A Simple Method for Precise Determination of 23 Trace Elements in Granitic Rocks by ICP-MS after Lithium Tetraborate Fusion   总被引：1，自引：0，他引：1  

Shunsaku Awaji    Kentaro Nakamura  Tatsuo Nozaki  Yasuhiro Kato 《Resource Geology》2006,56(4):471-478

Abstract. An improved alkali fusion method followed by HF-HNO₃-HC1O₄ treatment is performed for simultaneous determination of 23 trace elements (Sr, Y, Zr, Nb, Ba, Hf, Ta, Th, U, and REE) by ICP-MS in rock reference materials: basaltic rocks (JB-2, JB-3) and granitic rocks (JG-la, JG-2, JG-3). Our improved method offers several advantages including: (1) suppression of whitish precipitates probably composed of insoluble fluorides by addition of HCIO4, (2) simple and reliable preparation procedure, (3) instrument calibration which enables straightforward simultaneous multi-elemental analysis, and (4) the very low background levels by using pure lithium tetraborate flux. We obtained the analytical results with a reproducibility of mostly <2 % (1) for the basaltic rocks and <7 % for the granitic rocks. The higher relative standard deviation (RSD) values for granitic rocks may be attributed to sample heterogeneity of coarse-grained granitic rocks. The analytical results of the granitic rocks demonstrate that Zr and Hf abundances are consistent with the compiled values and that REE concentrations agree well with recently published data, suggesting that the Li₂B₄O₇ fusion method applied in the present study is suitable for the analysis of the granitic rocks.  相似文献   

Whole-rock Geochemistry of Basic Schists from the Besshi Area, Central Shikoku: Implications for the Tectonic Setting of the Besshi Sulfide Deposit     

Tatsuo Nozaki    Kentaro Nakamura  Shunsaku Awaji  Yasuhiro Kato 《Resource Geology》2006,56(4):423-432

Abstract. Whole-rock chemical compositions of the Besshi basic schist closely associated with the Besshi massive sulfide deposit from the Sanbagawa Belt are reported. Studied samples were collected from four outcrops around the Dozan-goe, central Shikoku. Common metamorphic mineral assemblage of the basic schist is albite + epidote + actinolite + chlorite ± muscovite ± quartz. Major element contents are similar to those of typical tholeiitic basalts. Trace element patterns of the basic schist normalized to normal mid-ocean ridge basalt (N-MORB) are generally flat, although concentrations of highly mobile large-ion lithophile elements are quite variable. Chondrite-normalized rare earth element (REE) patterns are flat to slightly light REE-depleted patterns. In the Hf-Th-Ta and Nb-Zr-Y discrimination diagrams, basic schist samples closely associated with the sulfide deposit are plotted within the N-MORB field. The Th/Nb ratios of the basic schist are also comparable to those of N-MORB. These geo-chemical lines of evidence indicate that the protolith of the Besshi basic schist is N-MORB and the Besshi sulfide deposit was formed by hydrothermal activity in conjunction with MOR volcanism.  相似文献   

Onboard experiment investigating metal leaching of fresh hydrothermal sulfide cores into seawater     

Shigeshi Fuchida  Jun-ichiro Ishibashi  Kazuhiko Shimada  Tatsuo Nozaki  Masanobu Kawachi  Yoshitaka Matsushita  Hiroshi Koshikawa 《Geochemical transactions》2018,19(1):15

We observed the initial release rate of metals from four fresh (i.e., without long time exposure to the atmosphere) hydrothermal sulfide cores into artificial seawater. The sulfide samples were collected by seafloor drilling from the Okinawa Trough by D/V Chikyu, powdered under inert gas, and immediately subjected to onboard metal-leaching experiments at different temperatures (5 °C and 20 °C), and under different redox conditions (oxic and anoxic), for 1–30 h. Zinc and Pb were preferentially released from sulfide samples containing various metals (i.e., Mn, Fe, Cu, Zn, Cd, and Pb) into seawater. Under oxic experimental conditions, Zn and Pb dissolution rates from two sulfide samples composed mainly of iron disulfide minerals (pyrite and marcasite) were higher than those from two other sulfide samples with abundant sphalerite, galena, and/or silicate minerals. Scanning electron microscopy confirmed that the high metal-releasing sample contained several galvanic couples of iron disulfide with other sulfide minerals, whereas the low metal-releasing sample contained fewer galvanic couples or were coated by a silicate mineral. The experiments overall confirmed that the galvanic effects with iron disulfide minerals greatly induce the initial release of Zn and Pb from hydrothermal sulfides into seawater, especially under warm oxic conditions.  相似文献   

Cordilleran-type orogeny and episodic growth of continents: Insights from the circum-Pacific continental margins     

Takahiro Tagami  & Noriko Hasebe 《Island Arc》1999,8(2):206-217

A new material migration hypothesis for the plate subduction zone orogeny, so-called ‘the cordilleran-type orogeny’, is proposed on the basis of geological constraints as well as mechanics of accretionary wedges. The major tectonic processes of the hypothesis comprise: (i) episodic, extensive magmatism along the margin of an overriding plate; (ii) supply of voluminous igneous and eroded materials through forearc to trench, with an increase in the net sediment influx into trench; (iii) accelerated accretion of sediments beneath an overriding older accretionary wedge; and (iv) upward material migration within the wedge and resultant exhumation of high-P/T metamorphic rocks near the inland margin of the wedge. This hypothesis was validated by the test using available geo- and thermo-chronological data from two classical types of subduction-related orogens in Southwest Japan and California. The hypothesis, coupled with the thermochronologic point of view, requires the reconsideration of coevality of paired metamorphism. The temporal pairing is to be observed between the beginning of the regional high-T/P metamorphism and that of the uplift and exhumation of high-P/T metamorphism, with some time lag needed for material migration. Where the temporal pairing is examined therefore, the formation age of igneous rocks and related high-T/P metamorphic rocks should be compared to the exhumation age of high-P/T metamorphic rocks. The episodic, extensive magmatism that triggers the cordilleran-type orogeny shows a temporal correlation in the mid-Cretaceous for most circum-Pacific continental margins. The resultant widespread formation of accretionary complexes is also observed in the western part of the circum-Pacific margins. The deduced mid-Cretaceous circum-Pacific orogeny accompanied a gross increase in the continental crust production rate, and was approximately coeval with the Pangea breakup and the Central Pacific superplume episode, implying the orogeny as a part of the mid-Cretaceous pulsation of the Earth.  相似文献   

Spirits of Yokokurayama: shrine of the Japanese trilobites     

Christopher Stocker  Mark Williams  Tatsuo Oji  Gengo Tanaka  Toshifumi Komatsu  Simon Wallis 《Geology Today》2019,35(1):15-19

‘We are such stuff as dreams are made on, and our little life is rounded with a sleep’. So sleep the trilobites of Yokokurayama, a sacred mountain hidden within the beautiful landscape of Japan’s Shikoku’s island. And though Prospero may have been speaking to his daughter and her fiancé (in William Shakespeare’s The Tempest), he might well have been contemplating the magnificent trilobite fossils of Yokokurayama. Japan may be better known for its sweeping volcanic landscapes, majestic castles, Shinto shrines and bullet trains, but it is also home to important collections of Silurian and Devonian trilobites.  相似文献   

Dragons,brimstone and the geology of a volcanic arc on the island of the last Samurai,Kyushu, Japan     

Mark Williams  Simon Wallis  Toshifumi Komatsu  Gengo Tanaka  Tatsuo Oji  Nicola Clark 《Geology Today》2016,32(1):21-26

Not even Hollywood could dream of a place so magical as Kyushu. The southern‐most of the four major islands of the Japanese archipelago, this is a land of volcanoes, dinosaurs, and the last stand of the Samurai. And for good measure, James Bond visited here too, in the 1967 film You Only Live Twice. The final explosive scenes of that film featured the destruction of megalomaniac Ernst Stavro Blofeld's headquarters hidden inside the crater of one of Kyushu's most emblematic volcanoes, Shinmoedake. Kyushu also straddles the largest geological structure in Japan, the Median Tectonic Line (MTL) that runs from the western approaches of the island to the central part of Honshu. The MTL has been active since the Cretaceous, and the sedimentary basins formed along its line in Kyushu contain some of Japan's most famous dinosaur finds. The MTL also defines a fundamental divide between the geological histories of the terranes north and south of its line, a history that takes us back to the origins of the Japanese archipelago half a billion years ago.  相似文献   

Size distribution of condensed aromatic rings in various soil humic acids     

Kosuke Ikeya  Tatsuo HikageShigeo Arai  Akira Watanabe 《Organic Geochemistry》2011,42(1):55-61

Condensed aromatic rings are important skeletal components with regard to the recalcitrant nature of humic acids (HAs) in the environment. However, they have not been extensively studied. The relative content and composition (size distribution) of condensed aromatic rings in HAs were obtained from various soils subjected to transmission electron microscopy (TEM) and X-ray diffraction (XRD) profile analysis. In the XRD profiles of all the HAs, the 11 band that was derived from the carbon layer planes was clearly observed. Analysis of the 11 band indicated that the size of the carbon layer planes in HAs ranged from 0.48-1.68 nm, corresponding to 4- to 37-ring condensed aromatic structures. The contents of the total and larger carbon layer planes were larger in HAs with darker color and larger aromatic carbon content. At the same time, the carbon layer planes in HAs were smaller than those in a carbon black reference (from 0.24 to >3.66 nm). In the TEM analysis, fringes observed in HAs were less distinct and less ordered than those in carbon black, which was in agreement with the XRD result.  相似文献   

Simulating present climate of the global ocean–ice system using the Meteorological Research Institute Community Ocean Model (MRI.COM): simulation characteristics and variability in the Pacific sector     

Hiroyuki Tsujino  Mikitoshi Hirabara  Hideyuki Nakano  Tamaki Yasuda  Tatsuo Motoi  Goro Yamanaka 《Journal of Oceanography》2011,67(4):449-479

A long-term spin-up and a subsequent interannual simulation are conducted for the ocean–ice component of the climate model intercomparison project (CMIP)-class earth system model of the Japan Meteorological Agency/Meteorological Research Institute. This experiment has three purposes: first is to assess the ability of our model with the Coordinated Ocean–ice Reference Experiments (COREs) forcing in reproducing the present ocean-climate; second is to understand the ocean-climate variability for the past 60 years; third is to present an example of evaluating an ocean–ice interannual variability simulation. The Pacific Ocean is focused on for the last two purposes. After integrating for about 1500 years with repeated use of a detrended CORE interannual forcing, the model reaches a quasi-steady state where the present climate is reproduced satisfactorily. Then, the interannual variability simulation is conducted with the retrieved forcing trend and the result is analyzed. The simulation is successful at reproducing the long-term variability in the Pacific and surrounding oceans. Brief analyses of the tropical and mid-latitude upper layer, deep circulation, and the Arctic sea ice are presented. A caveat in treating other parts of the globe is due to the recent intense convection in the Southern Ocean caused by a remarkably increasing trend of the Southern Hemisphere westerly. Overall, the current simulation with our CMIP-class ocean–ice model is shown to be useful for studying the present ocean-climate variability, specifically in the Pacific sector. It could also be used as a benchmark control experiment that facilitates further research, model development, and intercomparison.  相似文献   

Numerical investigation on the performance of Wells turbine with non-uniform tip clearance for wave energy conversion     

Zahari Taha  Sugiyono  T.M.Y.S. Tuan Ya  Tatsuo Sawada 《Applied Ocean Research》2011,33(4):321-331

The performance of a Wells turbine with various non-uniform tip clearances was investigated using computational fluid dynamics (CFD). The investigation was performed on numerical models of a NACA0020 blade profile under steady flow conditions. The performance of turbines with uniform and non-uniform tip clearances was compared. The results were also compared with experimental results in literature. It was shown that the performance of turbine with non-uniform tip clearance is similar with that of turbine with uniform one in terms of torque coefficient, input power coefficient, and efficiency. However, the turbine with non-uniform tip clearance seems to have a preferable overall performance. An investigation on the flow-field around the turbine blade was performed in order to explain the phenomena.  相似文献   

An upper limit of visible emission from the plume generated by the impact of the K fragment of SL9     

Masahisa Yanagisawa  Satoshi Tanaka  Tatsuaki Okada  Tatsuo Konno 《Earth, Moon, and Planets》1996,73(2):117-124

We monitored Jupiter with a video movie camera attached to a 1.3 m reflector during the impact event of the K fragment of D/Shoemaker-Levy 9. The camera was sensitive to visible radiation. A plume, which was generated by the impact and prominent in infrared wavelength, was not detected. Jovian images with hypothetical plumes were synthesized to examine how luminous the plume should have been to be recognized. It has been revealed that the plume was no more than twice as bright as Io in visible wavelength.  相似文献