DISCUSSION OF "An Alternate Procedure for Analyzing Aquifer Tests Using the Theis Nonequilibrium Solution," by O. L. Franke, May–June 1987 issue, v. 25, no. 3, pp. 314–320.     

Willard A. Murray 《Ground water》1987,25(5):616-617

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Cryogenic Tests of Volume-Phase Holographic Gratings: I. Results at 200 K     

N. Tamura  G. J. Murray  P. Luke  C. Blackburn  D. J. Robertson  N. A. Dipper  R. M. Sharples  J. R. Allington-Smith 《Experimental Astronomy》2003,15(1):1-12

We present results from cryogenic tests of a Volume-Phase Holographic(VPH) grating at 200 K measured at near-infrared wavelengths. The aims of these tests were to see whether the diffraction efficiency and angular dispersion of a VPH grating are significantly different at a low temperature from those at a room temperature, and to see how many cooling and heating cycles the grating can withstand. We have completed 5 cycles between room temperature and 200 K, and find that the performance is nearly independent of temperature, at least over the temperature range which we are investigating. In future, we will not only try more cycles between these temperatures but also perform measurements at a much lower temperature (e.g., ∼80 K).  相似文献   

Marine scavenging: Trace metal adsorption by interfacial sediment from MANOP Site H     

Laurie S. Balistrieri  James W. Murray 《Geochimica et cosmochimica acta》1984,48(5):921-929

The adsorption of thirteen trace metals from seawater was studied on interfacial sediment from MANOP site H. The adsorption data indicate a long (~20 day) equilibration time for most metals, an increase in adsorption with an increase in pH and particle concentration, a dependence of adsorption on total metal concentration at high adsorption densities, and a lack of correlation between metal binding ability and metal hydrolysis in solution.Apparent equilibrium binding constants normalized to the total number of available sites on the solid were determined for metal binding with the interfacial sediment. The binding constants indicate that the affinity sequence for metal interactions with the interfacial sediment is: Pb > Fe > Sn ? Co≈ Mn > Cu > Be > Sc ? Zn > Ni > Cd ? Ba > Cs at pH 7.82 in seawater.A comparison of the binding constants for suspended particles, interfacial sediment, and surface sediment indicate that the composition of particles influences the binding ability of the particles. Biogenic particles tend to bind most metals more strongly than lithogenic or authigenic particles.Based on limited data, there is a strong positive correlation between the measured binding constants and the observed partitioning of metals between sediment and seawater.  相似文献   

A model for coupled sulfate reduction and methane oxidation in the sediments of Saanich Inlet   总被引：2，自引：0，他引：2  

A.H. Devol  J.J. Anderson  K. Kuivila  J.W. Murray 《Geochimica et cosmochimica acta》1984,48(5):993-1004

A methane-sulfate coupled reaction diffusion model has been developed to describe the inverse relationship commonly observed between methane and sulfate concentrations in the pore waters of anoxic marine sediments. The sediment column was divided into two zones; an upper zone where diagenetic reaction rates are limited by the concentration of oxidizable organic matter and a lower zone in which reaction rates are limited by the concentration of oxidizing agent—sulfate. For each zone differential equations describing the distribution of methane and sulfate were derived. The boundary conditions used to solve these equations resulted in a set of four coupled equations. When fit to data from Saanich Inlet (B.C., Canada) and Skan Bay (Alaska) the model not only reproduces the observed methane and sulfate pore water concentration profiles but also accurately predicts the methane oxidation and sulfate reduction rates. Maximum methane oxidation rates occur at the transition boundary from the upper to the lower layer. In Saanich Inlet sediments from 23 to 40% of the downward sulfate flux is consumed in methane oxidation while in Skan Bay this value is only about 12%.  相似文献   

Metallogeny and tectonic development of the Tasman Fold Belt System in Queensland     

C.G. Murray 《Ore Geology Reviews》1986,1(2-4)

The northern part of the Tasman Fold Belt System in Queensland comprises three segments, the Thomson, Hodgkinson- Broken River, and New England Fold Belts. The evolution of each fold belt can be traced through pre-cratonic (orogenic), transitional, and cratonic stages. The different timing of these stages within each fold belt indicates differing tectonic histories, although connecting links can be recognised between them from Late Devonian time onward. In general, orogenesis became younger from west to east towards the present continental margin. The most recent folding, confined to the New England Fold Belt, was of Early to mid-Cretaceous age. It is considered that this eastward migration of orogenic activity may reflect progressive continental accretion, although the total amount of accretion since the inception of the Tasman Fold Belt System in Cambrian time is uncertain.The Thomson Fold Belt is largely concealed beneath late Palaeozoic and Mesozoic intracratonic basin sediments. In addition, the age of the more highly deformed and metamorphosed rocks exposed in the northeast is unknown, being either Precambrian or early Palaeozoic. Therefore, the tectonic evolution of this fold belt must remain very speculative. In its early stages (Precambrian or early Palaeozoic), the Thomson Fold Belt was probably a rifted continental margin adjacent to the Early to Middle Proterozoic craton to the west and north. The presence of calc-alkaline volcanics of Late Cambrian Early Ordovician and Early-Middle Devonian age suggests that the fold belt evolved to a convergent Pacific-type continental margin. The tectonic setting of the pre-cratonic (orogenic) stage of the Hodgkinson—Broken River Fold Belt is also uncertain. Most of this fold belt consists of strongly deformed, flysch-type sediments of Silurian-Devonian age. Forearc, back-arc and rifted margin settings have all been proposed for these deposits. The transitional stage of the Hodgkinson—Broken River Fold Belt was characterised by eruption of extensive silicic continental volcanics, mainly ignimbrites, and intrusion of comagmatic granitoids in Late Carboniferous Early Permian time. An Andean-type continental margin model, with calc-alkaline volcanics erupted above a west-dipping subduction zone, has been suggested for this period. The tectonic history of the New England Fold Belt is believed to be relatively well understood. It was the site of extensive and repeated eruption of calc-alkaline volcanics from Late Silurian to Early Cretaceous time. The oldest rocks may have formed in a volcanic island arc. From the Late Devonian, the fold belt was a convergent continental margin above a west-dipping subduction zone. For Late Devonian- Early Carboniferous time, parallel belts representing continental margin volcanic arc, forearc basin, and subduction complex can be recognised.A great variety of mineral deposits, ranging in age from Late Cambrian-Early Ordovician and possibly even Precambrian to Early Cretaceous, is present in the exposed rocks of the Tasman Fold Belt System in Queensland. Volcanogenic massive sulphides and slate belt-type gold-bearing quartz veins are the most important deposits formed in the pre-cratonic (orogenic) stage of all three fold belts. The voicanogenic massive sulphides include classic Kuroko-type orebodies associated with silicic volcanics, such as those at Thalanga (Late Cambrian-Early Ordovician. Thomson Fold Belt) and at Mount Chalmers (Early Permian New England Fold Belt), and Kieslager or Besshi-type deposits related to submarine mafic volcanics, such as Peak Downs (Precambrian or early Palaeozoic, Thomson Fold Belt) and Dianne. OK and Mount Molloy (Silurian—Devonian, Hodgkinson Broken River Fold Belt). The major gold—copper orebody at Mount Morgan (Middle Devonian, New England Fold Belt), is considered to be of volcanic or subvolcanic origin, but is not a typical volcanogenic massive sulphide.The most numerous ore deposits are associated with calc-alkaline volcanics and granitoid intrusives of the transitional tectonic stage of the three fold belts, particularly the Late Carboniferous Early Perman of the Hodgkinson—Broken River Fold Belt and the Late Permian—Middle Triassic of the southeast Queensland part of the New England Fold Belt. In general, these deposits are small but rich. They include tin, tungsten, molybdenum and bismuth in granites and adjacent metasediments, base metals in contact meta somatic skarns, gold in volcanic breccia pipes, gold-bearing quartz veins within granitoid intrusives and in volcanic contact rocks, and low-grade disseminated porphyry-type copper and molybdenum deposits. The porphyry-type deposits occur in distinct belts related to intrusives of different ages: Devonian (Thomson Fold Belt), Late Carboniferous—Early Permian (Hodgkinson—Broken River Fold Belt). Late Permian Middle Triassic (southeast Queensland part of the New England Fold Belt), and Early Cretaceous (northern New England Fold Belt). All are too low grade to be of economic importance at present.Tertiary deep weathering events were responsible for the formation of lateritic nickel deposits on ultramafics and surficial manganese concentrations from disseminated mineralisation in cherts and jaspers.  相似文献   

The adsorption of Cu,Pb, Zn,and Cd on goethite from major ion seawater     

L.S. Balistrieri  J.W. Murray 《Geochimica et cosmochimica acta》1982,46(7):1253-1265

The adsorption of Cu, Pb, Zn, and Cd on goethite (αFeOOH) from NaNO₃ solutions and from major ion seawater was compared to assess the effect of the major ions of seawater (Na, Mg, Ca, K, Cl, and SO₄) on the adsorption behavior of the metals. Magnesium and sulphate are the principal seawater ions which enhance or inhibit adsorption relative to the inert system. Their effect, as determined from the site-binding model of Davis et al. (1978), was a combination of changing the electrostatic conditions at the interface and decreasing the available binding sites.The basic differences between the experimental system of major ion seawater and natural seawater were examined. It was concluded that: 1) although the experimental metal concentrations in major ion seawater were higher than those found in natural seawater, estimates of the binding energy of Cu, Zn, and Cd with αFeOOH for natural seawater concentrations could be made from the data, 2) Cu, Pb, Zn, and Cd showed little or no competition for surface sites on goethite, and 3) the presence of carbonate, phosphate, and silicate had little or no effect on the adsorption of Zn and Cd on goethite.  相似文献   

Aerobic respiration in pelagic marine sediments     

Varis Grundmanis  James W Murray 《Geochimica et cosmochimica acta》1982,46(6):1101-1120

Analyses for dissolved oxygen, nitrate and total CO₂ in the interstitial water have been combined with solid phase sediment analyses of carbon and nitrogen to calculate the rates of reaction and stoichiometry of decomposing organic matter in central Equatorial Pacific pelagic sediments. The diagenesis is dominated by aerobic respiration and nitrification.Organic carbon and total nitrogen decrease exponentially with depth in both red clay and carbonate ooze sediments. In addition, there is a correlation between surface organic carbon and total nitrogen with distance from the equator. Fixed NH₄ is relatively constant with depth and constitutes 12 to 64% of the total nitrogen. The remainder is considered to be organic nitrogen.The $\text{C}\text{N}$ ratio of the decomposing organic matter was obtained using three approaches. Using the correlations of organic carbon with total nitrogen or organic nitrogen the molar ratios varied from 3.4 to 18.1. The average of all stations was 12.6 using total nitrogen and 13.7 using organic nitrogen. The Redfield ratio is 6.6. Approaches using interstitial water chemistry gave lower ratios. The average value using correlations between dissolved oxygen and nitrate was 8.1. The same approach using total CO₂ and nitrate gave an average of 9.1. Due to difficulties in unambiguously interpreting the solid phase data we favor the ratios obtained from the pore water analyses.The rate of organic matter decomposition can be obtained from model calculations using the dissolved oxygen and solid organic carbon data. Most gradients occur in the upper 10 to 20 cm of the sediments. Assuming that bioturbation is more important than sedimentation we have calculated first order rate constants. The average values using organic carbon and dissolved oxygen was 3.9 kyr^? and 4.2 kyr^? respectively using a biological mixing coefficient of 100 cm² kyr^?1. These rate constants decrease in direct proportions to the mixing coefficient.  相似文献   

Sedimentary indicators of water movement in the western approaches to the English Channel     

J.W. Murray  J.W. Weston  S. Sturrock 《Continental Shelf Research》1983,1(4):339-352

The continental shelf to the southwest of the British Isles is an area of intense tidal current activity. Although most of the sediment is coarse, it still contains a small proportion of fine (<63 μm) material, consisting mainly of biogenic debris. Coccoliths in particular are both common and widespread and they are found in the adjacent slope sediments. The results presented here show that coccolithophorid diversity is high in the deeper parts of Whittard Canyon, the abyssal plain, and on a small area of shelf. Diversity decreases away from the ocean towards the land. Coccoliths and coccospheres have also been recorded from surface water samples. Apart from the landward movement of oceanic water shown by the coccolithophorids, movement of material on the bottom from shelf to slope is shown by the distribution of benthic diatom frustules and mollusc shell chips cut by clionid sponges. Thus, a study of the fine sediment reveals details of sediment transport and water movement.  相似文献   

The Oyambre coastal terrace: a detailed sedimentary record of the Last Interglacial Stage in northern Iberia (Cantabrian coast,Spain)     

Elisa Sainz de Murieta  Pedro P. Cunha  Alejandro Cearreta  Andrew S. Murray  Jan-Pieter Buylaert 《第四纪科学杂志》2021,36(4):570-585

A detailed study is presented of a 15.3-m-thick Pleistocene coastal terrace located on the Cantabrian coast (northern Spain). Stratigraphic, sedimentological, topographic and micropalaeontological information is combined with a chronology based on luminescence dating to characterize the deposits. The sedimentary succession records: (i) a basal transgressive system, consisting of a wave-cut surface covered by a lower layer of beach gravels and upper beach pebbly sands; and (ii) a thicker upper highstand system (aggrading), comprising medium to very fine aeolian sands interbedded with thin palustrine muds. Luminescence dating involved a detailed sampling strategy (36 samples and two modern analogues) and the use of both quartz optically stimulated luminescence (OSL) and feldspar post-infrared infrared stimulated luminescence single aliquot regeneration protocols; feldspar results were used to confirm the completeness of bleaching of the quartz OSL signal. The quartz OSL luminescence age–depth relationship shows significant dispersion, but nevertheless two rapid phases of deposition can be clearly identified: one at ~130 ka [Marine Oxygen Isotope Stage (MIS) 5] and one at ~100 ka (MIS 5c). The top of the succession is dated to ~70 ka. The MIS 5e marine maximum flooding surface is identified at an elevation of 6.85 m above mean seal level. This elevation provides evidence of a regional sea-level highstand for this sector of the Cantabrian coast.  相似文献   

Identification and explanation of continental differences in the variability of annual runoff     

Murray C. Peel  Thomas A. McMahon  Brian L. Finlayson  Fred G. R. Watson 《Journal of Hydrology》2001,250(1-4):224-240

Continental differences in the variability of annual runoff were investigated using an expanded and improved database to that used in previous work. A statistical analysis of the data, divided by continent and Köppen climate type, revealed that continental differences exist in the variability of annual runoff. The variability of annual runoff for temperate Australia, arid southern Africa and possibly temperate southern Africa were noted to be generally higher than that of other continents with data in the same climate type. A statistical analysis of annual precipitation by continent and Köppen climate type revealed that differences in the variability of annual precipitation could account for some but not all the observed differences in the variability of annual runoff. A literature review of potential causes of continental differences in evapotranspiration resulted in the hypothesis that the significantly higher variability of annual runoff in temperate Australia and possibly temperate southern Africa may be due to the distribution of evergreen and deciduous vegetation. The process model Macaque was used to test this hypothesis. The model results indicate that the variability of annual runoff may be between 1 and 99% higher for catchments covered in evergreen vegetation as opposed to deciduous vegetation, depending on mean annual precipitation and the seasonality of precipitation. It is suggested that the observed continental differences in the variability of annual runoff are largely caused by continental differences in the variability of annual precipitation and in temperate regions the distribution of evergreen and deciduous vegetation in conjunction with the distribution of mean annual precipitation and precipitation seasonality.  相似文献