Crystal-field theory calculations for Fe2+ Ions in bronzite,augite, and olivine     

Takahiro Hiroi  Hiroshi Takeda 《Physics and Chemistry of Minerals》1992,19(4):229-235

Crystal-field theory was applied to Fe²⁺ ions in three types of silicates in an attempt to assign all the major absorption bands with only one parameter to adjust. Coulomb potential energy field were calculated by Fourier method based on all the actual atomic coordinates refined by X-ray diffraction studies. Perturbed d-electron splitting energies of the central Fe²⁺ ion were calculated by introducing Configuration Interaction (CI) method for the lowest energy spectral states. All the major absorption bands observed in powdered bronzite, augite, and olivine, were assigned to the transitions between those calculated energy levels by optimizing only one parameter that expresses expansion or contraction of d-electron cloud. The result of the calculations gives almost the same assignments as the other previous works for bronzites, different assignments for augites, and a possibility of the existence of the fourth band hidden in the composite 1-μm band of olivines.  相似文献   

The Increase of Biogenic Sulfate Aerosol and Particle Number in Marine Atmosphere over the Northwestern North Pacific     

Atsushi Ooki  Kazuhiko Miura  Mitsuo Uematsu 《Journal of Oceanography》2003,59(6):799-807

During a cruise aboard the R/V Hakuho-maru in the northwestern North Pacific in the summer of 1998 the particle number concentrations and the major ionic components of size fractionated aerosols were measured to investigate the aerosol produced by marine biological activity. Continuous low concentrations of nitrate (<1.8 nmol m⁻³), similar to the marine air background level, were found over the northwestern North Pacific (40–45°N) and the Sea of Okhotsk (44–45°N). Over the Sea of Okhotsk, a high concentration of chlorophyll-a (5.4 mg m⁻³) in seawater was observed, and atmospheric concentrations of non sea-salt (nss-) sulfate (44 nmol m⁻³), methane sulfonic acid (MSA) (1.8 nmol m⁻³) and particle number in the size range of 0.1 < D < 0.5 μm (199 cm⁻³) were found to be 9, 7, and 2 times, respectively, higher than those in the background marine air. The increase in particle number concentrations mainly in the size range of 0.2 < D < 0.3 μm was likely caused by the increase of biogenic sulfate over the high productive region of the Sea of Okhotsk. In humid air conditions (R.H. > 96%), the increased biogenic sulfate that condensed the large amount of water vapor would not have sufficient solute mass to activate as cloud condensation nuclei (CNN) and would remain as aerosol particles in the marine air with frequent sea-fogs over the high productive region. Biogenic sulfate originating from dimethyl sulfide (DMS) would gradually grow into the CCN size and continuously supply a great number of CCN to the marine air in the northwestern North Pacific. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Distribution pattern and morphochemical relationships of manganese nodules from the Central Indian Basin     

Ranadip Banerjee  Hiroyuki Miura 《Geo-Marine Letters》2001,21(1):34-41

In the Central Indian Basin manganese nodule abundance was variable in all sediment types. Mean abundance varied from 1.5 in calcareous ooze to 10.2 kg/m² in terrigenous-siliceous ooze sediments. Nodule grade and growth rates are positively correlated only up to 10 mm/My (million years), and grade shows no distinct relationship with abundance. Relationships between the morphochemical characteristics of the nodules and host sediment types are subtle. Both hydrogenetic and diagenetic nodules (with smooth and rough surfaces respectively) occur on almost all sediments, but in variable proportions. Thus, the overall distribution pattern shows that small nodules (<4-cm diameters) of lower grade (average value Ni+Cu+Co=1.21%) with smooth surfaces are more common on red clay, terrigenous, and terrigenous-siliceous ooze transition-zone sediments. By contrast, large nodules (>4-cm diameters) of higher grade (average value Ni+Cu+Co=1.80%) with rough surfaces are more prevalent on siliceous ooze, siliceous ooze-red clay, and calcareous ooze-red clay transition-zone sediments. This implies an enhanced supply of trace metals from pore waters to rough-surface nodules during early diagenesis.  相似文献   

Tidal Mixing in the Kuril Straits and Its Impact on Ventilation in the North Pacific Ocean     

Tomohiro Nakamura  Takahiro Toyoda  Yoichi Ishikawa  Toshiyuki Awaji 《Journal of Oceanography》2004,60(2):411-423

A numerical study using a 3-D nonhydrostatic model has been applied to baroclinic processes generated by the K ₁ tidal flow in and around the Kuril Straits. The result shows that large-amplitude unsteady lee waves are generated and cause intense diapycnal mixing all along the Kuril Island Chain to levels of a maximum diapycnal diffusivity exceeding 10³ cm²s⁻¹. Significant water transformation by the vigorous mixing in shallow regions produces the distinct density and potential vorticity (PV) fronts along the Island Chain. The pinched-off eddies that arise and move away from the fronts have the ability to transport a large amount of mixed water (∼14 Sv) to the offshore regions, roughly half being directed to the North Pacific. These features are consistent with recent satellite imagery and in-situ observations, suggesting that diapycnal mixing within the vicinity of the Kuril Islands has a greater impact than was previously supposed on the Okhotsk Sea and the North Pacific. To examine this influence of tidal processes at the Kurils on circulations in the neighboring two basins, another numerical experiment was conducted using an ocean general circulation model with inclusion of tidal mixing along the islands, which gives a better representation of the Okhotsk Sea Mode Water than in the case without the tidal mixing. This is mainly attributed to the added effect of a significant upward salt flux into the surface layer due to tidal mixing in the Kuril Straits, which is subsequently transported to the interior region of the Okhotsk Sea. With a saline flux into the surface layer, cooling in winter in the northern part of the Okhotsk Sea can produce heavier water and thus enhance subduction, which is capable of reproducing a realistic Okhotsk Sea Mode Water. The associated low PV flux from the Kuril Straits to the open North Pacific excites the 2nd baroclinic-mode Kelvin and Rossby waves in addition to the 1st mode. Interestingly, the meridional overturning in the North Pacific is strengthened as a result of the dynamical adjustment caused by these waves, leading to a more realistic reproduction of the North Pacific Intermediate Water (NPIW) than in the case without tidal mixing. Accordingly, the joint effect of tidally-induced transport and transformation dominating in the Kuril Straits and subsequent eddy-transport is considered to play an important role in the ventilation of both the Okhotsk Sea and the North Pacific Ocean. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Application of Sensitivity Analysis Using an Adjoint Model for Short-Range Forecasts of the Kuroshio Path South of Japan     

Yoichi Ishikawa  Toshiyuki Awaji  Nobumasa Komori  Takahiro Toyoda 《Journal of Oceanography》2004,60(2):293-301

A sensitivity experiment has been performed by assimilating altimetric data into a 1.5-layer primitive equation model as a first attempt to examine the impact of initialization on forecasts of the Kuroshio path variability south of Japan. By exploiting the advantage of an adjoint model, our approach clearly shows that a small meander off Shikoku Island has a large impact on the prediction of meander growth in the Kuroshio region. Further, the strengthening of the Kuroshio current and its recirculation clearly becomes an important factor in the development of the meander. These results demonstrate the effectiveness of our assimilation approach in identifying efficient initialization schemes on numerical forecasting of the Kuroshio south of Japan and should help in the construction of an effective observing system for improving the forecasting. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The Kyucho in the Bungo Channel,Japan —Periodic intrusion of oceanic warm water     

Hidetaka Takeoka  Hideki Akiyama  Takahiro Kikuchi 《Journal of Oceanography》1993,49(4):369-382

Kyucho is a sudden and swift current which is usually accompanied by rise of water temperature. Several features of the Kyucho in the Bungo Channel, Japan, are presented through field observations. The Kyucho in the Bungo Channel is an intrusion of warm water from the Pacific Ocean into the eastern half of the Bungo Channel, being driven gravitationally and advancing along the eastern coast of the channel. The Kyucho occurs usually in summer and seldom occurs in winter. It occurs at neap tides showing the prominent spring-neap periodicity. The modulation of the vertical mixing intensity associated with the variations of tidal current, wind and surface heating etc. is supposed to be a main cause of springneap and seasonal periodicities.  相似文献   

Effects of bottom topography and density stratification on variations of western boundary currents caused by periodic change in wind stress     

Hideo Miura  Nobuo Suginohara 《Journal of Oceanography》1984,40(1):67-79

Variations of the western boundary currents induced by a periodic change in wind stress are studied in a two-layer model with a continental slope along the western boundary. The variation of the total transport of the western boundary current over the continental slope shows a considerable phase lag with the wind stress and a decrease in amplitude compared with for the flat bottom ocean, though the interior barotropic response is to adjust almost instantaneously to the wind stress. The total transport variation of the western boundary current is well approximated by the upper layer transport variation. That is, almost complete separation of the upper- and lower-layer flows takes place over the slope, and only the upper layer flow contributes to the change in total transport of the western boundary current. Contributions of the interior barotropic and baroclinic responses to the upper layer transport variation depend on the forcing period. With decrease in the forcing period, the barotropic response becomes relatively important for determining the upper layer transport variation although the amplitude of the variation is smaller.  相似文献   

Induction of female‐to‐male sex change in a large protogynous fish,Choerodon schoenleinii          下载免费PDF全文

Taku Sato  Masato Kobayashi  Takayuki Takebe  Narisato Hirai  Koichi Okuzawa  Sayumi Sawaguchi  Takahiro Matsubara  Tomofumi Yamaguchi  Rihito Shinoda  Masahiko Koiso  Kazuhisa Teruya 《Marine Ecology》2018,39(1)

Most behavioral studies on hermaphroditic fishes have focused on small‐sized species, which are tractable for research. Although many species of large hermaphroditic fishes are important fishery resources, their proximate mechanisms (visual, chemical and/or behavioral cues) in the social regulation of sex change have not been determined. Determination of these would inform resource management and aquaculture. In order to get closer to understanding the proximate mechanisms underlying the social regulation of female‐to‐male sex change in large hermaphroditic fishes, this study reports situations that induced female‐to‐male sex change in black‐spot tuskfish, Choerodon schoenleinii, a species of large protogynous fish, in massive laboratory tanks. The situations differed in the possibility of male‐to‐female tactile contact and in the group sex ratio, enabling us to infer plausible proximate mechanisms underlying sex change induction. Tactile contact between individuals is suspected to be closely related to the incidence of female‐to‐male sex change in C. schoenleinii. Visual and chemical cues alone may be insufficient to inhibit such sex changes. Male‐to‐female tactile contact may have an important influence on female‐to‐male sex change, i.e., inhibition of this sex change, in this species. The effect of sex ratio of a social group on the incidence of sex change may be due to the relative frequency and intensity of male tactile contact with each female, which may vary with the number of females. In the absence of a dominant male, tactile contact among females may affect the incidence of sex change, as well as determine which individuals change sex.  相似文献   

Dating pseudotachylyte of the Asuke Shear Zone using zircon fission-track and U–Pb methods     

Masaki Murakami  Jan Ko&#x;ler  Hideo Takagi  Takahiro Tagami 《Tectonophysics》2006,424(1-2):99-107

Zircon fission-track (FT) and U–Pb analyses were performed on zircon extracted from a pseudotachylyte zone and surrounding rocks of the Asuke Shear Zone (ASZ), Aichi Prefecture, Japan. The U–Pb ages of all four samples are  67–76 Ma, which is interpreted as the formation age of Ryoke granitic rocks along the ASZ. The mean zircon FT age of host rock is 73 ± 7 (2σ) Ma, suggesting a time of initial cooling through the zircon closure temperature. The pseudotachylyte zone however, yielded a zircon FT age of 53 ± 9 (2σ) Ma, statistically different from the age of the host rock. Zircon FTs showed reduced mean lengths and intermediate ages for samples adjacent to the pseudotachylyte zone. Coupled with the new zircon U–Pb ages and previous heat conduction modeling, the present FT data are best interpreted as reflecting paleothermal effects of the frictional heating of the fault. The age for the pseudotachylyte coincides with the change in direction of rotation of the Pacific plate from NW to N which can be considered to initialize the NNE–SSW trending sinistral–extensional ASZ before the Miocene clockwise rotation of SW Japan. The present study demonstrates that a history of fault motions in seismically active regions can be reconstructed by dating pseudotachylytes using zircon FT thermochronology.  相似文献   

AFM study on surface nanotopography of matrix olivines in Allende carbonaceous chondrite     

Jun Nozawa  Junya Yamada  Ken Nagashima  Hitoshi Miura 《Icarus》2009,204(2):681-654

By means of nanoscale surface observation, we have proposed a new approach for investigating fine crystals of cosmic materials to reveal their origin and growth conditions. Several different morphologies of polyhedral fine olivines with faceted faces have been found in Allende carbonaceous chondrite (4.5 byr in geochronological age). In the present work, molecular level topography of the faceted matrix olivine by Atomic Force Microscopy (AFM) has successfully been performed. The matrix olivine found to have preserved growth step pattern on its surface even though quite long time has passed since they formed in the early Solar System. The surface pattern suggests that the faceted matrix olivine could have been condensed from the gas phase, and possibly that these olivine crystals had continued to grow under a rapid cooling condition (0.1-1 K s⁻¹). The estimated cooling rate agrees well with predictions based on hypothetical rapid heating and cooling events such as shock wave heating.  相似文献