Determination of the Concentration of Carbonic Species in Natural Waters: Results from a World‐Wide Proficiency Test          下载免费PDF全文

Mahendra P. Verma  Enrique Portugal  Sophie Gangloff  María Aurora Armienta  Dornadula Chandrasekharam  Mayela Sanchez  Roberto E. Renderos  Miguel Juanco  Robert van Geldern 《Geostandards and Geoanalytical Research》2015,39(2):233-255

The results of an international interlaboratory proficiency test for the determination of carbonic species are presented. Eight laboratories analysed twelve water samples (four synthetic waters, one lake water, four geothermal waters, one seawater and two petroleum waters) by two methods: (a) individual laboratory analytical procedure and (b) acid–base titration curves in tabular form following a standardised protocol. In case (b), the concentrations of carbonic species were calculated by the organiser using the (1) Hydrologists' method, (2) Geochemists' method and/or (3) initial pH and total alkalinity method. For synthetic waters, the averaged % trueness and precision of measurement of the two methods were (trueness = 7.6, precision = 9.4) and (9.0, 3.4) for total alkalinity, and (6.6, 31.0) and (7.8, 6.1) for carbonic alkalinity, respectively. This indicates that the total alkalinity calculation procedure is in general correct in the individual laboratory method, but the carbonic alkalinity calculation procedure has serious problems. The measurements of total alkalinity for lake and seawaters were in agreement in both the methods; however, the individual laboratory measurement method for geothermal and petroleum waters was conceptually incorrect. Thus, the analytical procedures for the determination of carbonic species were reviewed. To apply the Hydrologists' and/or Geochemists' methods, the location of NaHCO₃EP and H₂CO₃EP is necessary, even for samples with pH lower than that of NaHCO₃EP, and a backward titration curve after complete removal of CO₂ must be performed. The initial pH and total alkalinity method is appropriate where a complete analysis of species that contribute to the alkalinity is known.  相似文献   

Soil moisture-temperature feedbacks at meso-scale during summer heat waves over Western Europe     

Marc Stéfanon  Philippe Drobinski  Fabio D’Andrea  Cindy Lebeaupin-Brossier  Sophie Bastin 《Climate Dynamics》2014,42(5-6):1309-1324

This paper investigates the impact of soil moisture-temperature feedback during heatwaves occurring over France between 1989 and 2008. Two simulations of the weather research and forecasting regional model have been analysed, with two different land-surface models. One resolves the hydrology and is able to simulate summer dryness, while the other prescribes constant and high soil moisture and hence no soil moisture deficit. The sensitivity analysis conducted for all heatwave episodes highlights different soil moisture-temperature responses (1) over low-elevation plains, (2) over mountains and (3) over coastal regions. In the plains, soil moisture deficit induces less evapotranspiration and higher sensible heat flux. This has the effect of heating the planetary boundary layer and at the same time of creating a general condition of higher convective instability and a slight increase of shallow cloud cover. A positive feedback is created which increases the temperature anomaly during the heatwaves. In mountainous regions, enhanced heat fluxes over dry soil reinforce upslope winds producing strong vertical motion over the mountain slope, first triggered by thermal convection. This, jointly to the instability conditions, favors convection triggering and produces clouds and precipitation over the mountains, reducing the temperature anomaly. In coastal regions, dry soil enhances land/sea thermal contrast, strengthening sea-breeze circulation and moist cold marine air advection. This damps the magnitude of the heatwave temperature anomaly in coastal areas, expecially near the Mediterranean coast. Hence, along with heating in the plains, soil dryness can also have a significant cooling effect over mountains and coastal regions due to meso-scale circulations.  相似文献   

Dynamical downscaling of IPSL-CM5 CMIP5 historical simulations over the Mediterranean: benefits on the representation of regional surface winds and cyclogenesis   总被引：1，自引：1，他引：0  

Emmanouil Flaounas  Philippe Drobinski  Sophie Bastin 《Climate Dynamics》2013,40(9-10):2497-2513

The Mediterranean region is identified as one of the two main hot-spots of climate change and also known to have the highest concentration of cyclones in the world. These atmospheric features contribute significantly to the regional climate but they are not reproduced by the Atmosphere–Ocean General Circulation Models (AOGCM), due to their coarse horizontal resolution, which have recently been run in the frame of the 5th Climate Model Intercomparison Project. This article investigates the benefit of dynamically downscaling the Institut Pierre Simon Laplace (IPSL) AOGCM (IPSL-CM5) historical simulation by the weather and research forecasting (WRF) for the representation of the Mediterranean surface winds and cyclonic activity. Indeed, when considering IPSL-CM5 atmospheric fields, the dramatic underestimation of the cyclonic activity in the most cyclogenetic region of the world jeopardizes our ability to investigate in-depth the Mediterranean regional climate and trend in the context of global change. The WRF model shows remarkable skill to reproduce regional cyclogenesis. Indeed, cyclones occurrence is quasi-absent in IPSL-CM5 data but when applying dynamical downscaling their spatial–temporal variability is very close to the re-analysis. This is a clear benefit of dynamical downscaling in regions of strong topographic forcing. This “steady” source of forcing allows the production of lee cyclogenesis and the development of strong cyclones, whatever the quality of the large-scale circulation provided at the WRF’s boundaries by IPSL-CM5. However, dynamical downscaling still presents disadvantages as for instance the fact that large-scale inaccurate features of the IPSL-CM5 regional circulation are replicated by WRF due to the boundary controlled (small domain) simulation. The advantages and disadvantages of dynamical downscaling are thoroughly discussed in this paper revealing its importance for climate research, especially in the context of future scenarios and wind impacts.  相似文献   

Aerosol and ozone changes as forcing for climate evolution between 1850 and 2100   总被引：2，自引：0，他引：2  

Sophie Szopa  Y. Balkanski  M. Schulz  S. Bekki  D. Cugnet  A. Fortems-Cheiney  S. Turquety  A. Cozic  C. Déandreis  D. Hauglustaine  A. Idelkadi  J. Lathière  F. Lefevre  M. Marchand  R. Vuolo  N. Yan  J.-L. Dufresne 《Climate Dynamics》2013,40(9-10):2223-2250

Global aerosol and ozone distributions and their associated radiative forcings were simulated between 1850 and 2100 following a recent historical emission dataset and under the representative concentration pathways (RCP) for the future. These simulations were used in an Earth System Model to account for the changes in both radiatively and chemically active compounds, when simulating the climate evolution. The past negative stratospheric ozone trends result in a negative climate forcing culminating at ?0.15 W m^?2 in the 1990s. In the meantime, the tropospheric ozone burden increase generates a positive climate forcing peaking at 0.41 W m^?2. The future evolution of ozone strongly depends on the RCP scenario considered. In RCP4.5 and RCP6.0, the evolution of both stratospheric and tropospheric ozone generate relatively weak radiative forcing changes until 2060–2070 followed by a relative 30 % decrease in radiative forcing by 2100. In contrast, RCP8.5 and RCP2.6 model projections exhibit strongly different ozone radiative forcing trajectories. In the RCP2.6 scenario, both effects (stratospheric ozone, a negative forcing, and tropospheric ozone, a positive forcing) decline towards 1950s values while they both get stronger in the RCP8.5 scenario. Over the twentieth century, the evolution of the total aerosol burden is characterized by a strong increase after World War II until the middle of the 1980s followed by a stabilization during the last decade due to the strong decrease in sulfates in OECD countries since the 1970s. The cooling effects reach their maximal values in 1980, with ?0.34 and ?0.28 W m^?2 respectively for direct and indirect total radiative forcings. According to the RCP scenarios, the aerosol content, after peaking around 2010, is projected to decline strongly and monotonically during the twenty-first century for the RCP8.5, 4.5 and 2.6 scenarios. While for RCP6.0 the decline occurs later, after peaking around 2050. As a consequence the relative importance of the total cooling effect of aerosols becomes weaker throughout the twenty-first century compared with the positive forcing of greenhouse gases. Nevertheless, both surface ozone and aerosol content show very different regional features depending on the future scenario considered. Hence, in 2050, surface ozone changes vary between ?12 and +12 ppbv over Asia depending on the RCP projection, whereas the regional direct aerosol radiative forcing can locally exceed ?3 W m^?2.  相似文献   

Late Pleistocene (MIS 3–4) climate inferred from micromammal communities and δO of rodents from Les Pradelles,France     

Aurélien Royer  Christophe Lécuyer  Sophie Montuire  Gilles Escarguel  François Fourel  Alan Mann  Bruno Maureille 《Quaternary Research》2013

The middle Paleolithic stratigraphic sequence of Les Pradelles (Charente, France) spans from the end of Marine Isotope Stage (MIS) 4 until the middle of MIS 3. Micromammal remains are present in all the stratigraphic levels, offering a rare opportunity to address the questions of both environmental and climatic fluctuations throughout this period. Climate modes were studied through the taphonomy, biodiversity and oxygen isotope compositions of phosphate (δ¹⁸O_p) from 66 samples of rodent tooth enamel. The δ¹⁸O_p values from the lower sedimentary levels provide summer mean air temperatures of 19 ± 2°C (level 2/1) and of 16 ± 2°C (levels 2A, 2B and 4A). Within the middle of sequence (level 4B), a paleobiodiversity change can be identified with an increase of Dicrostonyx torquatus, which is associated with the largest amplitude in δ¹⁸O_p values and the highest maximal δ¹⁸O_p values. At the top of the sequence (level 5-2), a biodiversity change is observed with the increase of Microtus arvalis, but without any change in δ¹⁸O_p values. The association of cold rodent species with unexpected high and large amplitudes in the δ¹⁸O_p values of their teeth, possibly indicative of aridity, suggests their deposition during a Heinrich event.  相似文献   

TESSIN VISLab—laboratory for scientific visualization     

Lars Bilke  Thomas Fischer  Carolin Helbig  Charlotte Krawczyk  Thomas Nagel  Dmitri Naumov  Sebastian Paulick  Karsten Rink  Agnes Sachse  Sophie Schelenz  Marc Walther  Norihiro Watanabe  Björn Zehner  Jennifer Ziesch  Olaf Kolditz 《Environmental Earth Sciences》2014,72(10):3881-3899

Scientific visualization is an integral part of the modeling workflow, enabling researchers to understand complex or large data sets and simulation results. A high-resolution stereoscopic virtual reality (VR) environment further enhances the possibilities of visualization. Such an environment also allows collaboration in work groups including people of different backgrounds and to present results of research projects to stakeholders or the public. The requirements for the computing equipment driving the VR environment demand specialized software applications which can be run in a parallel fashion on a set of interconnected machines. Another challenge is to devise a useful data workflow from source data sets onto the display system. Therefore, we develop software applications like the OpenGeoSys Data Explorer, custom data conversion tools for established visualization packages such as ParaView and Visualization Toolkit as well as presentation and interaction techniques for 3D applications like Unity. We demonstrate our workflow by presenting visualization results for case studies from a broad range of applications. An outlook on how visualization techniques can be deeply integrated into the simulation process is given and future technical improvements such as a simplified hardware setup are outlined.  相似文献   

How basin model results enable the study of multi-layer aquifer response to pumping: the Paris Basin, France     

Camille Contoux  Sophie Violette  Raffaella Vivona  Patrick Goblet  Delphine Patriarche 《Hydrogeology Journal》2013,21(3):545-557

The Albian aquifer of the Paris Basin (France) has been exploited since 1841 and shows drastic drawdown. A three-dimensional (3D) groundwater flow model is used to study the hydrodynamic response of the multi-layered aquifers to pumping activity in the Albian, at basin scale over 167 years. This 3D flow model uses geometry and hydrodynamic parameter distributions that are inherited from a genetic approach through basin modelling, the basin model creating a geometric pattern of hydrodynamic properties constrained by geological history. The paper aims to promote the use of the basin model approach (long time scale, 248 Ma) for the study of deep-aquifer response to anthropogenic perturbation (short time scale, 167 years) in situations for which hydrodynamic data are scarce but geological data are numerous. The results show that parameter distribution is insufficient to reproduce the Albian aquifer behaviour, notably highlighting a different meaning of the specific storage coefficient between basin modelling and groundwater-flow modelling. Dividing the storage coefficient by 100 and including available transmissivity data significantly improved the model/data comparison. The potential impact on a deep aquitard is then discussed. This study sheds light on the advantages and limitations of the basin model approach for groundwater-flow modelling in 3D.  相似文献   

Antenna-coupled arrays of NbSi micro-bolometers     

Aur��lien Bideaud  Benoit Belier  Alain Benoit  Laurent Berg��  Philippe Camus  Sophie Collin  Louis Dumoulin  Christian Hoffmann  Stefanos Marnieros  Alessandro Monfardini 《Experimental Astronomy》2011,32(2):179-191

Microbolometers are at present the most sensitive detectors for mm and sub-mm Astronomy. They are in use in most of the present instruments in that bandwidth. We have developed filled arrays of NbSi-based planar antenna coupled microbolometers. The fabrication details are given, together with characterization of the NbSi thermometers and optical results. The optical performances are potentially good for ground-based mm-wave astronomy applications, while the overall detectors performances are limited by low-frequency excess noise in the thermometric NbSi high-impedance sensors (Anderson insulator).  相似文献   

Analytical solutions for co- and counter-current imbibition of sorbing, dispersive solutes in immiscible two-phase flow     

Karen Sophie Schmid  Sebastian Geiger  Kenneth Stuart Sorbie 《Computational Geosciences》2012,16(2):351-366

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A kernel spatial density estimation allowing for the analysis of spatial clustering. Application to Monsoon Asia Drought Atlas data     

Sophie Dabo-Niang  Leila Hamdad  Camille Ternynck  Anne-Françoise Yao 《Stochastic Environmental Research and Risk Assessment (SERRA)》2014,28(8):2075-2099

A nonparametric density estimate that incorporates spatial dependency has not been studied in the literature. In this article, we propose a new spatial density estimator that depends on two kernels: one controls the distance between observations while the other controls the spatial dependence structure. The uniform almost sure convergence of the density estimate is established with the rate of convergence. The consistency of the mode of this kernel density is also studied. Then a spatial hierarchical unsupervised clustering algorithm based on the mode estimate is presented. Some simulations as well as an application to the Monsoon Asia Drought Atlas data illustrate the efficiency of our algorithm, and a comparison of the spatial structures of these data detected by the density estimate and clustering algorithm are done.  相似文献