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351.
During the last glacial cycle an intriguing feature of the British-Irish Ice Sheet was the North Sea Lobe (NSL); fed from the Firth of Forth and which flowed south and parallel to the English east coast. The controls on the formation and behaviour of the NSL have long been debated, but in the southern North Sea recent work suggests the NSL formed a dynamic, oscillating terrestrial margin operating over a deforming bed. Further north, however, little is known of the behaviour of the NSL or under what conditions it operated. This paper analyses new acoustic, sedimentary and geomorphic data in order to evaluate the glacial landsystem imprint and deglacial history of the NSL offshore from NE England. Subglacial tills (AF2/3) form a discontinuous mosaic interspersed with bedrock outcrops across the seafloor, with the partial excavation and advection of subglacial sediment during both advance and retreat producing mega-scale glacial lineations and grounding zone wedges. The resultant ‘mixed-bed’ glacial landsystem is the product of a dynamic switch from a terrestrial piedmont-lobe margin with a net surplus of sediment to a partially erosive, quasi-stable, marine-terminating, ice stream lobe as the NSL withdrew northwards. Glaciomarine sediments (AF4) drape the underlying subglacial mixed-bed imprint and point to a switch to tidewater conditions between 19.9 and 16.5 ka cal BP as the North Sea became inundated. The dominant controls on NSL recession during this period were changing ice flux through the Firth of Forth ice stream onset zone and water depths at the grounding line; the development of the mixed-bed landsystem being a response to grounding line instability. © 2018 John Wiley & Sons, Ltd.  相似文献   
352.
The homogeneity and Ar‐dating suitability of the GL‐O reference material were re‐evaluated to determine whether this material is sufficiently homogeneous to be suitable for the calibration of modern high sensitivity instruments. Based on new micro‐analyses and noble gas determinations, our contribution reveals several kinds of inhomogeneity at the grain scale: disparity in the glauconitisation among and within the pellets, variable occurrence of a phosphatic component within pellets (1% m/m on average), and rare occurrences of calcite and detrital grains. Measurements on test portions of ≤ 1 mg reflect such heterogeneity with variability in 40Ar* content that exceeds analytical uncertainty, including a few highly anomalous values. The lesser evolved glauconite population yielded 40Ar* contents ~ 15% lower than the value of 24.8 nl g?1 recommended by Odin et al. (1982, Numerical dating in stratigraphy. Wiley (Chichester, UK), 123–148). But the measured concentrations of 40Ar* converge towards the aforementioned value as test portion mass increased to > 3 mg. A few rare 3 mg experiments still yielded 40Ar* contents lower than the recommended value (down to 24.0 nl g?1), and we recommend using more conservative minimum masses of 5–10 mg. A further purification step for GL‐O or the intercalibration of its powder version could be considered to diminish the size of the test portions and the intensity of the measured signals.  相似文献   
353.
Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE2+ correction for rock glasses, yields the most accurate and precise 87Sr/86Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for 87Sr/86Sr measurements for materials with < 1000 μg g-1 Sr.  相似文献   
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