Iron oxidation state of a 2.45-Byr-old paleosol developed on mafic volcanics     

Satoshi Utsunomiya  Takashi Murakami  Takeshi Kasama 《Geochimica et cosmochimica acta》2003,67(2):213-221

The 2.45-Byr-old weathering profile developed on early Proterozoic mafic volcanics located near Cooper Lake, Ontario, Canada, was examined geochemically and mineralogically for a better understanding of the atmospheric oxygen evolution. Ferrous to ferric ion, Fe(II) and Fe(III), respectively, ratios of the bulk rock samples were analyzed by Mössbauer spectrometry. The total Fe (Fe(T)) and Fe(II) concentrations decrease from 12.0 and 11.2 wt.% to 1.85 and 0.89 wt.%, respectively, from the bottom to the top of the weathering profile. The Fe(T) and Fe(II) concentrations normalized to Ti and Zr, as well as the Fe(II)/Fe(III) ratio of raw data, linearly decrease with depth toward the top, while the Fe(III) concentration remains nearly constant throughout the profile. The linear decrease of Fe(II), accompanied by the nearly constant distribution of Fe(III), is difficult to be explained by the scenario of oxidizing weathering and subsequent reducing hydrothermal alteration. The behaviors of Fe(II) and Fe(III) can be simply explained by anoxic weathering. The anoxic weathering suggests that the 2.45-Ga atmosphere was anoxic. The slight increase of Fe/(Fe+Mg) in the octahedral sites of chlorite toward the top and no Ce anomaly in the REE patterns are also consistent with anoxic weathering.  相似文献   

青藏高原局地因素对近地表层地温的影响   总被引：23，自引：6，他引：23  

王绍令  丁永建  赵林  小池俊雄 《高原气象》2002,21(1):85-89

青藏高原近地表层地温既受区域性因素（高度、经度、纬度）控制，同时又受局地因素的影响。观测结果表明，高原稀疏植被地段比裸地地温高，短时期薄层雪盖起降低地温的作用，南坡比北坡地温高2－7℃，黑色沥青路面年平均温度比碎石土天然的年平均地表温度高4．5℃，亦高于其它材料的路面地温。  相似文献   

Neural Network-Based Estimation of Principal Metal Contents in the Hokuroku District,Northern Japan,for Exploring Kuroko-Type Deposits   总被引：7，自引：0，他引：7  

Koike  Katsuaki  Matsuda  Setsuro  Suzuki  Toru  Ohmi  Michito 《Natural Resources Research》2002,11(2):135-156

The Hokuroku district, extending over 40 × 40 km² in northern Japan, is known to be dominated by kuroko-type massive sulfide deposits that have a genetic relation to submarine volcanic activity. The deposits are hosted in a specific stratigraphic zone of Miocene volcanic rocks. Because kuroko-type deposits are under exploration in several countries, it is important to integrate the geologic and geochemical data that have been accumulated in the Hokuroku district to characterize the distribution of deposits and produce a map of mineral potential. Thus, we collected data on multiple chemical components from 1917 rock cores at 143 drillhole sites and concentrated on components with relatively large amounts of data, which are SiO₂, Al₂O₃, and Fe₂O₃ as major elements and Cu, Pb, and Zn as trace elements. Although frequencies of these data can be approximated by normal or lognormal distributions, spatial correlation structures cannot be extracted from the semivariograms of each component nor from the cross-semivariograms between two components of the major or minor elements. To handle such complexity, a spatial method of modeling content distribution, SLANS, is developed by applying a feedforward neural network. The principle of SLANS is to train a network repeatedly to recognize the relation between the data value and the location and lithology of a sample point. One-hundred outputs for each element are obtained by changing the numbers of neurons in a middle layer from 1 to 10 and sample data used for training from 3 to 12, and finally one output is selected based on the estimation precision of the network which is restricted near the target point. After constructing a geologic distribution model from the geological column classified into 25 rock codes, three-dimensional distributions of Cu, Pb, and Zn contents are estimated over the study area. The content models are considered to be valid because high-content zones are located on the known mine sites and the margins of ancient volcanoes or calderas. Some zones are distributed along strikes of major deep-seated fractures in the district.  相似文献   

Late quaternary sediment budget in alluvial-fan–source-basin systems in Japan     

Takashi Oguchi 《第四纪科学杂志》1997,12(5):381-390

Sediment budgets since the Late-glacial were constructed for five alluvial-fan–source-basin systems in Japan. The Late-glacial and Holocene sediment yield from each source area was estimated based on digital elevation data and the morphometric analyses of geomorphological maps, in which all hillslopes and fluvial surfaces were classified. Late-glacial and Holocene sediment storage in each fan was calculated from stratigraphical data. The results have revealed that the ratio of sediment storage in a fan to sediment supply is between ca. 0.3 and 0.8. Such high ratios of sediment storage over long time periods cast doubt on the previously proposed steady-state theory of alluvial fan development. The storage ratio decreases if fan sediments are removed by neighbouring large rivers. The maximum storage ratio of 0.8 reflects the ratio of washload to total load for Japanese mountain rivers. © 1997 John Wiley & Sons, Ltd.  相似文献   

Effect of canopy openness and meteorological factors on spatial variability of throughfall isotopic composition in a Japanese cypress plantation   总被引：1，自引：0，他引：1       下载免费PDF全文

Xinchao Sun  Yuichi Onda  Akiko Hirata  Hiroaki Kato  Takashi Gomi  Xueyan Liu 《水文研究》2018,32(8):1038-1049

Spatial variability of throughfall (TF) isotopic composition, used as tracer input, influences isotope hydrological applications in forested watersheds. Notwithstanding, identification of the dominant canopy factors and processes that affect the patterns of TF isotopic variability remains ambiguous. Here, we examined the spatio‐temporal variability of TF isotopic composition in a Japanese cypress plantation, in which intensive strip thinning was performed and investigated whether canopy structure at a fine resolution of canopy effect analysis is related to TF isotopic composition and how this is affected by meteorological factors. Canopy openness, as an index of canopy structure, was calculated from hemispherical photographs at different zenith angles. TF samples were collected in a 10 × 10 m experimental plot in both pre‐thinning (from July to November 2010) and post‐thinning (from May 2012 to March 2013) periods. Our results show that thinning resulted in a smaller alteration of input δ¹⁸O of gross precipitation, whereas the changes in deuterium excess varied in both directions. Despite the temporal stability of spatial patterns in TF amount, the spatial variability of TF isotopic composition was not temporally stable in both pre‐ and post‐thinning periods. Additionally, after thinning, the isotopic composition of TF was best related to canopy openness calculated at the zenith angle of 7°, exhibiting three different relationships, that is, significantly negative, significantly positive, and nonsignificant. Changes in meteorological factors (wind speed, rainfall intensity, and temperature) were found to affect the relationships between TF δ¹⁸O and canopy openness. The observed shifts in the relationships reveal different dominant factors (partial evaporation and the selection), and canopy water flowpaths control such differences. This study provides useful insights into the spatial variability of TF isotopic composition and improves our understanding of the physical processes of interception through canopy passage.  相似文献   

Characterization of sulfate mineral deposits in central Thailand          下载免费PDF全文

Junichiro Kuroda  Hidetoshi Hara  Katsumi Ueno  Thasinee Charoentitirat  Teruyuki Maruoka  Takashi Miyazaki  Akira Miyahigashi  Stefano Lugli 《Island Arc》2017,26(2)

In this paper we present petrographic and geochemical data of sulfate mineral deposits in northeast Nakhon Sawan, central Thailand, and provide new constraints on their age. The deposits are made up mainly of strongly deformed nodular and massive gypsum in the upper part, and less deformed layered anhydrite in the lower part. They are intruded by andesitic dikes that contain Middle Triassic zircons (ca 240 Ma). These dikes are probably part of the regional magmatic activity of the Sukhothai Arc during the Early to Middle Triassic. Sulfur (δ³⁴S) and strontium (⁸⁷Sr/⁸⁶Sr) isotopic compositions of the sulfates range from 15.86 ‰ to 16.26 ‰ and from 0.70810 to 0.70817, respectively. Comparisons with the Phanerozoic seawater isotopic evolution curve indicate that those values are best explained by precipitation of the sulfates from Carboniferous seawater, in particular seawater of late Mississippian age (ca 326 Ma), and this would be consistent with previous studies of calcareous fossils in the limestones that crop out around this site. Our interpretation is that evaporitic gypsum was originally precipitated from hypersaline seawater on a shallow lagoon or shelf on the Khao Khwang Platform during the Serpukhovian, and that this gypsum changed to anhydrite during early burial. The anhydrite was then cut by andesitic dikes during the Middle Triassic, and more recently the upper part of which was rehydrated during exhumation to form secondary gypsum near the surface.  相似文献   

Fluvial to bay sequence stratigraphy and seismic facies of the Cretaceous to Paleogene successions in the MITI Sanriku‐oki well and the vicinities,the Sanriku‐oki forearc basin,northeast Japan          下载免费PDF全文

Osamu Takano  Takashi Tsuji 《Island Arc》2017,26(4)

This paper describes the significant depositional setting information derived from well and seismic survey data for the Upper Cretaceous to Lower Eocene forearc basin sediments in the central part of the Sanriku‐oki basin, which is regarded as a key area for elucidating the plate tectonic history of the Northeast Japan Arc. According to the results of well facies analysis utilizing cores, well logs and borehole images, the major depositional environments were of braided and meandering fluvial environments with sporadically intercalated marine incursion beds. Seismic facies, reflection terminations and isopach information provide the actual spatial distributions of fluvial channel zones flowing in a north–south trending direction. The transgression and regression cycles indicate that the Upper Cretaceous to Lower Eocene successions can be divided into thirteen depositional sequences (Sequences SrCr‐0 to SrCr‐5, and SrPg‐1 to SrPg‐7). These depositional sequences demonstrate three types of stacking patterns: Types A to C, each of which shows a succession mainly comprising a meandering fluvial system, a braided fluvial system with minor meandering aspects in the upper part, and major marine incursion beds in the middle part, respectively, although all show an overall transgressive to regressive succession. The Type C marine incursion beds characteristically comprise bay center and tidal‐dominated bay margin facies. Basin‐transecting long seismic sections demonstrate a roll up structure on the trench slope break (TSB) side of the basin. These facts suggest that during the Cretaceous to Eocene periods, the studied fluvial‐dominated forearc basin was sheltered by the uplifted TSB. The selective occurrences of the Type C sequences suggest that when a longer‐scale transgression occurred, especially in Santonian and early Campanian periods, a large bay basin was developed, creating accommodation space, which induced the deposition of the Cretaceous Kuji Group along the arc‐side basin margin.  相似文献   

Spatial Simulation and Characterization of Three-Dimensional Fractures in Gejiu tin District,Southwest China,Using GEOFRAC     

Liu  Chunxue  Kubo  Taiki  Lu  Lei  Koike  Katsuaki  Zhu  Wenjie 《Natural Resources Research》2019,28(1):99-108

Natural Resources Research - Fracture is an important factor controlling mineralization and ore distribution in metallic deposits. Fracture also affects mechanical stability of drifts. A plausible...  相似文献   

Redeposition of volcaniclastic sediments by a tsunami 4600 years ago at Kushima City,south-eastern Kyushu,Japan     

Masaki Yamada  Shigehiro Fujino  Takashi Chiba  Kazuhisa Goto  James Goff 《Sedimentology》2020,67(3):1354-1372

The Hyuga-nada Sea, south-eastern Kyushu, Japan, is located between a strong (Nankai Trough) and a weak interplate coupling zone (Ryukyu Trench). Over the past 400 years this area has only experienced Magnitude 7·5 earthquakes or smaller and associated small-scale tsunamis. However, this short historical record most likely does not include the full range of high magnitude, low frequency giant earthquakes that might have occurred in the region. Thus, it is still unclear whether giant earthquakes and their associated tsunamis have occurred in this region. This paper reports on a prehistoric tsunami deposit discovered in a coastal lowland in south-eastern Kyushu facing the Hyuga-nada Sea. There is a reddish-brown pumiceous layer preserved in a non-marine, organic-rich mud sequence obtained from onshore sediment cores. This layer is recognized as the ca 4600 year old Kirishima-Miike tephra (that is now placed around 4500 years ago) sourced from Mount Kirishima, southern Kyushu. Another whitish pumiceous layer is evident below the Kirishima-Miike tephra in almost all of the sediment cores. A relatively high percentage of marine and brackish diatoms is recorded within this lower pumiceous layer (but not in the surrounding muds or in the overlying Kirishima-Miike tephra), indicating a marine or beach sediment source. Plant material obtained from organic-rich mud immediately below the event layer was dated to ca 4430 to 4710 cal yr bp , providing a limiting-maximum age for this marine incursion event. The presence of marine diatoms below the event layer is probably explained by pre-seismic subsidence. An absence of the resting spore of the planktonic brackish diatom Cheatoceros and the appearance of the freshwater diatom Eunotia serra immediately above the event layer probably represents a marked change to a relatively low-salinity environment. Assuming that there were no significant local geomorphological changes, such as drainage obstruction caused by formation of a new barrier spit, it is considered that co-seismic or immediate post-seismic uplift are the most likely explanations for this notable environmental change. Based on the crustal movements noted before and after the marine incursion, this event is interpreted here as an earthquake-generated tsunami. Moreover, because of these notable seismic crustal movements the tsunamigenic earthquake probably occurred immediately offshore of the study site.  相似文献   

Influence of non-photosynthetic pigments on light absorption and quantum yield of photosynthesis in the western equatorial Pacific and the Subarctic North Pacific     

Anil Kumar Vijayan  Takashi Yoshikawa  Shigeki Watanabe  Hiroaki Sasaki  Kazuhiko Matsumoto  Sei-Ichi Saito  Shigenobu Takeda  Ken Furuya 《Journal of Oceanography》2009,65(2):245-258

Regional variations in the contribution of non-photosynthetic pigments (ā _np^*) to the total light absorption of phytoplankton (ā _ph^*) and its influence on the maximum quantum yield of photosynthesis (φ _m) were investigated. In the western equatorial Pacific, the surface ā _np^* : ā _ph^* ratio was higher in the western warm pool than that in the upwelling region. This difference appears to be attributable to severe nitrate depletion and higher percentage of prokaryotes, which can accumulate very high concentrations of zeaxanthin in the western warm pool. In the subarctic North Pacific, the ā _np^* : ā _ph^* ratio was expected to be higher in the Alaskan Gyre where the thermocline is sharper and iron limitation may possibly be more severe than in the Western Subarctic Gyre. However, the ratio was actually higher in the Western Subarctic Gyre, contradictory to our expectations. This east-west variation appears to be attributable to changes in the taxonomic composition; cyanobacteria were more abundant in the Western Subarctic Gyre. The values of ā _np^* : ā _ph^* and its vertical variations were relatively small in the subarctic North Pacific compared to those in the western equatorial Pacific. These inter-regional variations appear to be attributable to the lower solar radiation intensity, smaller percentage of cyanobacteria, and relatively strong vertical mixing in the subarctic North Pacific. The spatial variations in ā _np^* : ā _ph^* significantly influence φ _m. In comparison with φ _m based on the total light absorption (φ _{m ph}), the values corrected for the contribution of non-photosynthetic pigments (φ _{m ps}) showed an increase in both the western equatorial Pacific and the subarctic North Pacific.  相似文献