Interaction of copper with fatty acids in Soxhlet extraction and its influence     

Ming Jin  Yanqing Xia  Tianzhu Lei  Junli Qiu  Rui Zhang 《中国地球化学学报》2008,27(2):157-160

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.  相似文献   

GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea   总被引：4，自引：1，他引：3  

Shuanggen Jin  O. F. Luo  P. Park 《Journal of Geodesy》2008,82(12):883-892

The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward electric field, and are not associated with the increase of the O/N₂ ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically coupled upward to generate ionospheric perturbations and oscillations.  相似文献   

GIS支持的城市固体废弃物规划管理信息系统构建     

李劲  王华 《测绘工程》2008,17(1):60-63

研究了基于组件式GIS平台MapX的城市固体废弃物规划管理信息系统的设计与实现;讨论了系统框架与系统功能设计、数据库设计和系统实现的关键技术。以昆明市为例,构建了基于MapX的城市固体废弃物规划管理信息系统。该系统能够实现城市固体废弃物各类数据的采集、表达和输出,提供与城市固体废弃物管理模型无缝集成的接口,可利用地图、文字、表格等多种手段为城市固体废弃物规划管理提供辅助决策。  相似文献   

Study on Recovering the Earth＇s Potential Field Based on GOCE Gradiometry     

Wenbin Shen  Jin Li  Jiancheng Li  Zhengtao Wang  Jinsheng Ning  Dingbo Chao 《地球空间信息科学学报》2008,11(4):273-278

Given the second radial derivative Vrr（P） ｜δs of the Earth＇s gravitational potential V（P） on the surface δS corresponding to the satellite altitude, by using the fictitious compress recovery method, a fictitious regular harmonic field rrVrr（P）^＊ and a fictitious second radial gradient field V：（P） in the domain outside an inner sphere Ki can be determined, which coincides with the real field V（P） in the domain outside the Earth. Vrr^＊（P）could be further expressed as a uniformly convergent expansion series in the domain outside the inner sphere, because rrV（P）^＊ could be expressed as a uniformly convergent spherical harmonic expansion series due to its regularity and harmony in that domain. In another aspect, the fictitious field V^＊（P） defined in the domain outside the inner sphere, which coincides with the real field V（P） in the domain outside the Earth, could be also expressed as a spherical harmonic expansion series. Then, the harmonic coefficients contained in the series expressing V^＊（P） can be determined, and consequently the real field V（P） is recovered. Preliminary simulation calculations show that the second radial gradient field Vrr（P） could be recovered based only on the second radial derivative V（P）｜δs given on the satellite boundary. Concerning the final recovery of the potential field V（P） based only on the boundary value Vrr （P）｜δs, the simulation tests are still in process.  相似文献   

有色噪声作用下的卡尔曼滤波   总被引：2，自引：0，他引：2  

赵长胜  陶本藻 《武汉大学学报(信息科学版)》2008,33(2):180-182,207

利用GPS载波相位三差观测量进行动态定位(或精密导航),就必须研究有色噪声滤波的理论问题.根据需求,推导了动态噪声、观测噪声为有色噪声的线性系统滤波公式,并证明白噪声卡尔曼滤波是有色噪声卡尔曼滤波的特例,或者说有色噪声的卡尔曼滤波是白噪声卡尔曼滤波的推广.  相似文献   

应用混合分布研究银川平原地下水埋深对植被的影响   总被引：1，自引：0，他引：1  

孙宪春  金晓媚  万力 《地学前缘》2008,15(5):344

银川平原地处西北干旱地区,自然生态环境在西北地区具有典型性。研究银川平原的生态环境,需要研究植被,它反映多种因素的作用。在影响植被的各种因素中,地下水对植被生长的影响非常重要,但将地下水对植被生长的影响进行定量化分离并不容易。近年来,用混合分布函数处理大量数据的方法受到越来越多的关注,但是混合分布函数的参数求解一直比较困难。文章提出了一种基于混合分布函数和数据直方图之间的关系,用最小二乘法估计参数的新方法;并用这种方法,结合银川平原遥感数据中的归一化植被指数NDVI,对地下水埋深与植被生长的关系进行定量分析,得到地下水埋深对植被影响所服从的正态分布密度函数。  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

基于整体最小二乘法的线性回归建模和解法   总被引：11，自引：0，他引：11  

鲁铁定  陶本藻  周世健 《武汉大学学报(信息科学版)》2008,33(5):504-507

对基于自变量和因变量误差的回归问题进行了进一步研究,证明了两种方法的实质并未解决同时考虑自变量和因变量的误差问题,其解算结果和不考虑自变量误差的解算结果完全相同.给出了能同时顾及自变量和因变量误差的新的回归模型,并推导了具体的解算方法.算例结果和基于矩阵分解的整体最小二乘法解算方法的结果相同,说明了本文方法的正确性.  相似文献   

鄂尔多斯高原植被生态分区及其水文地质意义   总被引：2，自引：0，他引：2  

黄金廷  侯光才  陶正平  赵振宏  王晓勇  崔旭东 《地质通报》2008,27(8):1330-1334

保护生态环境是鄂尔多斯高原地下水可持续开发利用中亟待解决的问题。在查清植被生态群落分布特征的基础上,通过分析植被演替的自然驱动因素,将鄂尔多斯高原的植被生态划分为基岩台地植被生态水文地质区、沙盖基岩植被生态水文地质区、沙地植被生态水文地质区和滩地植被生态水文地质区。结果表明,气象和地形地貌控制着区内植被生态的总体分布格局,包气带和地下水因素控制着植被生态的演替,沙地植被生态和滩地植被生态的生长发育与地下水关系密切,是地下水开发时保护植被生态的靶区。  相似文献   

山西保德—静乐地区新近纪地层时代讨论     

朱大岗  孟宪刚  邵兆刚  雷伟志  王津  韩建恩  余佳  吕荣平  王艳 《地质通报》2008,27(4):510-516

通过对山西保德-静乐地区新近纪地层的野外地质调查和实测剖面,对分布于该区的新近纪地层进行了详细的研究和划分,获得了新的ESR和古地磁测年数据,并结合生物地层序列确定了该区新近系地层的顺序为：新近系上新统静乐组（N2j）、新近系中新统上部保德组（N1^26）和中新统下部芦子沟组（N1^1l）。  相似文献