankton bloom started. The inventories of Pb-210 and Po-210 also showed minima in early spring. These results suggest that the removal of these nuclides from sea water is accelerated by biological activity. The concentration of Th-234 decreased with depth, but those of Po-210 and Pb-210 were higher in the bottom water in August 1979 when the bay water was strongly stratified. This may be due to the supply of Pb-210 and Po-210 from the bottom. However, if the supply of these nuclides is expected in sediment particles, the concentrations of these nuclides in suspended matter were not sufficient to explain their increments in the bottom water.Residence times of Th, Pb and Po were estimated by applying a non-steady state model to the bay water when the water stayed in and the concentrations of these nuclides were changing. The mean residence time of Th is not significantly different from that of Pb, but is about half of that of Po, although the difference is much smaller than that obtained by applying a steady state model.  相似文献   

Removal of²³⁴Th from a coastal sea: Funka Bay,Japan     

Masao Minagawa  Shizuo Tsunogai 《Earth and Planetary Science Letters》1980,47(1):51-64

In Funka Bay of Hokkaido, Japan, seawater, suspended matter and settling matter were collected once every month in the summer of 1974. These samples were analyzed for²³⁴Th, a short-lived daughter of dissolved²³⁸U. A pronounced disequilibrium between²³⁴Th and²³⁸U, and a highly variable concentration of²³⁴Th were found. Positive correlation, however, exist among the deficiency of²³⁴Th relative to²³⁸U in seawater, the concentration of particulate²³⁴Th, the fraction of particulate²³⁴Th to total²³⁴Th in seawater, the total dry weight of suspended matter, and the primary productivity during the month previous to sampling. The specific activity of²³⁴Th for the settling particles (620 ± 170 dpm/g) was nearly equal to that for suspended particles (720 ± 600 dpm/g) but much greater than that for plankton (47 ± 24 dpm/g). These facts suggest that suspended particles are somehow closely related to the removal of heavy metals from seawater, in spite of the negligibly small settling flux of suspended matter. The residence time of thorium in Funka Bay (mean depth: 60 m) is found to be about 60 days, which is nearly equal to those of²¹⁰Pb and²¹⁰Po.  相似文献   

Strain geometries in the Sanbagawa Metamorphic Belt inferred from deformation structures in metabasite     

Ichiko Shimizu  Shizuo Yoshida 《Island Arc》2004,13(1):95-109

Abstract Ductile deformation in the Sanbagawa Metamorphic Belt has been considered to be characterized by uniaxial elongation parallel to the east–west‐trending lineation, based on strain analysis of radiolarian fossils in metachert. However, only limited data were available to test this idea in strongly recrystallized schists. Strain measurements on deformed pillow structures in central Shikoku show uniaxial flattening, whereas pressure shadows around pyrite in the Kanto Mountains indicate constrictional strain. In addition, in the low‐grade part of the Sanbagawa Metamorphic Belt belonging to the Northern Chichibu Belt in the Kanto Mountains, deformed amygdules in pillow lava show flattening strain, which is consistent with the results of strain measurements using radiolarian fossils in the same area. These observations, together with the results of other strain analyses reported so far, indicate that the strain field is not uniform and that the east–west‐trending shearing and stretching were not pervasive in the Sanbagawa Metamorphic Belt.  相似文献   

Lead-210 in the North Pacific and the transport of terrestrial material through the atmosphere     

Yoshiyuki Nozaki  Shizuo Tsunogai 《Earth and Planetary Science Letters》1973,20(1):88-92

²¹⁰Pb in the surface water of the North Pacific was extensively determined. The results showed that the highest concentrations of²¹⁰Pb of 19 ± 3dpm/100kg were found in the northern mid-latitudes around 30°N, but longitudinal variation across the North Pacific was not observed. The mean residence time of²¹⁰Pb in the surface water up to 100 m in depth is calculated to be 230 days. In the mid-latitudes of the northern hemisphere,²¹⁰Pb may be transported by the prevailing westerly wind of a higher speed than 15 m/sec, likely the jet stream.  相似文献   

Low detection capability of global earthquakes after the occurrence of large earthquakes: investigation of the Harvard CMT catalogue   总被引：4，自引：0，他引：4  

Takaki Iwata 《Geophysical Journal International》2008,174(3):849-856

We investigated the detection capability of global earthquakes immediately after the occurrence of a large earthquake. We stacked global earthquake sequences after occurrences of large earthquakes obtained from the Harvard centroid-moment tensor catalogue, and applied a statistical model that represents an observed magnitude–frequency distribution of earthquakes to the stacked sequence. The temporal variation in model parameters, which corresponds to the detection capability of earthquakes, was estimated using a Bayesian approach. We found that the detection capability of global earthquakes is lower than normal for several hours after the occurrence of large earthquakes; for instance, the duration of lowered detection capability of global earthquakes after the occurrence of an earthquake with a magnitude of seven or larger is estimated to be approximately 12 hr.  相似文献   

3D analytical solution to the tidally induced Lagrangian residual current equations in a narrow bay   总被引：1，自引：0，他引：1  

Wensheng Jiang  Shizuo Feng 《Ocean Dynamics》2014,64(8):1073-1091

The 3D first-order Lagrangian residual velocity (LRV) equation is established, and its analytical solution is obtained in a narrow bay. The results show clearly the 3D structure of the first-order LRV. When the exponential bottom profile is assumed, the upper half layer of the water flows in through the deep channel from the open boundary directly to the head of the bay. Then the water will return to the area surrounding the lower half of the inflow area. The downwelling area is located mainly at the deep channel, while the upwelling area occupies both sides of the bay. The inter-tidal water transport, obtained by integrating the 3D first-order LRV through the water column, has a pattern similar to the previous study in which the 2D depth-averaged Lagrangian residual current equations were solved. The inter-tidal water transport is used to analyze the water exchange, and it is found that the water exchange at different cross sections increases smoothly with the distance between the cross sections and the head of the bay until about one wavelength. It is also found that the pattern of the breadth-averaged Lagrangian residual current varies with the length of the bay if a non-flat bottom profile is used. The depth-integrated LRV and the breadth-averaged LRV are mainly determined by the different terms of the tidal body force, with the former determined by the bottom friction related term and the latter by the eddy viscosity related term. When the bay is longer than one wavelength, different results in the outer bay can be observed.  相似文献   

Simulation of the Lagrangian tide-induced residual velocity in a tide-dominated coastal system: a case study of Jiaozhou Bay, China     

Guangliang Liu  Zhe Liu  Huiwang Gao  Zengxiang Gao  Shizuo Feng 《Ocean Dynamics》2012,62(10-12):1443-1456

The Eulerian residual transport velocity and the first-order Lagrangian residual velocity for weakly nonlinear systems have been used extensively in the past to depict inter-tidal mass transport. However, these could not explain the observed net surface sediment transport pattern in Jiaozhou Bay (JZB), located on the western Yellow Sea. JZB is characterized by strong tidal motion, complex topography and an irregular coastline, which are features of typical nonlinear systems. The Lagrangian residual velocity, which is applicable to general nonlinear systems, was simulated with the water parcel tracking method. The results indicate that the composition of the Lagrangian residual velocity at different tidal phases coincides well with the observed net surface sediment transport pattern. The strong dependence of water flushing time on the initial tidal phase can also be explained by the significant intra-tidal variation of the Lagrangian residual velocity. To investigate the hydrodynamic mechanism governing the nonlinearity of the M ₂ tidal system, a set of nonlinearity indexes were defined and analysed. In the surface layer, horizontal advection is the main contributor to the strong nonlinearity near the bay mouth, while in the bottom layer, the strong nonlinearity near the bay mouth may result from the vertical viscosity and horizontal advection.  相似文献   

Arsenic species and their accumulation features in green turtles (Chelonia mydas)     

Tetsuro Agusa  Kozue Takagi  Hisato Iwata  Shinsuke Tanabe   《Marine pollution bulletin》2008,57(6-12):782

Total arsenic (As) and its compounds were determined in liver, kidney, muscle, and stomach contents of green turtles (Chelonia mydas). Total As concentrations in the muscle were higher than those in the kidney and liver. Arsenobetaine (AB) was the predominant compound in all the three tissues and its levels were positively correlated with total As concentrations. This indicates that AB greatly contributes to As accumulation in green turtles. Higher concentrations of remaining As in the sample after extraction were detected in the liver, implying that lipid-soluble or protein bound As compounds accumulate in the liver of green turtles. Total As levels in tissues showed significant negative correlations with standard carapace length. The size-dependence of As accumulation in green turtles may be related to their feeding habit, shifting from carnivore to herbivore at different growth stages. Concentrations of AB and dimethylarsinic acid (DMA) were low in the stomach contents but high in the tissues, implying bioaccumulation of these arsenicals in green turtles.  相似文献