Organic matters and acid‐sulfate alteration in Itomuka mercury mine,Hokkaido, Japan: Implications for the transportation and deposition mechanisms of Hg     

Takuya Echigo  Mitsuyoshi Kimata  Masahiro Shimizu 《Resource Geology》2020,70(2):204-213

In order to examine the transportation and deposition mechanisms of Hg, we investigated the ore and hydrothermal alteration minerals and solid organic matters from Itomuka mercury mine located in the eastern part of central Hokkaido. In addition to the ore minerals, native mercury and cinnabar, quartz, marcasite, alunite, kaolinite, and minor amounts of pyrite and smectite were identified in the Hg ore by powder X‐ray diffraction (XRD) analysis. This mineral assemblage of acid sulfate alteration was likely developed under the conditions of low temperature (≤100°C) and low pH (≤2) in the steam‐heated environment. The H₂SO₄ was produced above the water table by the oxidation of H₂S separated from deep, near‐neutral fluids by boiling. The dominance of native mercury over cinnabar in Hg ore indicates that the greater part of mineralized Hg was transported as Hg⁰ in aqueous solution and vapor with low sulfur fugacity. The solid organic matters found in the Hg ore were analyzed with SEM‐EDS, micro‐XRD, and micro‐Fourier transform infrared (FTIR) spectroscopy, and these results suggest that the organic matters contributed to keeping the low fO₂ of the Hg‐bearing fluid and transportation of Hg as Hg⁰ in S‐poor condition. Because the solubility of Hg in acidic fluid is low, neutral to alkaline fluid seems to have leached Hg from the basement sedimentary rocks of Hidaka Group which also supplied the organic matters to the fluid. The oxidation and cooling of Hg‐bearing solution and vapor triggered the deposition of liquid Hg as a primary phase.  相似文献   

Northward-propagating nighttime medium-scale traveling ionospheric disturbances observed with SuperDARN Hokkaido HF radar and GEONET     

Akimitsu Ichihara  Nozomu Nishitani  Tadahiko Ogawa  Takuya Tsugawa 《极地研究(英文版)》2013,24(1)

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Seismic resistance capacity of beam–column connections in high‐rise buildings: E‐Defense shaking table test     

Yu‐Lin Chung  Takuya Nagae  Tomohiro Matsumiya  Masayoshi Nakashima 《地震工程与结构动力学》2011,40(6):605-622

A series of E‐Defense shaking table tests are conducted on a large‐scale test specimen that represents a high‐rise steel building. Two types of connections featuring the connection details commonly used in 1970s, in the early days of high‐rise construction in Japan, are adopted: the field‐welded connection consisting of welded unreinforced flanges and a bolted web type, and the shop‐welded connection in which the flanges and web are all‐welded to the column flange in the shop. To examine the seismic capacity of a total of 24 beam‐to‐column connections of the specimen, particularly when it is subjected to long‐period ground motion characterized not so much by large amplitude as by very many cycles of repeated loading, the test specimen is shaken repeatedly until the connections fractured. The test results indicate that a few of the field‐welded connections fractured from the bottom flange weld boundary in a relatively small cumulative rotation primarily due to the difficulties in ensuring the welding and inspection performance in the actual field welding. The shop‐welded connections are able to sustain many cycles of plastic rotation, with an averaged cumulative plastic rotation of 0.86 rad. Two shop‐welded connections exhibit ductile fractures but only after experiencing many cycles. The presence of RC floor slabs promotes the strain concentration at the toe of the weld access hole in the bottom flange by at least twice compared with the case without the slab, which had resulted in a decrease in the cumulative plastic rotation by about 50%. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Long-term high-frequency measurements of dibromomethane in the atmosphere at algae-rich and algae-poor coastal sites     

Yoko?YokouchiEmail author  Takuya?Saito  Hitoshi?Mukai 《Journal of Atmospheric Chemistry》2018,75(2):171-180

Dibromomethane (CH₂Br₂), a natural stratospheric ozone depleting substance, is mostly emitted from the ocean, but the relative importance of coastal (or macroalgae) and open ocean emissions is unknown. We made long-term high-frequency measurements of CH₂Br₂ concentrations at two remote coastal sites in Japan, on the subtropical Hateruma Island (poor in macroalgae) and at Cape Ochiishi (rich in macroalgae). CH₂Br₂ concentrations at Hateruma showed prominent seasonal variation, being lower in summer (around 0.94 ppt) than in winter (around 1.23 ppt). In contrast, CH₂Br₂ concentrations at Ochiishi were highly variable, often exceeding 2 ppt in the summer but with minimum baseline concentrations close to those from Hateruma; in the winter the concentrations were almost constant at about 1.3 ppt. Analysis of the data suggested that (1) emissions from macroalgae were not likely to extend offshore, but instead were localized near the shore, (2) strong macroalgal emissions of CH₂Br₂ were almost limited to the summer, but it was not reflected in the seasonality of the baseline concentrations of CH₂Br₂ in the atmosphere, and therefore (3) macroalgal or coastal emissions of CH₂Br₂ in the temperate zone might have a rather limited contribution to the global CH₂Br₂ sources. These findings are especially important for the understanding of the tropospheric and stratospheric bromine budget.  相似文献   

Sea surface temperature record off central Japan since the Last Glacial Maximum using planktonic foraminiferal Mg/Ca thermometry     

Takuya Sagawa  Kazuhiro Toyoda  Tadamichi Oba 《第四纪科学杂志》2006,21(1):63-73

We conducted paired measurements of the Mg/Ca ratio and δ¹⁸O of planktonic foraminifera, Globigerina bulloides, from a sediment core (MD01‐2420) off central Japan in the northwest Pacific, to reconstruct current movements since the Last Glacial Maximum (LGM). These methods make it possible to determine the magnitude and timing of the sea surface temperature (SST) changes and to reconstruct the variations of the past seawater δ¹⁸O (δ¹⁸Ow) off central Japan. The amplitude of Mg/Ca‐based SST changes between the Holocene and the LGM was about 10°C. The strong resemblance of the SSTs estimated from both methods, Mg/Ca‐based and δ¹⁸O‐based, suggests that the SST changes were caused primarily by latitudinal displacement of the Kuroshio–Oyashio currents and no distinct change in the carbonate dissolution of the core. The southward migration of the water mass was 5–6° in latitude at the LGM. The values for regional δ¹⁸Ow changes, which were obtained by subtracting the ice volume contribution from the calculated δ¹⁸Ow, describe the millennial‐scale water mass migration over the last 30 kyr. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Radio and infrared recombination studies of the southern massive star forming region G333.6−0.2     

Takuya Fujiyoshi  Craig H. Smith  James L. Caswell  Toby J. T. Moore  Stuart L. Lumsden  David K. Aitken  Patrick F. Roche 《Monthly notices of the Royal Astronomical Society》2006,368(4):1843-1855

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Noble gases in Muong Nong‐type tektites and their implications     

Sayaka MIZOTE  Takuya MATSUMOTO  Jun‐ichi MATSUDA  Christian KOEBERL 《Meteoritics & planetary science》2003,38(5):747-758

Abstract— We have the elemental abundances and isotopic compositions of noble gases in Muong Nong‐type tektites from the Australasian strewn field by crushing and by total fusion of the samples. We found that the abundances of the heavy noble gases are significantly enriched in Muong Nong‐type tektites compared to those in normal splash‐form tektites from the same strewn field. Neon enrichments were also observed in the Muong Nong‐type tektites, but the Ne/Ar ratios were lower than those in splash‐form tektites because of the higher Ar contents in the former. The absolute concentrations of the heavy noble gases in Muong Nong‐type tektites are similar to those in impact glasses. The isotopic ratios of the noble gases in Muong Nong‐type tektites are mostly identical to those in air, except for the presence of radiogenic ⁴⁰Ar. The obtained K‐Ar ages for Muong Nong‐type tektites were about 0.7 Myr, similar to ages of other Australasian tektites. The crushing experiments suggest that the noble gases in the Muong Nong‐type tektites reside mostly in vesicles, although Xe was largely affected by adsorbed atmosphere after crushing. We used the partial pressure of the heavy noble gases in vesicles to estimate the barometric pressure in the vesicles of the Muong Nong‐type tektites. Likely, Muong Nong‐type tektites solidified at the altitude (between the surface and a maximum height of 8–30 km) lower than that for splash‐form tektites.  相似文献   

Near-infrared imaging observations of the southern massive star-forming region G333.6−0.2     

Takuya Fujiyoshi  Craig H. Smith  Toby J. T. Moore  Stuart L. Lumsden  David K. Aitken  Patrick F. Roche 《Monthly notices of the Royal Astronomical Society》2005,356(3):801-809

We present near-infrared broad-band JHK ' images of the southern massive star-forming region G333.6−0.2. The slope of the K -luminosity function towards the region  (0.24 ± 0.01)  is considered to be equivalent to that expected for main-sequence stars in the solar neighbourhood. Point sources with their ( H − K ) colour greater than 1 are more likely to be located in extended emission and it is suggested that these objects are physically associated with the H  ii region.  相似文献   

Distribution of noble gases in Chinese tektites: Implication for neon solubility in natural glasses     

Daniele L. PINTI  Takuya MATSUMOTO  Jun‐Ichi MATSUDA  Zhong FANG 《Meteoritics & planetary science》2004,39(1):87-96

Abstract— Five indochinites from Hainan Island and the Leizhou Peninsula, China were analyzed for noble gas abundances and isotopic ratios. These splash‐form tektites show vesiculation ranging from 0.4 vol% to 8 vol%, as determined by digital image analysis (software SXM®) on thin section photographs. To study the distribution of noble gases in vesicles and in glass, the gases were extracted by heating and by crushing, respectively, on 2 aliquots of the same sample. The results show that 5 to 53% of the total measured ²⁰Ne resides in vesicles. The calculated concentration of neon dissolved in the glass is higher (0.7‐1 times 10^?7 cm³STP/g) than that expected from solubility equilibrium (1 times 10^?8 cm³STP/g), assuming solubility data from MORB glasses. The neon concentration of splash‐form tektites, those analyzed in this work and those from other strewn‐fields worldwide, is correlated with the SiO₂ content of glass and with the nonbridging oxygen per tetrahedral cation in the melt (hereafter NBO/T ratio), the latter being an index of the free‐volume in the silica network where neon could be dissolved. These correlations suggest that the glass structure of tektite has a larger free‐volume available for dissolving noble gases than MORB glasses.  相似文献   

Spatial and Seasonal Variation in Surface Water pCO2 in the Ganges,Brahmaputra, and Meghna Rivers on the Indian Subcontinent     

Takuya Manaka  Hiroyuki Ushie  Daisuke Araoka  Souya Otani  Akihiko Inamura  Atsushi Suzuki  H. M. Zakir Hossain  Hodaka Kawahata 《Aquatic Geochemistry》2015,21(5):437-458

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