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321.
John L. Daniels Gautham P. Das Maria Teresa Serrano Hernandez Sunyoung Bae 《Marine Georesources & Geotechnology》2006,24(3):183-191
The Taiwan Strait region has many miles of coastline, and the Taiwan Straits Tunnel (TST) project faces many potential pollution problems as construction proceeds through sensitive areas. Conventional approaches for pollution mitigation require further examination. The recent development of nanoscale particle technology has shown distinct advantages for contaminant attenuation and ground improvement. This paper is focused on trace metals and is part of the overall effort to develop the nanoscale particle technology. Trace metals in ground and surface waters represent a continued threat to human and ecological health. One of the difficulties in removing toxic concentrations of trace metals from solution is the variable oxidation state and amphoteric nature of multiple constituents. In particular, while cationic metals (e.g., Pb2+, Cd2+, Ni2+) may be rendered less mobile under high pH conditions, anionic metals (e.g., AsO43-, CrO42-, SeO42-)may become more mobile. The objective of this research was to evaluate the sorption of both cationic and anionic trace elements, including arsenic (As), cadmium (Cd), chromium (Cr) and selenium (Se) under batch conditions. Mixtures of a local residual soil were tested alone and in combination with lime and zero valent iron. It was hypothesized that lime would raise the pH and precipitate positively charged metals while zero valent iron would create reducing conditions favorable to the immobilization of negatively charged metals. Results indicate that the use of lime and/or zero valent iron can increase the sorption capacity of soil. Compared to the baseline soil, sorption capacity increased with addition of lime for arsenic and cadmium while it decreased for chromium and selenium. In the case of zero valent iron addition, sorption capacity increased for cadmium, chromium and selenium, while showing no change for arsenic. When both lime and zero valent iron were used, the sorption capacity increased for all metals tested. These results suggest that the combined use of lime and zero valent iron may serve as an alternative treatment technology for removing trace metals from contaminated water systems. 相似文献
322.
Fossi MC Marsili L Lauriano G Fortuna C Canese S Ancora S Leonzio C Romeo T Merino R Abad E Jiménez B 《Marine environmental research》2004,58(2-5):269-274
Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily - Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups. 相似文献
323.
Ford AT Fernandes TF Rider SA Read PA Robinson CD Davies IM 《Marine environmental research》2004,58(2-5):169-173
Intersexuality has been found in both males and females of the marine/estuarine amphipod, Echinogammarus marinus, at polluted and reference sites in East Scotland. Polluted sites had significantly more intersex specimens than reference sites, however the cause of intersexuality is unclear. Discriminant analysis of morphometric data showed that normal male specimens from the most polluted site resembled pooled intersex males, suggesting that subtle endocrine disruption (ED) maybe occurring in these otherwise apparently normal males. The main discriminating character was gnathopod size, recognised to be under androgenic gland control. The association of distinctive morphometry with intersexuality may provide a new approach to biomarkers of ED in crustaceans. The opportunities for other novel biomarkers, for example biochemical or behavioural markers, may also be explored through study of intersex animals. 相似文献
324.
Maria Teresa Gómez-Pugnaire Gerhard Franz Vicente López Sánchez-Vizcaino 《Contributions to Mineralogy and Petrology》1994,116(4):448-461
A Permo-Triassic pelite-carbonate rock series (with interacalated metabasitic rocks) in the Cordilleras Béticas, Spain, was metamorphosed during the Alpine metamorphism at high pressures (P min near 18 kbar). The rocks show well preserved sedimentary features of evaporites such as pseudomorphs of talc, of kyanite-phengitetalc-biotite, and of quartz after sulfate minerals, and relicts of baryte, anhydrite, NaCl, and KCl, indicating a salt-clay mixture of illite, chlorite, talc, and halite as the original rock. The evaporitic metapelites have a whole rock composition characterized by high Mg/(Mg+Ca) ratios>0.7, variable alkaline and Sr, Ba, contents, but are mostly K2O rich (<8.8 wt%). The F (<2600 ppm), Cl (<3600 ppm), and P2O5 (<0.24 wt%) contents are also high. The pelitic member of this series is a fine grained biotite rock. Kyanite-phengite-talc-biotite aggregates in pseudomorphs developed in the high pressure stage. Albite-rich plagioclase was formed when the rocks crossed the albite stability curve in the early stages of the uplift. Scapolite, rich in NaCl (Ca/(Ca+Na) mol% 24–40) and poor in SO4, with Cl/(Cl+CO3) ratios between 0.6 and 0.8, formed as porphyroblasts, sometimes replacing up to 60% of the rock in a late stage of metamorphism (between 10 and 5 kbar, near 600°C). No reaction with albite is observed, and the scapolite formed from biotite by: $$\begin{gathered} Al - biotite + CaCO_3 + NaCl + SiO_2 \hfill \\ = Al - poor biotite + scapolite + MgCO_3 + KCl \hfill \\ + MgCl_2 + H_2 O \hfill \\ \end{gathered}$$ Calculated fluid composition in equilibrium with scapolite indicates varying salt concentrations in the fluid. Distribution of Cl and F in biotite and apatite also indicates varying fluid compositions. 相似文献
325.
Miriam Peña Manuel Peimbert Silvia Torres-Peimbert Maria Teresa Ruiz Jose Maza 《Astrophysics and Space Science》1996,238(1):55-58
The recent evolution of the central star of the planetary nebula LMC-N66 is presented. Before 1987, it showed a weak continuum with aT
eff120 000 K andL
bol25 000L
and in a few years it developed strong WR features (P Cygni line profiles in N v at 124.0 nm and C IV at 155.0 nm, wide Heii emission, etc.) typical of a WN 4.5. Additionally the stellar continuum increased by a large factor and the absolute visual magnitude of the star changed from + 1.24 in 1987 to–2.57 in January, 1995. The WR features and enhanced continuum, evidencing a powerful mass-loss event remained with small variations for more than 5 years. Recent ultraviolet and optical data shows that the mass-loss seems to have diminished abruptly in the last three months. 相似文献
326.
The Zgorzelec-Wiżajny profile cuts through the main European geotectonic units of the Palaeozoic Western and Central European
Platform and the East European Craton, including the connecting Trans-European Suture Zone. The paper summarises 40 years
of research on geomagnetic secular variations along the Zgorzelec-Wiżajny profile since 1966. It discusses methods of processing
measurement records and presenting their results. The latter are presented against the background of the local geology and
the crustal deep magnetic structure data.
The hitherto method of variation analysis was modified to address a new trend in the geomagnetic secular variations that has
emerged in the East European Craton during the last five years (2001–2005). 相似文献
327.
328.
Teresa Suter Bowers Karen L. Von Damm John M. Edmond 《Geochimica et cosmochimica acta》1985,49(11):2239-2252
Chemical analyses yielding elemental concentrations of major and minor elements of four hot springs on the East Pacific Rise at 21°N and 10 hot springs from the southern trough of the Guaymas Basin, Gulf of California provide a basis for thermodynamic modeling of conductive cooling of the hydrothermal endmembers, mixing of the hydrothermal endmember with seawater, and reaction of an EPR-type fluid with sediment of bulk chemical composition corresponding to unaltered sediment from DSDP hole 477 in the Guaymas Basin. Results of the calculations indicate that conductive cooling of endmember fluids within closed chimneys and conduits accounts for the solution composition of one vent on the East Pacific Rise and several vents in Guaymas Basin. Mixing of the hydrothermal fluids with seawater yields a prediction of mineral assemblages closely approximating those observed in samples of chimneys from the East Pacific Rise and drill cores in Guaymas Basin. The hypothesis that Guaymas Basin hydrothermal fluids result from interaction of an EPR-type fluid with sediment cover in Guaymas Basin is supported by calculations which predict an increase in pH to a value similar to Guaymas Basin fluids, an order-of-magnitude decrease in metal concentrations, and an excellent agreement between predicted mineral assemblages as a function of extent of interaction with sediment, and observed mineral assemblage distribution with depth. 相似文献
329.
Maria Teresa Miranda Espinosa Gregory Giuliani Nicolas Ray 《International Journal of Digital Earth》2020,13(2):236-252
ABSTRACTEssential Climate Variables (ECVs) are geophysical records generated from systematic Earth Observations associated with climate variations, changes, and impacts. ECVs products support the data and information needs of international frameworks and policies such as the work of the United Nations Framework Convention on Climate Change (UNFCCC) and the Intergovernmental Panel on Climate Change (IPCC). We map the main networks and initiatives publishing ECVs, by presenting an overview of existing satellite-based ECVs, their general data creation characteristics, discoverability and accessibility methods from an end-user perspective. We investigate key initiatives providing or coordinating access to ECV data records, such as the Global Climate Observing System (GCOS), the Committee on Earth Observation Satellites (CEOS), the Coordination Group for Meteorological Satellites (CGMS), Joint Working Group on Climate (WGClimate), the Remote Sensing Systems (REMSS), and the European Space Agency Climate Change Initiative (ESA CCI). We find that ECV data discovery and access is difficult and time consuming due to the lack of common data and metadata catalogues. In addition, the selection of fit-for-purpose data records by end-users requires the implementation of interoperable standards and scalable data infrastructures to allow the generation of tailored applications and data-driven information products in support of decision-making processes. 相似文献
330.
R. León L. Somoza T. Medialdea F. J. González V. Díaz-del-Río M. C. Fernández-Puga A. Maestro M. P. Mata 《Geo-Marine Letters》2007,27(2-4):237-247
Underwater images taken from deepwater carbonate-mud mounds located along the continental margin of the Gulf of Cádiz (eastern
Central Atlantic) have identified a great variety of hydrocarbon seep-related geomorphic features that exist on the sea floor.
An extensive photographic survey was made along the Guadalquivir Diapiric Ridge, after detailed examination of the main mounds
identified on previous swath bathymetry coverage, high-resolution seismic imagery, dredge and gravity core data. Recognised
fluid-induced geomorphic features include seep precipitates, named here generically as hydrocarbon-derived authigenic carbonates
(HDACs), mud-breccia flows and piping/rills, at scales ranging from metres to centimetres. Based on the viscosity, texture,
morphology, and the nature of observed features, we have categorized the geomorphic seeps into the following types: mud-breccia
flows and liquid seepages, which can be grouped as highly viscous and viscous mud-breccia flows, gassy mud-breccia flows,
and small-scale piping/rills; HDACs types, including massive crusts, “honeycombed” carbonate crusts, nodular aggregated crusts,
steeply dipping to vertical slabs, and pipe-like formations (chimneys). These widespread geomorphic features observed along
the carbonate-mud mounds reveal alternate periods of (1) active mud-flow extrusion (mud-volcano formation), (2) reduced seepage
activity, with the formation of extensive carbonate features by chemosynthetic organisms, and (3) formation of hardgrounds
and colonisation by non-chemosynthetic organisms such as deepwater corals (e.g. Lophelia pertusa, Madrepora oculata). The formation of large amounts of HDACs is related to the microbially mediated oxidation of hydrocarbon fluids (biogenic
and thermogenic) during periods of slower fluid venting. This has led to the hypothesis that these carbonate-mud mounds could
be built up by alternating episodes of varying fluid-venting rates, with peaks that may have been triggered by tectonic events
(e.g. high-seismicity periods) and slower rates controlled by climate/oceanographic factors (e.g. glacial to interglacial
climatic transitions, increasing shallow subsurface hydrate formation, and sealing of sea-floor fluid venting). 相似文献