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11.
A new catalytic dehydrohalogenation method for chlorinated phenols is described, which can be used to break down chlorinated pollutants in wastewater. It uses a system of Pd‐C as catalyst with sodium formate as reducing agent. This economic method is easy to perform with a complete degradation of the pollutant within 12 to 30 h at room temperature. The ecoefficieny of the procedure is compared with eleven alternative methods showing the special advantages of the method.  相似文献   
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Crucian carp were exposed to three combinations of pH and inorganic aluminium concentrations for 25 days. Mortality, plasma chloride and haematocrit, and gill aluminium content were investigated. No mortality was observed in any of the three exposures. Crucian carp survived acidic Al-rich water (pH 5.17) with a high concentration of low-molecular weight inorganic Al species (242 µgl–1) for 25 days. These fish had lowered plasma chloride levels and high amounts of aluminium on their gills compared to fish exposed to acidic Al-poor water (pH 5.16 and 12 µgl–1 Ali) and control water (pH 6.29 and 4 µgl–1 Ali). Haematocrit was the same in all three exposures. Because aluminium was not acutely toxic to the anoxia tolerant crucian carp, the present results give support to the hypothesis that Al polymerization with subsequent hypoxia is of high importance for the mechanism of acute Al toxicity to fish.  相似文献   
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A method for history matching of an in-house petroleum reservoir compositional simulator with multipoint flux approximation is presented. This method is used for the estimation of unknown reservoir parameters, such as permeability and porosity, based on production data and inverted seismic data. The limited-memory Broyden–Fletcher–Goldfarb–Shanno method is employed for minimization of the objective function, which represents the difference between simulated and observed data. In this work, we present the key features of the algorithm for calculations of the gradients of the objective function based on adjoint variables. The test example shows that the method is applicable to cases with anisotropic permeability fields, multipoint flux approximation, and arbitrary fluid compositions.  相似文献   
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