Potassium loss during metasomatic alteration of mica pyroxenite from Oldoinyo Lengai,northern Tanzania: contrasts with fenitization     

J. B. Dawson  J. V. Smith 《Contributions to Mineralogy and Petrology》1992,112(2-3):254-260

Mica pyroxenite xenoliths, occurring as the cores of nephelinite and ijolite bombs in the pyroclastic deposits of the active volcano Oldoinyo Lengai, have undergone metasomatism in which K was lost and Fe²⁺ and Ti gained. This is unlike the alkali and ferric iron addition that typifies most examples of metastomatism adjacent to peralkaline igneous rocks in carbonatite complexes.  相似文献   

Kalsilite in the lavas of Mt. Nyiragongo (Belgian Congo)     

SAHAMA  TH. G. 《Journal of Petrology》1960,1(1):146-171

A considerable part of the nephelinite lavas of the volcanoMt. Nyiragongo in the eastern Belgian Congo contains kalsiliteas one of the main constituents. The mineral never occurs asthe only feldspathoid of the rock but is accompanied by nepheline,abundant melilite, and, sometimes, by small to moderate amountsof leucite. Other important constituents of these kalsilite-bearingrocks are clinopyroxene, olivine, perovskite, titanomagnetite,sodalite, &c. The feldspars are lacking. Kalsilite occurs both as complex nepheline-kalsilite phenocrystsin which these phases are strictly co-axial and in the fine-grainedgroundmass as grains separate from those of nepheline. The complex nepheline-kalsilite phenocrysts exhibit a continuousseries of progressing exsolution schematically presented inFig. 5. The series begins with a perthite-like nepheline-kalsilitecore surrounded by a drop-like development of nepheline in themargin of the crystal and ends up with a homogeneous kalsilitecore surrounded by a nepheline margin. The complex phenocrysts occur mostly as aggregates causing atypically glomeroporphyritic texture. Evidence is presentedindicating that, in the very first stages of crystallization,some of the Nyiragongo lavas are able to precipitate small amountsof phenocrysts of approximate composition K₃NaAl₄Si₄O₁₆. Throughcrystal-rise under turbulent currents in the molten lava massthese phenocrysts have been accumulated into aggregates andthus have been preserved until extrusion. Granted sufficientlyslow cooling under static conditions, the phenocrysts wouldhave reacted with the molten lava. The roles of the crystal-riseand of the turbulent currents in lava are illustrated by theoccurrence of the ‘giant’ leucite aggregates foundin the inner walls of the crater and by observations on thelava lake of the mountain. The occurrence of kalsilite in the groundmass is explained bythe existence of a two-phase area in the sub-solidus range inthe nepheline-kalsilite system. The Nepheline Aggregate lavas represent the last extrusionsemitted by the Nyiragongo main crater. The nepheline phenocrystscharacteristic of these lavas range considerably higher in potassiumcontent than the nephelines found in other Nyiragongo flows.The crystals are slightly zoned with a large potassium-richcore coated by a narrow margin with gradually decreasing potassiumcontent. The zoning may be detected only by using special methods.The history of crystallization of the nepheline phenocrystsis considered analogous to that of the complex nepheline-kalsilitephenocrysts with the only difference that the nepheline phenocrystsof the Nepheline Aggregate lavas are less rich in potassiumand, consequently, have not been subjected to exsolution.  相似文献   

Kalsilite in the lavas of Mt. Nyiragongo (Belgian Congo)     

SAHAMA  TH. G. 《Journal of Petrology》1960,1(2):146-171

A considerable part of the nephelinite lavas of the volcanoMt. Nyiragongo in the eastern Belgian Congo contains kalsiliteas one of the main constituents. The mineral never occurs asthe only feldspathoid of the rock but is accompanied by nepheline,abundant melilite, and, sometimes, by small to moderate amountsof leucite. Other important constituents of these kalsilite-bearingrocks are clinopyroxene, olivine, perovskite, titanomagnetite,sodalite, &c. The feldspars are lacking. Kalsilite occurs both as complex nepheline-kalsilite phenocrystsin which these phases are strictly co-axial and in the fine-grainedgroundmass as grains separate from those of nephe-line. The complex nepheline-kalsilite phenocrysts exhibit a continuousseries of progressing exsolution schematically presented inFig. 5. The series begins with a perthite-like nepheline-kalsilitecore surrounded by a drop-like development of nepheline in themargin of the crystal and ends up with a homogeneous kalsilitecore surrounded by a nepheline margin. The complex phenocrysts occur mostly as aggregates causing atypically glomeroporphyritic texture. Evidence is presentedindicating that, in the very first stages of crystallization,some of the Nyiragongo lavas are able to precipitate small amountsof phenocrysts of approximate composition K₃NaAl₄Si₄O₁₆. Throughcrystal-rise under turbulent currents in the molten lava massthese phenocrysts have been accumulated into aggregates andthus have been preserved until extrusion. Granted sufficientlyslow cooling under static conditions, the phenocrysts wouldhave reacted with the molten lava. The roles of the crystal-riseand of the turbulent currents in lava are illustrated by theoccurrence of the ‘giant’ leucite aggregates foundin the inner walls of the crater and by observations on thelava lake of the mountain. The occurrence of kalsilite in the groundmass is explained bythe existence of a two-phase area in the sub-solidus range inthe nepheline-kalsilite system. The Nepheline Aggregate lavas represent the last extrusionsemitted by the Nyiragongo main crater. The nepheline phenocrystscharacteristic of these lavas range considerably higher in potassiumcontent than the nephelines found in other Nyiragongo flows.The crystals are slightly zoned with a large potassium-richcore coated by a narrow margin with gradually decreasing potassiumcontent. The zoning may be detected only by using special methods.The history of crystallization of the nepheline phenocrystsis considered analogous to that of the complex nepheline-kalsilitephenocrysts with the only difference that the nephe-line phenocrystsof the Nepheline Aggregate lavas are less rich in potassiumand, consequently, have not been subjected to exsolution.  相似文献   

Eucolite from oldoinyo Lengai,Tanzania     

J.B. Dawson  T. Frisch 《Lithos》1971,4(3):297-303

Eucolite occurs in ejected blocks of agpaitic wollastonite-bearing nepheline syenite in the pyroclastics of the active carbonatite volcano Oldoinyo Lengai, northern Tanzania. An analysis of the syenite is given, and chemical, optical and X-ray data for the eucolite are presented. The agpaitic paragenesis at Oldoinyo Lengais is one of the few recorded instances of agpaitic rocks in carbonatite environment.  相似文献   

PCBs in the firth of clyde     

J.I. Waddington  G.A. Best  J.P. Dawson  T. Lithgow 《Marine pollution bulletin》1973,4(2):26-28

Attention to detail is essential for the reduction of pollution. By detective work, a river purification board has been able to track down an important single source of PCB contamination of its sewage sludge and institute remedial action.  相似文献   

The monosaccharide spectra of natural waters     

Kenneth Mopper  Rodger Dawson  Gerd Liebezeit  Venu Ittekkot 《Marine Chemistry》1980,10(1):55-66

Monosaccharides were determined in waters and sediment pore waters from a wide variety of environments and locations. Desalting was performed by electrodialysis and concentrated extracts were analyzed by two forms of liquid chromatography. At least 12 sugars were identified. Glucose and fructose were the dominant monosaccharides in nearly all samples examined. Analyses of over 150 seawater and sediment pore water samples showed that fructose is highly significantly correlated (>0.99) with glucose concentrations. Laboratory kinetic experiments on the epimerization reaction, glucose ? fructose, in sterilized natural seawater in the dark, yielded a forward rate constant, k₁, of 1.2 × 10^?5 h^?1 at 25°C and 1.6 × 10^?7 h^?1 at 2°C. The approximate time required to attain equilibrium at 25°C was 1.1 y and at 2°C, 15.4 y; the measured equilibrium constant was in the range 0.3–0.4. The actual ratio of fructose to glucose in natural water samples was usually in the range 1.0–1.4/l, independent of the total monosaccharide concentrations, which varied in the samples by a factor of ～100. Several possible explanations for the apparent discrepancy in the determined and found ratios are discussed: the presence of universal, as yet, undiscovered major biological sources for fructose in marine environments; preferential utilization of glucose; preferential incorporation of fructose into or onto inorganic colloids; and preferential formation of fructose-transition metal ion associations.  相似文献   

Tsunami deposits in the geological record   总被引：2，自引：0，他引：2  

Alastair G. Dawson  Iain Stewart 《Sedimentary Geology》2007,200(3-4):166-183

A review is presented here of tsunami deposits in the geological record. It begins with a discussion of the relationships between the processes of tsunami generation and propagation and the sedimentary responses. This is followed by a consideration of the sedimentary processes associated with the passage of tsunami waves across coastlines. Attention is also given to the sedimentary processes associated with tsunami-triggered gravity backwash flows and comparisons are made with turbidity current action. We observe that despite sedimentary evidence for recent tsunamiites, geological research on ancient tsunamis has not identified stratigraphic units associated with onshore tsunami sedimentation. Equally, it is noted that nearly all published studies of sedimentary processes associated with modern tsunamis have not considered patterns of sediment transport and deposition in the offshore zone.  相似文献   

COMBISWEEP—A CONTRIBUTION TO SWEEP TECHNIQUES*     

H. WERNER  TH. KREY 《Geophysical Prospecting》1979,27(1):78-105

Nonlinear sweeps have often successfully been employed in the 1960s. However, this area of sweep technology has been neglected since the introduction of digital recording techniques in the Vibroseis system. Now the advent of computerized recording instruments yields a new economical possibility of forming approximately nonlinear sweeps by combining several linear sweeps with or without time gaps to a “Combisweep”. The total duration of a Combisweep may be as long as the maximum available recording time, for example 32 s. Beside the attenuation of correlation noise, the new method has further merits, such as the weighting of predetermined frequency ranges, in order to effect a certain kind of optimum filtering on the emitter side, or in order to compensate to some degree for frequency dependent absorption. In all these applications the Combisweep is considered as one signal in the correlation process. But by correlating with the individual sweeps or a partial combination of them and by applying automatic switching at predetermined times within the gaps between the individual sweeps additional possibilities arise, such as obtaining in one run with a twenty-four channel recording unit twenty-four traces with small distances between vibrators and geophones for shallow reflections and another twenty-four traces with larger distances for deeper reflections. Various Combisweeps and their applications are presented.  相似文献   

Employment in retailing: A case study of employment in suburban shopping centres     

Ian Alexander  John A. Dawson 《Geoforum》1979,10(4):407-425

There have been many studies of the retail industry in recent years, and of the impact that retailing has had on the spatial arrangement of urban areas and on consumer behaviour. Little attention has been paid, however, to employment in retailing, which is disturbing in view of its growing importance and its rapidly changing nature and composition. This paper examines the nature of the broad structural changes within the industry, and investigates their spatial consequences through a case study of employment generation within a system of suburban retail centres in Canberra, Australia. It is shown that the evolution of suburban centres, particularly those of a regional variety, has had an important and enriching impact on the suburban labour market. The regional centres are also seen to be the focus of the major structural employment changes currently affecting the retail industry. This has some important implications for urban planning.  相似文献   

Fertile and barren AlCr-spinel harzburgites from the upper mantle: Ion and electron probe analyses of trace elements in olivine and orthopyroxene: Relation to lherzolites     

R.L. Hervig  J.V. Smith  I.M. Steele  J.B. Dawson 《Earth and Planetary Science Letters》1980,50(1):41-58

Ion and electron microprobe analyses of twenty-one CrAl-spinel harzburgite xenoliths from southern African kimberlites show two chemical groups. Orthopyroxenes from “fertile” harzburgites have higher CaO (mean of 11, 0.95 wt.%), Al₂O₃ (3.05 wt.%), Cr₂O₃ (0.85 wt.%) and Li (0.8 ppmw) than those from “barren” harzburgites (mean of 10, CaO 0.24 wt.%, Al₂O₃ 1.10 wt.%, Cr₂O₃ 0.35 wt.%, Li 0.3 ppmw). Olivines from all harzburgites have similar chemistry except that mean values of Li and Na are higher for barren than fertile harzburgites (Li 0.9 vs. 0.4 ppmw; Na₂O 16 vs. 7 ppmw). Orthopyroxenes from fertile harzburgites are chemically distinct from those in garne lherzolites from southern Africa and spinel lherzolites from southwest U.S.A., but orthopyroxenes from barren harzburgites are indistinguishable from those in many coarse garnet lherzolites.Chromium, Ca, Ni, Na and Li in coexisting olivines and orthopyroxenes from the above rock types show complex patterns, which for Ca, Cr and Ni can be related to pressure and temperature. Temperatures from an empirically calibrated thermometer based on Ni-Mg exchange between olivine and orthopyroxene, measured modes of harzburgites (fertile, mean of 10: ol 68, opx 31, spinel-silicate intergrowth <0.5; barren, mean of 8: ol 76, opx 23, spinel and spinel-silicate intergrowth 1), and high-pressure experimental studies suggest (a) that harzburgites are residues of partial melting, (b) that barren harzburgites were melted to a greater extent at a higher temperature (though probably at a similar depth) than fertile harzburgites, and (c) that incomplete reequilibration during retrograde metamorphism has led to development of complex inter- and intragranular textures, probably in the range ～700–900°C.  相似文献