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In the period 1997-2000, approximately 1,800,000 m3 of material dredged from the Port of Leghorn was discharged into a sea dumping site located 14 miles from the coast. The red mullet (Mullus barbatus) was used as a bioindicator species for monitoring the biological impact of these discharges on a geographical and temporal scale. Organisms were sampled over three years (1998-2000) at different stations and several biomarkers, both of exposure and effect, were analyzed. Bioavailability of specific classes of pollutants was evaluated by analyzing levels of metallothioneins, the activity of cytochrome P450 1A (CYPIA) and of glutathione S-transferases. Among biomarkers of effect, special attention was paid to the balance between prooxidant challenge and antioxidant defenses, and to the appearance of damage caused by oxidative stress. The analyses of the main components of the antioxidant system included superoxide dismutase, catalase, glutathione peroxidases, glutathione reductase, glyoxalase I and II, and total glutathione. These data were integrated with the measurement of total oxyradical scavenging capacity (TOSC) as an indication of the overall biological resistance to toxicity of different forms of oxyradicals (peroxyl radicals, hydroxyl radicals and peroxynitrite). Results indicated a biological impact in organisms sampled near the disposal site; the impact was particularly evident during 1999 and mainly related to organic chemicals such as PAH. Exposure to these pollutants also caused variations in the levels and activity of several antioxidants. The analysis of TOSC, however, revealed that the overall capacity of specific tissues of organisms to absorb various oxidants was not seriously compromised when challenged with increased prooxidant pressures. Variations of single antioxidants were useful in revealing early warning "biological responses", while integration with TOSC analyses indicated if such changes also reflect a more integrated and functional "biological effect" with possible consequences at the organisms level. The red mullet appears to be a useful sentinel species for a biomarker approach to monitoring impact caused by dredged materials.  相似文献   
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A global database of 2,626 rainfall events that have resulted in shallow landslides and debris flows was compiled through a thorough literature search. The rainfall and landslide information was used to update the dependency of the minimum level of rainfall duration and intensity likely to result in shallow landslides and debris flows established by Nel Caine in 1980. The rainfall intensity–duration (ID) values were plotted in logarithmic coordinates, and it was established that with increased rainfall duration, the minimum average intensity likely to trigger shallow slope failures decreases linearly, in the range of durations from 10 min to 35 days. The minimum ID for the possible initiation of shallow landslides and debris flows was determined. The threshold curve was obtained from the rainfall data using an objective statistical technique. To cope with differences in the intensity and duration of rainfall likely to result in shallow slope failures in different climatic regions, the rainfall information was normalized to the mean annual precipitation and the rainy-day normal. Climate information was obtained from the global climate dataset compiled by the Climate Research Unit of the East Anglia University. The obtained global ID thresholds are significantly lower than the threshold proposed by Caine (Geogr Ann A 62:23–27, 1980), and lower than other global thresholds proposed in the literature. The new global ID thresholds can be used in a worldwide operational landslide warning system based on global precipitation measurements where local and regional thresholds are not available..  相似文献   
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This study provides an analysis of a five-year time series chemical composition of the bulk deposition (2009–2013), collected within a farm surrounded by industrial and urban settlements in a semi-rural area of the Po Valley, with the aim of characterizing potential emission sources affecting precipitation composition at the site. Most monitoring efforts in this region, recognized as one of the most polluted in the world both due to the intense industrialisation and urbanisation as well as to frequent air stagnation conditions, are presently devoted more to gaseous and particulate pollutants than to precipitation chemistry. The bulk deposition samples were very concentrated in chemical species, both acidic and alkaline, high compared to other polluted sites in the world and to locations in the same district. The mean ions concentrations (in μeq l?1) are: NO3 ? (243) > SO4 2? (220) > PO4 3? (176) > Cl? (153) > NO2 ? (29) > F? (2.6); NH4 + (504) > Ca2+ (489) > K+ (151) > Na+ (127) > Mg2+ (127). pH data shows a trend toward slightly alkaline conditions attributed to the large presence of ammonium and crustal elements, in spite of high concentrations of nitrates and sulphates. The relevant concentrations of Ca2+ and Mg2+ further suggests that these alkaline conditions might be due to the correspondingly significant concentrations of carbonates/bicarbonates in our dataset. While back-trajectories analysis suggests the stronger importance of local resuspension over long-range transport, statistical analyses on ion composition highlight the key role exerted by agricultural activity, especially in the case of NH4 +, K+, Ca2+ and PO4 3? (especially linked to fertilisation practices and soil resuspension due to mechanical operations). Apart from Na+ and Cl? ions which correlate well as expected, indicating their likely common origin from marine salt, the identification of the origin of the other ions is very complex due to the contribution of diverse local sources, such as industrial and residential settlements.  相似文献   
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Road building in Congo Basin forests has increased due to expansion of commercial logging, with potential to expose intact forests to greater establishment of agriculture. We developed new knowledge of agriculture clearing sizes, spatial patterns, and relationships with roads in seven case study sites comprising 7,529 km2. Using very high spatial resolution satellite imagery, we mapped roads and rivers, plus clearings for agriculture, settlements, and logging. Mapped clearings (N = 1,781) ranged in size from 0.008 ha to more than 300 ha; most were smallholder agriculture, with 64 percent ≤ 1 ha. Statistical tests of spatial pattern confirmed that agriculture occurred in an inhomogeneous-aggregated pattern, suggesting interactions with other landscape elements. Proximity analyses showed that 76 percent of clearings were within 1 km of a road or river. Thirty-five percent of agriculture clearings were within 1 km of main public roads built before 1990, compared to 17 percent for logging roads built after 2000. Less than 6 percent of agriculture clearings were within 1 km of logging roads with overgrown canopies, suggesting transient relationships. Results based on fine-scale data provide new empirical support for understanding the interactions between agriculture and roads in one of the remaining relatively intact forest areas of the Congo Basin.  相似文献   
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Coastal ocean primary productivity is often limited by nitrogen (N) availability, which is determined by the balance between N sources (e.g., N-fixation, groundwater, river inputs, etc.) and sinks (e.g., denitrification, sediment burial, etc.). Historically, heterotrophic N-fixation in sediments was excluded as a significant source of N in estuarine budgets, based on low, indirectly measured rates (e.g., acetylene reduction assay) and because it was unnecessary to achieve mass balance. Many recent studies using net N2 flux measurements have shown that sediment N-fixation can equal or exceed N2 loss. In an effort to quantify N2 production and consumption simultaneously, we measured N-fixation and denitrification directly in sediment cores from a temperate estuary (Waquoit Bay, MA). N-fixation, dissimilatory nitrate reduction to ammonium, and denitrification occurred simultaneously, and the net N2 flux shifted from uptake (N-fixation) to efflux (denitrification) over the 120-h incubation. Evidence for N-fixation included net 28N2 and 30N2 uptake, 15NH4 + production from 30N2 additions, 15Norganic matter production, and nifH expression. N-fixation from 30N2 was up to eight times higher than potential denitrification. However, N-fixation calculated from 15NO3 ? was one half of the measured fixation from 30N2, indicating that 15NO3-isotope labeling calculations may underestimate N-fixation. These results highlight the dynamic nature of sediment N cycling and suggest that quantifying individual processes allows a greater understanding of what net N2 fluxes signify and how that balance varies over time.  相似文献   
260.
Intense natural pollution has occurred in the past in Italy corresponding to intense volcanic activity, which appears to have diminished somewhat in recent times. Between 1500 and 1900, Etna, Vesuvius, Vulcano and Stromboli, plus volcanoes outside Italy were very active and there are numerous, well documented episodes of atmospheric acidification which caused widespread damage, especially to the vegetation. Other than the acid rains, volcanic emissions also caused so calleddry fogs which consist of a more or less dense mist composed of foul smelling gases and aerosols, characterized by a reddish color, that could appear and persist when the relative humidity was low as shown by measurements taken on such occasions. This phenomenon appeared most frequently at the beginning of the hot season. In fact, volcanic clouds of gases and aerosols formed especially when the Tyrrhenian sea water was relatively cold giving rise to very stable atmospheric conditions locally and the summer anticyclone meant that the winds were calm. Under such conditions the emissions of Stromboli and Vulcano, especially those emitted at low levels, remained entrapped in the stable layer, which were then transported towards the land reaching Northern Italy at a distance on the order of 103 km. Thedry fogs could persist for days or weeks. Harvests were seriously damaged and frequently the crops were subsequently attacked by parasites. The leaves of the vegetation became discoloured with numerous punctiform lesions or gangrene at the edges of the leaves. The phenomenon was so frequent that, in texts on agricultural meteorology of the 1800s, a distinction was made between the causticdry fogs which damaged the vegetation anddamp fogs which instead were good for it. The most important episode occurred in 1783 due to the activity of Laki Grímsvötn (Iceland) with the contribution of Italian volcanoes. This dry fog lasted many months and affected the greater part of the northern hemisphere including Europe and Asia, harming people, animals and vegetation. Apart from paroxysmal cases, from the 1300s up to today, some tens ofdry fogs have been noted, all of which have been sufficiently well documented. The frequency of these events culminated between the middle of the 1700s and the middle of the 1800s. There is reason to believe that this well documented phenomenon of the past, with sufficient volcanic activity, could recur on the meso and large scale; with present day activity the emissions continue to cause damage to vegetation, both in the Aspromonte mountains (Calabria, Southem Italy) as well as in other parts of Italy.  相似文献   
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