High‐resolution synchrotron X‐ray fluorescence investigation of calcite coralloid speleothems: Elemental incorporation and their potential as environmental archives     

Valentina Vanghi  Andrea Borsato  Silvia Frisia  Daryl L. Howard  Gertruida Gloy  John Hellstrom  Petra Bajo 《Sedimentology》2019,66(7):2661-2685

Synchrotron high‐resolution and micro‐X‐ray fluorescence elemental mapping of two coeval coralloid speleothems from Lamalunga Cave (Italy) are complemented with petrographic, morphological and microstratigraphic studies. The importance of these speleothems relies on their direct and indirect association with a complete Neanderthal skeleton (‘Altamura Man’) found inside the cave. The coralloids grew discontinuously between 64·6 ka and the Holocene and reveal exceptionally high concentrations of Mg, Sr and Si, particularly on convex surfaces, where evaporation is more intense. The incorporation of trace elements depends on several factors including location, shape and geometrical evolution during their growth, as well as climate and environmental parameters. This resulted in calcite precipitation with Sr compositions from 100 to 1200 ppm and an average concentration of 7000 ppm Mg. An unusually high Si content (up to 16%) is possibly derived from volcanic ash transported as particulate and in solution inside the cave. The most common fabrics observed consist of non‐fluorescent elongated columnar calcite forming clean isopachous bands and fluorescent fibre‐like crystals associated with laminated, lenticular bands high in Sr, Mg and Si. Variability in Sr, Mg and Si concentrations appears to induce fabric changes in the coralloids. Elongation and lattice distortion of the crystals was found to coincide with high Mg concentrations. The transition from compact elongated to open to fibre‐like, is here interpreted as due to high concentrations of Si and Sr, which are preferentially incorporated in the speleothem at crystal boundaries and intra‐laminae. It is here inferred that coralloid fabric changes and their elemental content potentially record local rainfall variations through time, with the clean compact calcite marking high infiltration and open fibre‐like and micrite fabrics recording dry periods.  相似文献   

Tsunamis recorded in tide gauges at Costa Rica Pacific coast and their numerical modeling     

Silvia Chacón-Barrantes  Alejandro Gutiérrez-Echeverría 《Natural Hazards》2017,89(1):295-311

Here we perform an inventory of tsunamis recorded by tide gauges in the Pacific coast of Costa Rica. This paper also reveals nine tsunami records that had not been published before, at Puntarenas tide gauge corresponding to the 1979 Colombia tsunami and at Quepos tide gauge corresponding to the 1985 Mexico twin tsunamis, the 2010, 2014 and 2015 Chile tsunamis, the 2006 Tonga tsunami, the 2011 Japan tsunami and the 2013 Solomon Islands tsunami. The original record of 1990 Cóbano tsunami at Quepos was digitized again at a higher resolution and re-processed. The arrival of 1979, 1985, 2006 and 2014 tsunamis to Costa Rica is not listed on tsunami catalogs. The maximum tsunami height obtained here after processing 1990, 2011 and 2013 records was higher than reported on catalogs. The opposite happened for the 2010 tsunami. Quepos gauge record for January 2007 was analyzed as it seemed to have registered the Kuril Islands tsunami, but the results were not conclusive due to the low sample rate and the small tsunami amplitude if any. All those eleven tsunamis were modeled and the results compared with the records. A good agreement was obtained for the Quepos gauge, although the modeled 2011 and 2013 tsunamis had a difference of 8 min on the arrival time. An acceptable agreement was obtained for the Puntarenas gauge for 1979 tsunami, considering at least the first 4 h of the marigram is lost.  相似文献   

Influence of Organic Enrichment and <Emphasis Type="Italic">Spisula subtruncata</Emphasis> (da Costa, 1778) on Oxygen and Nutrient Fluxes in Fine Sand Sediments     

Javier Sospedra  Silvia Falco  Tania Morata  Miguel Rodilla 《Estuaries and Coasts》2017,40(3):726-740

The role of labile organic material and macrofaunal activity in benthic respiration and nutrient regeneration have been tested in sublittoral fine sand sediments from the Gulf of Valencia (northwestern Mediterranean Sea). Three experimental setups were made using benthic chambers. One experiment was performed in-situ through the annual cycle in a well-sorted fine sand community. The remaining experiments were carried out with mesocosms under laboratory conditions: one with different concentrations of organic enrichment (mussel meat and concentrated diatoms culture), and the other adding two different densities of the endofaunal bivalve Spisula subtruncata. Biochemical variables in surface sediment and changes in oxygen consumption and nutrient fluxes throughout incubation period were studied in each experiment. In the in situ incubations, dissolved oxygen (DO) fluxes showed a strong correlation with sedimentary biopolymeric fraction of organic carbon. Organic enrichment in the laboratory experiments was responsible for increased benthic respiration. However, sediment response (expressed as DO uptake and dissolved inorganic nitrogen—DIN—release) between oligotrophic and eutrophic conditions was more intense than between eutrophic and hypertrophic conditions. S. subtruncata abundances close to 400 and 850 ind m^?2 also intensified benthic metabolism. DO uptake and DIN production in mesocosms with added fauna were between 60 and 75 % and 65–100 % higher than in the control treatment respectively. The results of these three experiments suggest that the macrobenthic community may increase the benthic respiration by roughly a factor of two in these bottoms, where S. subtruncata is one of the dominant species. Both organic enrichment and macrobenthic community in general, and S. subtruncata in particular, did not seem to have a relevant role in P and Si cycles in these sediments.  相似文献   

Carbon Isotope Analysis to Evaluate Nanoscale Fe(O) Treatment at a Chlorohydrocarbon Contaminated Site     

Martin Elsner  Georges Lacrampe Couloume  Silvia Mancini  Leanne Burns  Barbara Sherwood Lollar 《Ground Water Monitoring & Remediation》2010,30(3):79-95

Remediation of groundwater contaminated by chlorinated hydrocarbons via in situ technologies such as direct injection of nanoscale zero valent iron (ZVI, Fe(O)) particles is increasingly common. However, assessing target compound degradation by abiotic processes is difficult because (1) the injection may displace the contaminant plume so that concentration measurements alone are often inconclusive and (2) biodegradation may also occur, making it challenging to identify and evaluate the abiotic degradation component. In this study, trichloroethylene (TCE) and 1,1,1-trichloroethane (1,1,1-TCA) were treated in a highly heterogeneous hydrogeologic setting. The purpose of this study was to evaluate the potential for compound-specific stable isotope analysis (CSIA) to monitor the effectiveness of ZVI injection by assessing TCE and 1,1,1-TCA degradation. Prior to ZVI injection, carbon isotope measurements demonstrated biodegradation of TCE by native microorganisms. This in situ biodegradation was quantified by measuring the enrichment of ¹³C in TCE samples downstream of the suspected source. When ZVI was injected through only two injection wells, no changes in TCE and 1,1,1-TCA isotope signatures were detected compared to preinjection values. In contrast, when ZVI was injected through 11 wells covering a greater portion of the contaminated area, 5 out of 10 monitoring wells showed further enrichment of ¹³C in either TCE or 1,1,1-TCA, indicating additional target compound transformation. The abiotic nature of this TCE transformation was confirmed through temporal trends in carbon isotope values of the putative transformation products cis-dichloroethylene (cis-DCE), ethene and ethane. This demonstrates the usefulness of CSIA in distinguishing abiotic vs. biotic transformation in the field.  相似文献   

Temporal correlations and clustering of landslides     

Annette Witt  Bruce D. Malamud  Mauro Rossi  Fausto Guzzetti  Silvia Peruccacci 《地球表面变化过程与地形》2010,35(10):1138-1156

This paper examines temporal correlations and temporal clustering of a proxy historical landslide time series, 2255 reported landslides 1951–2002, for an area in the Emilia‐Romagna Region, Italy. Landslide intensity is measured by the number of reported landslides in a day (D_L) and in an ‘event’ (S_event) of consecutive days with landsliding. The non‐zero values in both time series D_L and S_event are unequally spaced in time, and have heavy‐tailed frequency‐size distributions. To examine temporal correlations, we use power‐spectral analysis (Lomb periodogram) and surrogate data analysis, confronting our original D_L and S_event time series with 1000 shuffled (uncorrelated) versions. We conclude that the landslide intensity series D_L has strong temporal correlations and S_event has likely temporal correlations. To examine temporal clustering in D_L and S_event, we consider extremes over different landslide intensity thresholds. We first examine the statistical distribution of interextreme occurrence times, τ, and find Weibull distributions with parameter γ << 1·0 [D_L] and γ < 1·0 [S_event]; thus D_L and S_event each have temporal correlations, but S_event to a lesser degree. We next examine correlations between successive interextreme occurrence times, τ. Using autocorrelation analysis applied to τ, combined with surrogate data analysis, we find for D_L linear correlations in τ, but for S_event inconclusive results. However, using Kendall's rank correlation analysis we find for both D_L and S_event the series of τ are strongly correlated. Finally, we apply Fano Factor analysis, finding for both D_L and S_event the timings of extremes over a given threshold exhibit a fractal structure and are clustered in time. In this paper, we provide a framework for examining time series where the non‐zero values are strongly unequally spaced and heavy‐tailed, particularly important in the Earth Sciences due to their common occurrence, and find that landslide intensity time series exhibit temporal correlations and clustering. Many landslide models currently are designed under the assumption that landslides are uncorrelated in time, which we show is false. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Carbon dioxide concentration in temperate climate caves and parent soils over an altitudinal gradient and its influence on speleothem growth and fabrics          下载免费PDF全文

Andrea Borsato  Silvia Frisia  Renza Miorandi 《地球表面变化过程与地形》2015,40(9):1158-1170

Carbon dioxide (CO₂) concentrations in caves and parent soils in the Italian Alps have been studied along a 2100 m altitudinal range – corresponding to a mean annual temperature (MAT) range of 12°C – in order to investigate the relationship between MAT, soil pCO₂ and cave air pCO₂, and to test the influence of soil pCO₂ on speleothem growth and fabric to ultimately gain insight into their palaeoclimatic significance in temperate climate settings. Our findings indicate that soil CO₂ is linearly correlated to MAT and its mean annual concentration is described by the equation: soil CO₂ (ppmv) = 1112 + 460 MAT. Soil pCO₂ can also be exponentially correlated to actual evapotranspiration. The pCO₂ in the aquifer is linearly correlated to MAT at the infiltration site and is more influenced by summer soil pCO₂. Cave air CO₂ in the innermost part of the caves exhibits a similar seasonal pattern, and commonly reaches concentrations of about 15% to 35%, with respect to the corresponding soil values, and is exponentially correlated to the MAT at the infiltration site. The combination of these parameters (soil pCO₂, dripwater pCO₂ and cave air pCO₂) results in speleothem growth and controls their fabrics which are typical of four MAT/elevation belts broadly corresponding to the present‐day vegetation zones. In the lower montane zone [100–800 m above sea level (a.s.l.)] speleothems mostly consist of columnar fabric, in the upper montane zone (800–1600 m a.s.l.) both columnar and dendritic fabrics are common, the Subalpine zone (1600–2200 m a.s.l.) is characterized mostly by moonmilk deposits, whereas in the Alpine zone (above 2200 m a.s.l.) no speleothems are forming today. Therefore, fabric changes in fossil speleothem can potentially be used to reconstruct MAT changes in temperate climate karst areas. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

地磁数据分析的一些思考   总被引：3，自引：1，他引：2       下载免费PDF全文

Laurentiu ASIMOPOLOS  Agata Monica PESTINA  Natalia Silvia ASIMOPOLOS 《地球物理学报》2010,53(3):765-772

通过若干实例,本文讨论了地磁数据分析中的一些方法.这些方法包括时间序列的多项式拟合,相关性分析,频谱分析和小波分析等.在Matlab和AutoSignal软件下实现了以上方法,并基于这些方法研究了地磁场形态和地磁现象的频谱特征.我们分析了Surlari观测台（余纬45.3°,经度26.3°）的地磁时间序列,并与Ottawa（余纬44.6°,〖JP2〗经度284.5°）,Canberra（余纬125.3°,经度149.3°）, Kakioka（余纬53.8°,经度140.2°）,Vernadsky〖JP〗（余纬155.3°,经度295.7°）等台站的结果进行了对比分析,讨论了Fourier变换时间窗和小波基函数选取的影响,有限长时间序列引起的边缘效应,以及小波尺度和Fourier频率的关系等问题.我们采用谱分析和小波分析处理了2007年两个台站的地磁数据,研究了地磁场形态和地磁现象的频谱特征,并讨论了Fourier变换和小波变换的优缺点.  相似文献   

A high-resolution Holocene record on the Southern Brazilian shelf: Paleoenvironmental implications     

Michel Michaelovitch de Mahiques  Ilana Klein Coaracy Wainer  Leticia Burone  Renata Nagai  Silvia Helena de Mello e Sousa  Rubens Cesar Lopes Figueira  Ilson Carlos Almeida da Silveira  Mrcia Caruso Bícego  Daniel Pavani Vicente Alves   yvind Hammer 《Quaternary International》2009,206(1-2):52

A high-resolution, multi-proxy record has been used to determine the environmental changes during the Holocene on the southern Brazilian shelf. Present oceanographic conditions reveal wind and freshwater input as the determinants of short-term productivity changes in the study area. Magnetic susceptibility and grain-size variations, together with proxies of productivity (organic carbon, carbon accumulation rate, Ba, Sr, and Ca content, Ba/Al, Ba/Ti, and Al/Ti ratios) were analyzed and compared with proxies of redox condition (V/Ti ratio), terrigenous input (Fe/Ca and Ti/Ca ratios), as well as other Element/Ti ratios, to evaluate the paleoceanographic and paleoclimatic changes over the period.The core covers a time interval of about 7650 years, with sedimentation rates varying from 0.025 to 0.250 cm a⁻¹, which represent time intervals of between 8 and 80 a per sample. There is a clear change in the sedimentation rate at about 2800 B.P.All grain-size and elemental results indicate the occurrence of conspicuous changes between 5200 and 5000 cal. B.P., as well as between 3000 and 2800 cal. B.P. A comparison of the results with the palynological information available from the adjacent continental areas suggests that the sedimentary changes in this last interval may be correlated with the onset of modern climatic conditions in South America, and especially, with the onset of the Plata Plume Water, a water mass that carries cold, less saline waters towards the north. However, minor changes are observed at ca. 1500 B.P. and are correlated with an increase in the atmospheric humidity. Furthermore, a time-series analysis undertaken using several proxies indicated the occurrence of Sub-Milankovitch cycles, which may be compared with those reported worldwide.  相似文献   

Seasonal and inter-annual zooplankton dynamics in temporary pools with different hydroperiods   总被引：1，自引：0，他引：1  

Silvia Tavernini   《Limnologica》2008,38(1):63-75

The results of a research carried out in 2001 on nine temporary mountain pools (Northern Apennines, Italy) underlined a major role of hydroperiod in shaping zooplankton communities of temporary habitats. In 2002, the same pools were studied to assess inter-annual differences in zooplankton seasonal patterns. Data on precipitations (both snow and rainfalls) were collected to evaluate the influence of precipitation regimes on hydroperiod and concurrently on hydrochemical features and zooplankton dynamics.Mean annual snow and rainfall abundances were highly similar in both years but precipitation patterns were different. Moreover, different air temperatures were measured in the 2 years of study. These factors influenced water persistence and dry and wet cycles in the pools: in 2001, three pools dried out in summer and remained dry until autumn rainfalls (type A pools), in five pools (type B pools) the summer dry period was interrupted by re-filling due to storms in July and only in one pool water did remain for the entire research period (C1). In 2002, type A and B pools underwent only one dry phase (June–July) while C1 showed a hydroperiod similar to the one that occurred in the previous year. Overall, type A and B pools can be classified as ‘seasonal’ and C1 as ‘near-permanent or permanent’.Principal component analysis and paired t-tests did not show significant differences between years in the hydrochemical features of the pools. However, the seasonal pools showed a wide range of variation in their hydrochemical parameters while water features of the permanent pool presented less variability.Within the pools, divergences in the number and in the type of zooplankton taxa between the 2 years were limited. Rotifer and copepod density of the seasonal pools were comparable over years and only cladocerans exhibited distinct density dynamics. Cladoceran appeared to be associated with ionic content and influenced by the occurrence of ice-melting and by the wet phase length of the pools.On the contrary, the permanent pool showed diverse zooplankton seasonal patterns in 2001 compared to 2002. Over years, different pH values were measured; pH and conductivity varied with changing water volume, which in turn explained a significant amount of the observed variation in zooplankton densities in 2002.  相似文献   

The influence of ENSO and PDO on tropical Andean glaciers and their impact on the hydrology of the Amazon Basin     

Njila Souza da Rocha  Bijeesh K Veettil  Atilio Grondona  Silvia Rolim 《Singapore journal of tropical geography》2019,40(3):346-360

Recent decades, particularly since the late 1970s, have witnessed a rapid retreat of glaciers in the tropical Andes. We compiled the changes in glacier surfaces along the eastern cordilleras of the tropical Andes of Peru and Bolivia since the early 1980s from the literature. Water levels from two Brazilian river basins in the Amazon basin (one (Madeira River) glacially fed by meltwater from the Andes and the other (Envira River) non‐glacially fed), were analysed for a 30‐year period between 1985?2014. Furthermore, precipitation data near these two basins were also analysed in order to understand the differential contributions of glacier melting and rainfall. Variations in the water levels from the glacially fed Madeira River showed that some years were associated with higher water levels even when the precipitation remained low during the corresponding season (May‐October). This observation was common when El Niño events occurred during the positive phase of Pacific Decadal Oscillation (PDO). Water levels in glacier‐fed Madeira River were slightly higher during the periods where El Niño and warm PDO co‐occurred. On the other hand, water levels in the Envira River were precipitation dependent; water levels were higher when the rainfall was high.  相似文献