The South Atlantic dipole and variations in the characteristics of the South American Monsoon in the WCRP-CMIP3 multi-model simulations   总被引：1，自引：1，他引：0  

Rodrigo J. Bombardi  Leila M. V. Carvalho 《Climate Dynamics》2011,36(11-12):2091-2102

This study investigates relationships between Atlantic sea surface temperature (SST) and the variability of the characteristics of the South American Monsoon System (SAMS), such as the onset dates and total precipitation over central eastern Brazil. The observed onset and total summer monsoon precipitation are estimated for the period 1979?C2007. SST patterns are obtained from the Empirical Orthogonal Function. It is shown that variations in SST on interannual timescales over the South Atlantic Ocean play an important role in the total summer monsoon precipitation. Negative (positive) SST anomalies over the topical South Atlantic along with positive (negative) SST anomalies over the extratropical South Atlantic are associated with early (late) onsets and wet (dry) summers over southeastern Brazil and late (early) onset and dry (wet) summers over northeastern Brazil. Simulations from Phase 3 of the World Climate Research Programme Coupled Model Intercomparison Project (CMIP-3) are assessed for the 20th century climate scenario (1971?C2000). Most CMIP3 coupled models reproduce the main modes of variability of the South Atlantic Ocean. GFDL2.0 and MIROC-M are the models that best represent the SST variability over the South Atlantic. On the other hand, these models do not succeed in representing the relationship between SST and SAMS variability.  相似文献   

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors     

Alfredo Gallego  Virginia L. Gemini  Susana L. Rossi  Carlos E. Gómez  Gustavo D. Bulus Rossini  Sonia E. Korol 《洁净——土壤、空气、水》2011,39(8):774-780

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.  相似文献   

Distribution of metals in soils and plants around mineralized zones at Cartagena-La Unión mining district (SE,Spain)   总被引：1，自引：1，他引：0  

O. Gonzalez-Fernandez  I. Queralt  J. I. Manteca  G. Garcia  M. L. Carvalho 《Environmental Earth Sciences》2011,63(6):1227-1237

A geochemical and mineralogical characterization of three zones (namely oxides zones, hydrothermal alteration zone and mining wastes zone) from a mineralized zone in the upper part of the Cartagena-La Unión range was carried out by analysing rocks, soils and three plant species (Piptatherum miliaceum, Ditrichia viscosa and Hirsfeldia incana). The transference and bioavailability of some metals (especially Pb, Zn, As and Fe) from soils to plants was also checked. Results show that rocks have a large content of Fe and Pb which are transferred to surrounding soils also highly enriched in these elements (Fe ranges from 9 to 35% and Pb 1 to 2.9%). Regarding soil to plant transfer, it was shown a differential behaviour for both the three plant species and the soil zones, with a higher level of metal accumulation rates for Piptatherum miliaceum in the hydrothermal alteration zone. Values of accumulation rates obtained for Pb in Piptatherum miliaceum allow considering it a good choice for phytoremediation purposes.  相似文献   

Chemistry of the Ferraria thermal water, S. Miguel Island, Azores: mixing and precipitation processes   总被引：1，自引：1，他引：0  

Maria do Rosário Carvalho  António Mateus  Jo?o C. Nunes  José M. Carvalho 《Environmental Earth Sciences》2011,64(2):539-547

The Ferraria thermal water emerges at the sea level in the Ferraria lava delta (western edge of S. Miguel Island, Azores) with temperature of ca. 60°C and pH varying between 5.4 and 6.2. It is of sodium chloride type, resulting from ca. 50% seawater mixing with an acid brackish, at ≈100°C, denoting the presence of significant CO₂(g) and the progress of water–rock interactions in open system conditions. The thermal Na–Cl water is strongly enriched with Sr and Mn and, comparatively, has low concentrations in Al, Fe and As. These elements are removed from the solution as critical conditions for the formation of several neo-formed mineral phases are gradually attained. Thermodynamic equilibrium calculations are consistent with this interpretation, showing that the thermal fluid can precipitate Fe³⁺-(hydr-)oxides, kaolinite and non-crystalline silica. Wells logging show fracture planes and pores fully/partly filled up with polyphase botryoidal aggregates mostly composed of goethite + ferrihydrite and displaying variable adsorbed contents of Si, P and As. These neo-formed phases result from the pristine fluid oxidation due to seawater mixing; its precipitation is easily affected by pH and redox variations of the brackish, due to volcanic gases pressure alterations, and fluid pressure or flow-velocity oscillation in the fractured aquifer.  相似文献   

Geochemistry of granites and metasediments of the urban area of Vila Real (northern Portugal) and correlative radon risk   总被引：2，自引：2，他引：0  

M. E. P. Gomes  L. J. P. F. Neves  F. Coelho  A. Carvalho  M. Sousa  A. J. S. C. Pereira 《Environmental Earth Sciences》2011,64(2):497-502

Radon concentration was evaluated in dwellings of the urban area of Vila Real (Northern Portugal). The area is mainly composed of Hercynian granites and Cambrian metasediments, and CR-39 passive detectors (n = 112) were used for the purpose. The results obtained in winter conditions suggest that the most productive geological unit is the Hercynian granite G1 (geometric mean of 364 Bq/m³), while Cambrian metasediments of the Douro Group show the lowest average indoor radon concentration (236 Bq/m³). The geological, geochemical and radiological data obtained suggest that the most effective control on the radon concentrations of the area is related with the uranium content of the rocks; indeed, the highest contents were observed in granite G1 (21 ppm) and the lowest in the metasediments (3 ppm). This is also confirmed by the results obtained for groundwater, where granites present the highest concentrations of dissolved radon (up to 938 Bq/l), uranium (5–18 ppb) and gross α activities (0.47–0.92 Bq/l). No important radiometric anomalies were found in relation with geological structures such as faults, veins and contacts, but a moderate increase of the uranium content can occur locally in such structures. Petrographic observations and SEM studies show that uranium is mainly contained within the rock in heavy accessory minerals (apatite, zircon, monazite, xenotime), which reduces radon emanation. Notwithstanding, due to the high U contents granites show a significant potential to induce indoor radon concentrations in dwellings in excess of the recommended value of 400 Bq/m³. Overall, we can conclude that the region of Vila Real presents a moderate to high radon risk in dwellings and groundwater.  相似文献   

Seasonal variability in somatic and reproductive investment of the bivalve Scrobicularia plana (da Costa, 1778) along a latitudinal gradient     

Sílvia Santos  Joana F.M.F. Cardoso  Célia Carvalho  Pieternella C. Luttikhuizen  Henk W. van der Veer 《Estuarine, Coastal and Shelf Science》2011

Monthly investment in soma and gonads in the bivalve Scrobicularia plana is described for three populations along its distributional range: Minho estuary, Portugal; Westerschelde estuary, The Netherlands and Buvika estuary, Norway. Seasonal cycles in body mass (BMI), somatic mass (SMI) and gonadal mass (GMI) indices were observed for all populations. In Portugal, BMI and SMI peaked in mid-autumn, while in The Netherlands both indices were at their highest in mid-spring. Norway showed a different pattern with two distinct peaks: one in mid-autumn and a second peak in spring. GMI reached maximum values in July in Portugal and Netherlands and in June in Norway. Overall, mean BMI and SMI were lower in Portugal while mean GMI was lower in Norway. The spawning period lasted the whole summer in Portugal, but was shorter (only two months) in The Netherlands and Norway. The reproductive investment in The Netherlands was significantly higher than in Portugal and Norway, with the lowest values being observed in Norway. Differences in annual cycles between populations were attributed to environmental factors, namely temperature and food availability. Temperature seems important in shaping the reproductive pattern with more northern populations showing shorter reproductive periods starting later in the year, and a lower reproductive output. In addition, winter water temperatures can explain the lower mean body and somatic mass values observed in Portugal. Food availability influenced the physiological performance of the species with peaks in somatic mass coinciding with phytoplankton blooms. This relation between physiological performance and environmental factors influences S. plana distribution, densities and even survival, with natural consequences on its commercial importance.  相似文献   

Resilience and brittleness in the ALERTA RIO system: a field study about the decision-making of forecasters     

Giovanni Dolif  Andre Engelbrecht  Alessandro Jatobá  Antônio José Dias da Silva  José Orlando Gomes  Marcos R. S. Borges  Carlos A. Nobre  Paulo Victor R. de Carvalho 《Natural Hazards》2013,65(3):1831-1847

Natural disasters, particularly those triggered by heavy rainfall, may cause major damage and death. However, if an accurate early warning is issued, the damage can be mitigated. In Latin America and Brazil, characteristics of socioeconomic development often lead to a disorderly growth of cities and, consequently, occupation and irregular construction in risk areas. Therefore, forecasts of heavy rainfall, as well as preventative and mitigatory actions based on meteorological data/alerts, are essential to saving lives and minimizing material loss. An event that would have benefited from such actions is that which occurred in the mountainous region of Rio de Janeiro in January 2011, when over 800 people lost their lives. This work describes the first research initiative on resilience engineering domain in systems to forecast heavy rains in Rio de Janeiro. The results indicate important sources of brittleness in the system that supports the work of meteorologists, mainly related to the technical and organizational framework, and suggests that the main source of resilience in dealing with critical situations is the tacit knowledge of experts.  相似文献   

Accumulation of paralytic shellfish toxins in digestive gland of Octopus vulgaris during bloom events including the dinoflagellate Gymnodinium catenatum     

Pedro Reis Costa  Maria Joo Botelho  Susana Margarida Rodrigues 《Marine pollution bulletin》2009,58(11):1747-1750

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Removal of Copper,Nickel and Zinc Ions from Aqueous Solution by Chitosan‐8‐Hydroxyquinoline Beads     

Francisco C. F. Barros  Francisco W. Sousa  Rivelino M. Cavalcante  Tecia V. Carvalho  Francisco S. Dias  Danilo C. Queiroz  Luiz C. G. Vasconcellos  Ronaldo F. Nascimento 《洁净——土壤、空气、水》2008,36(3):292-298

In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu²⁺ > Ni²⁺ > Zn²⁺ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu²⁺ > Zn²⁺ > Ni²⁺ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L^–1 HCl solution, with 90% regeneration.  相似文献   

A field study of coastal dynamics on a muddy coast offshore of Cassino beach,Brazil     

K. Todd Holland  Susana B. Vinzon  Lauro J. Calliari 《Continental Shelf Research》2009

Mud deposits near sandy beaches, found throughout the world, are of scientific and societal interest as they form important natural sea defenses by efficiently damping storm waves. A multi-national field experiment to study these phenomena was performed offshore Cassino beach in southern Brazil starting in 2004. This experiment aimed to investigate the formation of an offshore mud deposit, to characterize wave attenuation over potentially mobile muddy bottoms, and to evaluate the performance of models for wave transformation over heterogeneous beds through the measurement of water waves, near-bottom currents, bathymetry, and changes in bottom sediment characteristics. The main instrumentation was a set of wave sensors deployed in a transect from the shoreline across sandy and muddy deposits offshore to a depth of 25 m. Additional sensors, including current meters and optical backscatter sensors, were concentrated at stations in the middle of the mud deposit and in the surf zone to document aspects of the wave boundary layer and lutocline dynamics. This fieldwork also involved the geological and geotechnical characterization of the mud deposit using seismic equipment, echo-sounders, cores, surficial sampling and an in-situ density meter. These sediment samples were subsequently analyzed for density, grain size distribution, mineralogy, rheology and sedimentary structures. In addition, video and radar monitoring equipment were installed to measure the long-term aspects of surf zone damping by fluid mud and any associated morphodynamic responses. This paper provides a summary of environmental conditions monitored during the experiment and describes the major findings of the various investigations. Although data collection was more difficult than anticipated and dramatic wave attenuation involving the onshore transport of fluid mud into the surf zone region was not observed during the instrumented interval, the new methodologies developed and comprehensive observations obtained during this effort are being used to improve our understanding of shoaling wave dynamics and sediment transport in the coastal zone in regions with significant cohesive sediment deposits.  相似文献