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41.
The spatio-temporal variability of submesoscale eddies off southern San Diego is investigated with two-year observations of subinertial surface currents [O(1) m depth] derived from shore-based high-frequency radars. The kinematic and dynamic quantities — velocity potential, stream function, divergence, vorticity, and deformation rates — are directly estimated from radial velocity maps using optimal interpolation. For eddy detection, the winding-angle approach based on flow geometry is applied to the calculated stream function. A cluster of nearly enclosed streamlines with persistent vorticity in time is identified as an eddy. About 700 eddies were detected for each rotation (clockwise and counter-clockwise). The two rotations show similar statistics with diameters in the range of 5–25 km and Rossby number of 0.2–2. They persist for 1–7 days with weak seasonality and migrate with a translation speed of 4–15 cm s−1 advected by background currents. The horizontal structure of eddies exhibits nearly symmetric tangential velocity with a maximum at the defined radius of the eddy, non-zero radial velocity due to background flows, and Gaussian vorticity with the highest value at the center. In contrast divergence has no consistent spatial shape. Two episodic events are presented with other in situ data (subsurface current and temperature profiles, and local winds) as an example of frontal-scale secondary circulation associated with drifting submesoscale eddies.  相似文献   
42.
This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO4 or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO4. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO4 and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.  相似文献   
43.
A variety of soft‐sediment deformation structures formed during or shortly after deposition occurs in the Cretaceous Seongpori and Dadaepo Formations of the southeastern Gyeongsang Basin exposed along coastal areas of southeastern Korean Peninsula for 0.5–2 km. These are mostly present in a fluvial plain facies, with interbedded lacustrine deposits. In this study, the features of different kinds of soft‐sediment deformation structures have been interpreted on the basis of sedimentology of structure‐bearing deposits, comparison with normal sedimentary structures, timing and mechanism of deformation, and triggering mechanisms. The soft‐sediment deformation structures can be classified into four morphological groups: (i) load structures (load casts, ball‐and‐pillow structures); (ii) soft‐sediment intrusive structures (dish‐and‐pillars, clastic dykes, sills); (iii) ductile disturbed structures (convolute folds, slump structures); and (iv) brittle deformation structures (syndepositional faulting, dislocated breccia). The most probable triggering mechanisms resulting in these structures were seismic shocks. These interpretations are based on the following field observations: (i) location of the study area within tectonically active fault zone reactivated several times during the Cretaceous; (ii) deformation structures confined to single stratigraphic levels; (iii) lateral continuity and occurrences of various soft‐sediment deformation structures in the deformed level over large areas; (iv) absence of depositional slope to indicate gravity sliding or slumping; and (v) similarity to the structures produced experimentally. The soft‐sediment deformation structures in the study areas are thus interpreted to have been generated by seismic shocks with an estimated magnitude of M > 5, representing an intermittent record of the active tectonic and sedimentary processes during the development and evolution of two formations from the late Early Cretaceous to the Late Cretaceous.  相似文献   
44.
Abstract

The Hulu Langat basin, a strategic watershed in Malaysia, has in recent decades been exposed to extensive changes in land-use and consequently hydrological conditions. In this work, the impact of Land Use and Cover Change (LUCC) on hydrological conditions (water discharge and sediment load) of the basin were investigated using the Soil and Water Assessment Tool (SWAT). Four land-use scenarios were defined for land-use change impact analysis, i.e. past, present (baseline), future and water conservation planning. The land-use maps, dated 1984, 1990, 1997 and 2002, were defined as the past scenarios for LUCC impact analysis. The present scenario was defined based on the 2006 land-use map. The 2020 land-use map was simulated using a cellular automata-Markov model and defined as the future scenario. Water conservation scenarios were produced based on guidelines published by Malaysia’s Department of Town and Country Planning and Department of Environment. Model calibration and uncertainty analysis was performed using the Sequential Uncertainty Fitting (SUFI-2) algorithm. The model robustness for water discharge simulation for the period 1997–2008 was good. However, due to uncertainties, mainly resulting from intense urban development in the basin, its robustness for sediment load simulation was only acceptable for the calibration period 1997–2004. The optimized model was run using different land-use maps over the periods 1997–2008 and 1997–2004 for water discharge and sediment load estimation, respectively. In comparison to the baseline scenario, SWAT simulation using the past and conservative scenarios showed significant reduction in monthly direct runoff and monthly sediment load, while SWAT simulation based on the future scenario showed significant increase in monthly direct runoff, monthly sediment load and groundwater recharge.
Editor D. Koutsoyiannis; Associate editor C. Perrin  相似文献   
45.
In order to understand sequence development and sea-level fluctuations during the late Middle Cambrian to early Furongian on the North China epeiric platform, the present study focuses on a unique, subtle erosion surface of an extensive (approx. 100 km), strongly deformed limestone bed in the uppermost part of the Gushan Formation, Shandong Province, China. The Gushan Formation and the overlying Chaomidian Formation consist mainly of shales and a variety of carbonates that were deposited in subtidal environments (e.g., deep subtidal, shallow subtidal, shoreface/shoal, subtidal microbial flat, and restricted platform interior). Three third-order depositional sequences (S1–3) are identified, each of which comprises a thin transgressive systems tract (TST) and a relatively thick highstand systems tract (HST). Each sequence is bounded by a drowning unconformity (SB1), a subaerial unconformity (SB2), or a surface of submarine erosion (SB3). The upper sequence boundary (SB2) of sequence 1 (S1) is represented by a subtle erosion surface of an extensive, deformed limestone bed with a wide variety of soft-sediment deformation structures (e.g., lime mudstone breccias, chaotic wacke-packstone laminae and fragments, homogenized oolites, and clastic dykes), and is overlain by small sporadic microbial buildups and an extensive bioclastic grainstone bed. The deformed limestone was formed during early diagenesis by differential deformation processes (brecciation, liquefaction/fluidization, and injection) which were most likely induced by pore-water overpressure during the period of rapid sea-level fall. Despite the lack of subaerial exposure features (e.g., paleokarst, paleosol, etc.), the characteristics of the erosion surface (cutting well-lithified sediment below), the missing of a significant geological record (the Prochuangia biozone), and the worldwide correlatable positive carbon isotope excursion collectively indicate that the erosion surface developed under conditions of subaerial exposure after contemporaneous marine cementation of the deformed sediment. The missing of the Prochuangia biozone is most likely due to non-deposition at a subaerial hiatal surface. The erosion surface was submerged as a result of subsequent rise in sea level, where sporadic microbial buildups formed under suitable conditions. Freshly deposited, winnowed, shell-dominated transgressive lag deposits (containing Chuangia trilobite fragments, brachiopod shells, and abundant glauconite grains) formed with continued rise in sea level, which became, in turn, overlain by shale-dominated facies. The unique combination of the subtle erosion surface (sensu stricto a subaerial unconformity) and the underlying deformed limestone bed provides an important criterion for recognizing the subtle changes in relative sea level on shallow epeiric platforms.  相似文献   
46.
This study presents an example of locating Cambrian–Ordovician boundary in the lower Paleozoic carbonate succession in Korea using carbon isotope stratigraphy. The Yeongweol Unit of the lower Paleozoic Joseon Supergroup comprises the Upper Cambrian Wagok Formation and the Lower Ordovician Mungok Formation in the Cambrian–Ordovician transition interval. Conventionally, the boundary was placed at the lithostratigraphic boundary between the two formations. This study reveals that the boundary is positioned in the basal part of the Mungok Formation based on the carbon isotope stratigraphy coupled with biostratigraphic information of conodont and trilobite faunas. The δ13C curve of the Lower Ordovician Mungok Formation shows a similar trend to that of the coeval stratigraphic interval of Argentine Precordillera (Buggisch et al., 2003), suggesting that the δ13C curve of the Mungok Formation reflects the Early Ordovician global carbon cycle.  相似文献   
47.
This study presents the Bottom-hole pressure (BHP) behavior with different wettabilities and the optimal design scheme to effectively inject CO2 into the Gorae-V aquifer. As a result, the injection rate and injectivity were increased as the wettability condition became more water-wet. However, the more wettability condition becomes water-wet, the more the ultimate CO2 injection volume decreases. When the injectivity was 346 ton/day/Mpa at the Gorae-V aquifer, the aquifer can sustain CO2 injection at a rate of 2,425 tons per day over this time period. A design for a complete CCS system was developed based on the existing off-shore pipeline in combination with new on-shore CO2 transport infrastructure, and a pressure of 12.8 MPa is required at the CO2 source to maintain this injection rate.  相似文献   
48.
In order to investigate surf zone hydrodynamics through two-dimensional numerical simulations of nearshore circulation under random wave environment, a nearshore circulation model, SHORECIRC, and a random wave model, SWAN, were combined and utilized. Using this combined model, a numerical simulation of the October 2, 1997 SandyDuck field experiment was performed. For this simulation, field topography and an input offshore spectrum were constructed using observed data sets synchronized with the experiment. The wave-breaking model in SWAN was modified by using breaker parameters varied according to bottom slope. The simulation results were compared with the experimental data, which revealed a well-developed longshore current, as well as with results using other combinations which were SHORECIRC and its original monochromatic wave-driver, and SHORECIRC and the default of SWAN. The results from the novel combined model agreed well with the experimental data. The results of the present simulation also indicate that alongshore field topography influences shear fluctuation of longshore currents.  相似文献   
49.
Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.  相似文献   
50.
We present absorption cross sections of propane (C3H8) at temperatures from 145 K to 297 K in the 690–1550 cm−1 region. Pure and N2-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm−1, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm−1 region was determined to be 52.93 (±3%) × 10−19 cm−1/(molecule cm−2) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C3H8 pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo).  相似文献   
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