A study on the chemical forms of radionuclides in seawater—II chloride and sulfate complexes of60Co     

Shigeki Hirano  Taku Koyanagi 《Journal of Oceanography》1980,36(1):35-38

The apparent stability constants for chloride and sulfate ions with Co (II) at ionic strength of 0.67 were determined by the cation exchange method. The value of the stability constant ₁ for chloride ion with Co (II) ion was 0.79±0.055. The stability constants ₁, ₂ and ₃ for sulfate ion with Co (II) ion were 12.0±0.27, 91.5±11.4 and l,110±250, respectively. The chemical species of Co (II) in seawater was estimated at the pH of 8.0 to be present as Co²⁺ (63%), CoCl⁺ (27%) and CoSO₄ ⁰ (8.6%) using the known value of dissociation constant of Co (II), and under the assumption that only major inorganic anions are responsible for the chemical equilibrium of Co (II).  相似文献   

Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature     

Ayako Shinozaki  Hiroyuki Kagi  Hisako Hirai  Hiroaki Ohfuji  Taku Okada  Satoshi Nakano  Takehiko Yagi 《Physics and Chemistry of Minerals》2016,43(4):277-285

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.  相似文献   

Application of WetSpass model to estimate groundwater recharge variability in the Nile Delta aquifer     

Asaad M. Armanuos  Abdelazim Negm  C. Yoshimura  Oliver C. Saavedra Valeriano 《Arabian Journal of Geosciences》2016,9(10):553

Long-term groundwater recharge from rainfall in the Nile Delta is needed as an input for integrated groundwater modelling in the Nile Delta aquifer for more accurate simulation. The main objective is to estimate the spatial and temporal variation of groundwater recharge from rainfall in the Nile Delta aquifer. Water and Energy Transfer between Soil, Plants and Atmosphere under quasi-Steady State (WetSpass) model parameters were identified for the Nile Delta based on the available meteorological data for the area collected in 1991 and 2000. The collected data were rainfall, temperature, wind speed and evapotranspiration. Geomorphological characteristics, such as soil type, topography, groundwater depth and slope, were also collected as input data for the WetSpass model. ENVI software was used to come up with land use classification based on available land cover images of the Nile Delta for 1972, 1984, 1990, 2000 and 2009. The WetSpass model was calibrated by comparing the simulated groundwater recharge with the calculated one by using the water balance equation model. The results indicated close agreement in groundwater recharge between the two model outputs with R ² of 0.99 and 0.94, while the root-mean-square errors (RMSEs) were 4.86 and 9.39 mm for 1991 and 2000, respectively. The WetSpass model was then applied in respect of 1970, 1980, 1990 and 2010 for the purpose of validation. The overall RMSE and R ² for the 6 years were 8.83 mm and 0.88, respectively. The results of the WetSpass calibrated model provide information to support integrated groundwater modelling. The results reveal that WetSpass works well in simulating the components of the hydrological balance in the Nile Delta.  相似文献   

Quality Assessment of Southeast Nile Delta Groundwater for Irrigation     

Mohamed Galal Eltarabily  Abdelazim M. Negm  Chihiro Yoshimura  Sommer Abdel-Abdel-Fattah  Oliver C. Saavedra 《Water Resources》2018,45(6):975-991

The Nile Delta aquifer has deteriorated in the quality of the groundwater due to domestic, agricultural and industrial activities. In order to examine this, a dataset of thirty-one shallow groundwater samples and four surface water samples were collected in May 2014. The objective of our study is to investigate the hydrochemical characteristics of the groundwater at El-Khanka region in El-Qalubia governorate, southern Nile Delta to discuss the possibility of groundwater use for agricultural purpose. Groundwater types were defined, and the suitability for use in irrigation was evaluated. The factor analysis was conducted to investigate the relationship between the thirteen variables for exploring the loading of them in the model. Then, the principal component analysis was performed to identify the linear combination of variables that account for the greatest amount of common variance. Results showed that groundwater samples are mainly alkaline with an average pH value of 8.60. The total dissolved solids (TDS) range from 350 to 1456 mg/L. The highest concentrations of the anions and cations are sulfate (\(\rm{SO}_4^{2-}\)) and sodium (Na⁺) respectively. The residual sodium carbonate (RSC) is less than 1.25 meq/L. Also, all groundwater samples are located in good and permissible salinity with TDS < 1500 mg/L. In addition, all samples are located in the low sodium hazard zone where sodium adsorption ratio (SAR) is less than 10. Therefore, it is concluded that, the groundwater is suitable for irrigation use in El-Qalubia Governorate. Four factors with Eigenvalues above 1.0 which correlated to each other contributed to the model with 81% of the total variance and governed the spatial variability of the aquifer.  相似文献   

Bathymetric influences of the Emperor Seamounts upon the subarctic gyre of the North Pacific: Examining boundary current dynamics along the eastern side of the mountain ridge with an idealized numerical model     

Taku Wagawa  Yutaka Yoshikawa  Akira Masuda 《Journal of Oceanography》2010,66(2):259-271

The possible influences of the Emperor Seamounts (ESs) upon the subarctic gyre of the North Pacific (NPSAG) were investigated by a series of numerical experiments. In the experiments, a two-layer ocean with a meridional mountain ridge was forced by seasonally varying wind stress. We focused on how the return ratio, the ratio of the boundary transport along the eastern side of the ridge to the interior Sverdrup transport, changes with ridge height, width and density stratification. It was found that the return ratio can be large if the ridge width is greater than the width of the viscous boundary layer. In this case, the bottom pressure torque determines the return ratio; the return ratio is almost proportional to the ridge height when the ridge height is small and some contours of planetary potential vorticity pass over the ridge. However, the return ratio is independent of the ridge height and decreases with the stratification when the ridge height is large and all the contours of planetary potential vorticity are closed. These dependences of the return ratio were understood in terms of barotropic and baroclinic components of the bottom pressure torque. Implications for the bathymetric influences of ESs on the actual NPSAG are also discussed.  相似文献   

Ab initio investigation into the elasticity of ultrahigh-pressure phases of SiO2     

Arnaud Metsue  Taku Tsuchiya 《Physics and Chemistry of Minerals》2012,39(3):177-187

In this study, we report the elastic properties of three ultrahigh-pressure phases of SiO₂: pyrite, cotunnite and Fe₂P types between 300 and 1,500 GPa calculated by means of the density functional ab initio method. It is generally thought that materials tend to be more compact and isotropic with increasing pressure. These three ultrahigh-pressure phases of silica are mechanically stable in the investigated pressure range according to the Born criteria, while the cotunnite and Fe₂P types are unstable at lower pressure. The elastic azimuthal anisotropy of these ultrahigh-pressure phases of silica shows that all the structures counterintuitively have considerable anisotropies even at multimegabar pressures. Among the three investigated structures, the cotunnite type of SiO₂ is the most elastically anisotropic phase due to a soft compression along the b axis combined with a large distortion of the polyhedrons that make the structure. This might also be related to its thermodynamic unfavorability compared to the Fe₂P type under extreme pressure condition. The bond property analyses clearly show that the Si–O bond remains an ionic-covalent mixed bond even at multimegabar pressures with an invariable ionicity with pressure. This argument can explain the monotonously pressure dependence of the elastic anisotropy in the case of pyrite, while the changes in the velocity distribution patterns out of the thermodynamic instability range largely contribute to those of the cotunnite and Fe₂P types.  相似文献   

Modeling low salinity waters along the coast around Japan using a high-resolution river discharge dataset     

L. Shogo Urakawa  Masao Kurogi  Kei Yoshimura  Hiroyasu Hasumi 《Journal of Oceanography》2015,71(6):715-739

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Community structure of culturable bacteria on surface of Gulkana Glacier, Alaska     

Takahiro Segawa  Yoshitaka Yoshimura  Kenichi Watanabe  Hiroshi Kanda  Shiro Kohshima 《Polar Science》2011,5(1):41

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A generic formulation for microtremor exploration methods using three-component records from a circular array   总被引：1，自引：0，他引：1  

Ikuo Cho  Taku Tada  Yuzo Shinozaki 《Geophysical Journal International》2006,165(1):236-258

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Time evolution of hydraulic and electrokinetic parameters around the Nojima fault, Japan, estimated by an electrokinetic method     

Hideki Murakami  Naoto Oshiman  Satoru Yamaguchi  Takeshi Hashimoto  Ryokei Yoshimura 《Tectonophysics》2007,443(3-4):200

The Nojima Fault Zone Probe was designed to study the properties and healing processes of the Nojima fault, which is the surface fault rupture of the Hyogo-ken Nanbu earthquake (M7.2) of 1995 (1995 Kobe earthquake). In this project, water injection experiments were conducted in a borehole of 1800 m depth at the Nojima fault. We set up electrodes around the borehole and observed self-potential variations to investigate the magnitude of electrokinetic and hydraulic parameters around the Nojima fault zone. In the 1997 experiment, self-potential variations were in the range of a few to about 20 mV across 320–450 m electrode dipoles with hydraulic pressure variations from 3.5 to 4 MPa. In the 2000 experiment, self-potential variations were in the range of a few to about 85 mV across 160–260 m electrode dipoles with the hydraulic pressure variations from 3 to 4.5 MPa. In the 2003 experiment, self-potential variations were in the range of a few to about 30 mV across 20–80 m electrode dipoles with hydraulic pressure of 4 MPa. These observed self-potential variations were explained well with an electrokinetic effect due to the underground flow of the injected water. From the observed results, we estimated that the ratio of hydraulic parameters (permeability, porosity, and tortuosity) to electrokinetic parameters (zeta potential and dielectric constant) decreased approximately 40% during eight years after the earthquake. This result suggests that the healing process around the fault zone progress.  相似文献