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61.
ABSTRACT

Selecting the best structure and parameterization of rainfall–runoff models is not straightforward and depends on a broad number of factors. In this study, the “Modello Idrologico Semi-Distribuito in continuo” (MISDc) was tested on 63 mountainous catchments in the western Po Valley (Italy) and the optimal model parameters were regionalized using different strategies. The model performance was evaluated through several indexes analysing hydrological regime, high-flow condition and flow–duration curve (FDC). In general, MISDc provides a good fit behaviour with a Kling-Gupta Efficiency index greater than 0.5 for 100% and 84% of cases for calibration and validation, respectively. Concerning the regionalization, spatial proximity approach is the most accurate solution obtaining satisfactory performance. Lastly, the predicted FDCs showed an excellent similarity with the observed ones. Results encourage to apply MISDc over the study area for flood forecasting and for assessing water resources availability thanks to the modest computational efforts and data requirements.  相似文献   
62.
The spatial and temporal distribution of humic substances in aquatic ecosystems can have important effects on ecosystem productivity, negatively impacting primary productivity while positively impacting secondary productivity. In the present investigation, a large shallow lake ecosystem was studied to determine the spatial and seasonal variation of the composition and concentration of humic substances. Concentrations of total dissolved organic matter, humic acid, and fulvic acid were found to display significant spatial distributions (1.3…13.5 mg/L, DOM; 0.1…5.4 mg/L, HA). The distribution is described by using mapping techniques and the analysis of the spatial distribution of the lake. An analysis of the seasonal variations also indicated the dependence of the occurrence of these compounds on meteorological and hydrological conditions. To identify the potential sources of these organic materials, an analysis was made of the ratio of humic and fulvic acid fractions and total DOM. It was found that areas of high DOM concentration coincided with the areas of highest HA percentage of total DOM. Furthermore using the ratio of the normalised concentrations of HA, FA, and residual DOM (< 5000 g/mol) it was found that areas dominated by each are spatially distinct. This confirms the hypothesis that in these shallow lakes, photodegradation and bacterioplankton activity will create a residence time dependent zonation of each component of the total DOM.  相似文献   
63.
Agricultural coastal areas are frequently affected by the superimposition of various processes, with a combination of anthropogenic and natural sources, which degrade groundwater quality. In the coastal multi-aquifer system of Arborea (Italy)—a reclaimed morass area identified as a nitrate vulnerable zone, according to Nitrate Directive 91/676/EEC—intensive agricultural and livestock activities contribute to substantial nitrate contamination. For this reason, the area can be considered a bench test for tuning an appropriate methodology aiming to trace the nitrate contamination in different conditions. An approach combining environmental isotopes, water quality and hydrogeological indicators was therefore used to understand the origins and attenuation mechanisms of nitrate pollution and to define the relationship between contaminant and groundwater flow dynamics through the multi-aquifer characterized by sandy (SHU), alluvial (AHU), and volcanic hydrogeological (VHU) units. Various groundwater chemical pathways were consistent with both different nitrogen sources and groundwater dynamics. Isotope composition suggests a mixed source for nitrate (organic and synthetic fertilizer), especially for the AHU and SHU groundwater. Moreover, marked heterotrophic denitrification and sulfate reduction processes were detected; although, for the contamination related to synthetic fertilizer, the attenuation was inefficient at removing NO3? to less than the human consumption threshold of 50 mg/L. Various factors contributed to control the distribution of the redox processes, such as the availability of carbon sources (organic fertilizer and the presence of lagoon-deposited aquitards), well depth, and groundwater flow paths. The characterization of these processes supports water-resource management plans, future actions, and regulations, particularly in nitrate vulnerable zones.  相似文献   
64.
Susceptibility of intrusion-related landslides in an active volcano was evaluated coupling the landslide susceptibility estimation by random forest (RF), and the probabilistic volcanic vent opening distribution, as proxy for magma injection, using the QVAST tool. In order to develop and test the method proposed here, the RF/QVAST approach was adopted for Stromboli volcano (Southern Italy) since it experienced moderate to huge instability events, it is geomorphologically prone to instability events, and it is affected by active intense volcanic activity that can produce slope instability. The main destabilizing factors of the volcanic flanks are the slope, the aspect, the terrain roughness, the land cover and the litho-technical features of the outcropping rocks. Estimation of volcanic susceptibility shows that the areas with high probability of new vent opening are located in the north-western unstable volcano flank (Sciara del Fuoco), in the volcano summit and the north-eastern volcano flank coherent with the possible re-activation of the eruptive fissures related to the regional tectonic setting. The areas with higher probability of intrusion-related landslides are located in the upper part of the Sciara del Fuoco, while the rest of the island show moderate to low probability of intrusion-related landslide occurrence.  相似文献   
65.
Rip currents are fast moving, offshore flows that have the ability to move even the strongest swimmers into deeper waters. Miami Beach, Florida is one of the most visited beaches in the USA and a sought after destination for citizens and international tourists alike. It is also known to be a rip current “hot spot.” These factors greatly increase the risk of drowning; however, no previous research has focused on beachgoer perception of rip-related risks in South Florida. Over a 12-month period, 203 public surveys were collected to determine the rip current knowledge of beachgoers at Miami Beach based on factors such as swimming ability and frequency of beach visits. The responses were analyzed by constructing a normalized component factor to determine the respondent’s comprehensive knowledge of rips, and multiple regression models were used to assess the net influences of sociodemographic and behavioral characteristics on the responses. A significant proportion of the survey respondents showed insufficient knowledge, indicating they are at risk of drowning in a rip current. Frequent beachgoer’s exposure to the beach environment, maturation, and nativity is identified as the main contributors to knowledge net of other sociodemographic compositions. The most at-risk groups were determined to be young adults, foreign tourists, poor swimmers, and those who infrequently visited the beach. Miami Beach needs to initiate a rip current safety campaign to target these at-risk beachgoers, where interventions beyond familial and educational institutions should be introduced.  相似文献   
66.
Although elasmobranchs are widely distributed species, commonly found on sandy, gravely or muddy bottoms, several biological aspects of their metabolism still remain poorly investigated. In this work the efficiency of antioxidant system and detoxification enzymes were investigated in the coastal spotted dogfish Scyliorhinus canicula and in the red mullet Mullus barbatus for comparison with a teleost species.Organisms were sampled during a bottom trawl survey and analyzed for the biotransformation activity (EROD), levels of metallothioneins, catalase, glutathione S-transferases and total oxyradical scavenging capacity (TOSC) toward peroxyl radicals and hydroxyl radicals.EROD activity in the elasmobranchs was more than one order of magnitude lower than in the red mullets, while similar levels of metallothioneins were measured in these species. S. canicula showed significantly lower antioxidant enzymes and a more reduced efficiency in neutralizing OH; on the other hand the scavenging capability toward ROO was comparable in S. canicula and M. barbatus.  相似文献   
67.
Induction of cytochrome P4501A in fish is a well-known indicator of exposure to polycyclic aromatic hydrocarbons (PAHs) and determination of PAH metabolites in bile by fixed wavelength fluorescence (FF) or synchronous fluorescence spectroscopy (SFS), has become an useful method in monitoring programs. In this work the relationship between cytochrome P4501A (EROD activity) and levels of biliary PAH metabolites was measured in the European eel Anguilla anguilla, in both field and laboratory conditions: organisms were sampled on a seasonal basis from the Orbetello lagoon (Tuscany) to characterize the natural variability of these biological parameters, while in laboratory eels were intraperitoneally injected with benzo[a]pyrene to investigate temporal and dose-dependent induction patterns. Results showed that induction of cytochrome P450 and accumulation of PAHs metabolites in bile are not necessarily correlated either in field, or in laboratory investigations; different seasonal changes were measured in natural conditions and slight variations in dose and time response patterns were also obtained in laboratory exposures.  相似文献   
68.
A survey of the literature reveals that the title problem has not been previously solved. The fundamentals frequency of transverse vibration of the orthotropic structural element is determined by expanding the displacement amplitude function in terms of simple polynomial coordinate functions which satisfy identically the essential boundary conditions and approximately some of the natural edge requirements.The Ritz method is then used to generate the frequency equations.  相似文献   
69.
Induction of cytochrome P4501A in fish is a well-known indicator of exposure to polycyclic aromatic hydrocarbons (PAHs) and determination of PAH metabolites in bile by fixed wavelength fluorescence (FF) or synchronous fluorescence spectroscopy (SFS), has become an useful method in monitoring programs. In this work the relationship between cytochrome P4501A (EROD activity) and levels of biliary PAH metabolites was measured in the European eel Anguilla anguilla, in both field and laboratory conditions: organisms were sampled on a seasonal basis from the Orbetello lagoon (Tuscany) to characterize the natural variability of these biological parameters, while in laboratory eels were intraperitoneally injected with benzo[a]pyrene to investigate temporal and dose-dependent induction patterns. Results showed that induction of cytochrome P450 and accumulation of PAHs metabolites in bile are not necessarily correlated either in field, or in laboratory investigations; different seasonal changes were measured in natural conditions and slight variations in dose and time response patterns were also obtained in laboratory exposures.  相似文献   
70.
The present paper deals with an analytical and experimental investigation of the title problem when a concentrated mass is rigidly attached to the plate. Very simple yet quite accurate engineering frequency equations are derived.  相似文献   
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