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Jin‐Jing Lee Cheng‐Shin Jang Sheng‐Wei Wang Chin‐Ping Liang Chen‐Wuing Liu 《水文研究》2008,22(16):3029-3041
This study characterized the redox conditions in arsenic‐affected groundwater aquifers of the Lanyang plain, Taiwan. Discriminant analysis was adopted to delineate three redox zones (oxidative, transitional and reductive zones) in different aquifers and yielded 92·3% correctness on groundwater quality data. Arsenic is mainly distributed in the reductive zone, and arsenic distribution in the shallow aquifer is mainly affected by surface activities. According to PHREEQC modelling results, possible mechanisms for arsenic release to groundwater in Lanyang plain are explored. Arsenic released to groundwater in the oxidative zone (zone 1) is primarily caused by the oxidations of arsenic‐bearing pyrite minerals, and arsenate is the predominant species. While the reductive dissolution of Fe‐oxides are responsible for the high arsenic concentration found in the transitional and reductive zones (zones 2 and 3), arsenite is the predominant species. The reduction potential of groundwater rises as the depths and zones increase. Some sulphates may be reduced to form sulphide ions, which then react with arsenic to form arseno‐sulphide deposits (such as realgar, orpiment) and then slightly lower groundwater arsenic concentrations. A conceptual diagram which summarized the possible release processes of arsenic in different redox zones along groundwater flow in Lanyang plain is postulated. Arsenic‐bearing pyrite and arsenopyrite (FeAsS) are oxidized as they are exposed to the infiltrated oxygenated rainwater, releasing soluble arsenate Fe(II) and SO42? into zone 1. The dissolution of arsenic‐rich Fe‐oxides due to the onset of reducing conditions in zones 2 and 3 is responsible for the mobility of arsenic and likely to be the primary mechanism of arsenic release to groundwater in the Lanyang plain Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
105.
S. Young † C. Packham R. E. Mason J. T. Radomski C. M. Telesco 《Monthly notices of the Royal Astronomical Society》2007,378(3):888-892
We present spatially resolved 10-μm spectra of the nucleus of IC 5063 that are near-diffraction-limited. The observations were obtained with T-ReCS, the mid-infrared (mid-IR) imager and spectrometer on the 8.1-m Gemini South telescope, with the slit aligned at a position angle on the sky along the direction of the cone of narrow-line emission. The spectra cover the nucleus and the inner reaches of the ionization cones at a spatial resolution of approximately 0.4 arcsec (90 pc). Individual spectra, extracted in steps in the spatial direction along the slit, reveal variations in continuum slope and silicate feature profile and depth on subarcsecond scales, illustrating in unprecedented detail the complexity of the circumnuclear regions of this galaxy at mid-IR wavelengths. The dust population in the vicinity of the narrow-line region, north-west of the nuclear position, is significantly warmer than that to the south-east of the nucleus. This is consistent with an observation of the cooler dust associated with the outer reaches of the postulated torus that obscures the type 1 nucleus in this object. 相似文献
106.
The effects of frictional forces acting on the sidewalls of buried box culverts are presented as determined with finite element method (FEM) and detailed soil modelling. The possibility of reducing earth pressure on deeply buried concrete box culverts by the imperfect trench installation (ITI) method has been contemplated during the last several decades. There have been limited research results published primarily regarding the qualitative aspect of load reduction in ITIs. It was found during the course of this study that significant frictional forces develop along the sidewalls of box culverts and adjacent sidefills in ITIs. Current American Association of State Highway and Transportation Officials provisions do not consider these frictional forces, but they cannot be neglected in ITIs, as their effect is dominant. An optimum geometry for the soft zone in ITIs is presented to maximize earth load reductions. The soil–structure interaction at the box culvert–soil interface was found to have a significant effect on total earth pressure acting on the bottom slab. Predictor equations for earth load reduction rates were formulated for ITIs incorporating the optimum soft zone geometry based on the FEM. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
107.
Christopher Ke-shih Young 《Monthly notices of the Royal Astronomical Society》2004,354(4):1011-1019
108.
JUN Ki Cheon JEONG Weon Mu CHOI Jin Yong PARK Kwang Soon JUNG Kyung Tae KIM Mee Kyung CHAE Jang Won QIAO Fangli 《海洋学报(英文版)》2015,34(12):19-28
Record-breaking high waves occurred during the passage of the typhoon Bolaven (1215) (TYB) in the East China Sea (ECS) and Yellow Sea (YS) although its intensity did not reach the level of a super typhoon. Winds and directional wave measurements were made using a range of in-situ instruments mounted on an ocean tower and buoys. In order to understand how such high waves with long duration occurred, analyses have been made through measurement and numerical simulations. TYB winds were generated using the TC96 typhoon wind model with the best track data calibrated with the measurements. And then the wind fields were blended with the reanalyzed synoptic-scale wind fields for a wave model. Wave fields were simulated using WAM4.5 with adjustment of Cd for gust of winds and bottom friction for the study area. Thus the accuracy of simulations is considerably enhanced, and the computed results are also in better agreement with measured data than before. It is found that the extremely high waves evolved as a result of the superposition of distant large swells and high wind seas generated by strong winds from the front/right quadrant of the typhoon track. As the typhoon moved at a speed a little slower than the dominant wave group velocity in a consistent direction for two days, the wave growth was significantly enhanced by strong wind input in an extended fetch and non-linear interaction. 相似文献
109.
To understand the temporal and spatial variation of the prokaryotic community in the East Sea, their composition was determined by polymerase chain reaction (PCR)-denaturing gradient gel electrophoresis (DGGE)-sequencing techniques. The investigations were conducted twice annually in 2007 and 2009 in coastal and offshore stations. Prokaryotic abundance (PA), leucine incorporation rate, and other environmental parameters were also measured. By using the DGGE approach, we obtained 283 bacterial sequences and 160 archaeal sequences. The most frequently detected bacterial phylotypes during the investigations belonged to Alphaproteobacteria, Gammaproteobacteria, and Bacteroidetes. However, their relative compositions differed in time and space. Although Alphaproteobacteria and Bacteroidetes were the dominant groups in the surface water in May 2007 and in May and October 2007, Gammaproteobacteria was dominant in mesopelagic samples. However, Gammaproteobacteria was overwhelmingly dominant in most samples in August 2009. Although Deltaproteobacteria was rarely found as a dominant bacterial group, it occupied the highest fraction in a mesopelagic sample in October 2007. Epsilonproteobacteria also showed a similar trend, although its maximal dominance was found in a mesopelagic sample in August 2009. The archaeal community was dominated overwhelmingly by members of the Euryarchaeota in most of the investigations. However, Nitrosopumilales was dominant in aphotic samples in August 2009. Further, their spatiotemporal composition at the family level changed more dynamically in the East Sea. These temporal and spatial distributions of the prokaryotic community were influenced mainly by seawater temperature and depth in the East Sea. 相似文献
110.
G. F. HERZOG David FINK Jeffrey KLEIN Donald D. BOGARD L. E. NYQUIST C.‐Y. SHIH D. H. GARRISON Young REESE J. MASARIK R. C. REEDY G. RUGEL T. FAESTERMANN G. KORSCHINEK 《Meteoritics & planetary science》2011,46(2):284-310
Abstract– We report measurements of cosmogenic nuclides in up to 11 bulk samples from various depths in Norton County. The activities of 36Cl, 41Ca, 26Al, and 10Be were measured by accelerator mass spectrometry; the concentrations of the stable isotopes of He, Ne, Ar, and Sm were measured by electron and thermal ionization mass spectrometry, respectively. Production rates for the nuclides were modeled using the LAHET and the Monte Carlo N‐Particle codes. Assuming a one‐stage irradiation of a meteoroid with a pre‐atmospheric radius of approximately 50 cm, the model satisfactorily reproduces the depth profiles of 10Be, 26Al, and 53Mn (<6%) but overestimates the 41Ca concentrations by about 20%. 3He, 21Ne, and 26Al data give a one‐stage cosmic‐ray exposure (CRE) age of 115 Ma. Argon‐36 released at intermediate temperatures, 36Arn, is attributed to production by thermal neutrons. From the values of 36Arn, an assumed average Cl concentration of 4 ppm, and a CRE age of 115 Ma, we estimate thermal neutron fluences of 1–4 × 1016 neutrons cm?2. We infer comparable values from ε149Sm and ε150Sm. Values calculated from 41Ca and a CRE age of 115 Ma, 0.2–1.4 × 1016 neutrons cm?2, are lower by a factor of approximately 2.5, indicating that nearly half of the 149Sm captures occurred earlier. One possible irradiation history places the center of proto‐Norton County at a depth of 88 cm in a large body for 140 Ma prior to its liberation as a meteoroid with a radius of 50 cm and further CRE for 100 Ma. 相似文献