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41.
Koryu矿山位于北海道南西部,为一浅成低温热液型Au-Ag石英脉型矿床.矿床产于中新世黑色泥岩中的东西向剪切带内.矿床含有8个主要脉体,总体呈东西走向,在水平、垂直方向上均发生结构、构造的变化.1号脉和3号脉中冰长石K-Ar年龄为0.8~1.2 Ma,表明矿化时代为更新世.根据矿脉体的穿插关系和脉内矿物共生关系得出矿区有2期矿化,早期矿化可分3个阶段(即E-Ⅰ,E-Ⅱ,E-Ⅲ),晚期矿化可分成7个阶段(即L-Ⅰ,L-Ⅱ,L-Ⅲ,L-Ⅳ,L-Ⅴ,L-Ⅵ,L-Ⅶ).宽矿脉体由多阶段矿化组成,Au-Ag矿化主要与L-Ⅲ阶段矿化密切相关.早期矿化形成的特征矿物为钙菱镁矿、钙锰辉石及少量矿石矿物;晚期矿化形成大量矿石矿物.含AuAg的矿物主要为银金矿、螺状硫银矿-辉硒银矿、硫锑铜银矿-硫砷铜银矿、浓红银矿-淡红银矿、辉铜银矿、马硫铜银矿、碲银矿和黝铜矿.而脉石矿物为绿泥石、蒙脱石、石英.区内许多成矿阶段均含富气相流体包裹体,这表明沸腾作用在整个过程中间歇发生.早期矿化温度(263~283℃)稍高于晚期矿化温度(246~260℃).成矿溶液盐度为0.5%~6.0% NaCl当量,尽管CO2含量在晚期矿化阶段达0.4%(质量分数).这些特征表明成矿流体最大压力为3.1~6.8 M Pa,相当于古潜水面下430~850 m深度.石英形态学结合流体包裹体研究证实流体沸腾作用反复发生,导致SiO2过饱和,形成结构各异的二氧化硅矿物.在脉体形成过程中,SiO2重结晶形成石英.稳定同位素资料、矿物共生组合特征、石英结构特征和流体包裹体特征综合研究得出Koryu金-银矿床成矿模式如下:矿床矿化分为明显的两期,即早期和晚期,分别对应类型1和类型2两种热液流体.早期流体具相对高的W18O值(-5.3‰~-4.7‰),温度不低于260℃;晚期流体W18O值相对偏低(-9.3‰~-6.0‰),温度250℃以上.类型1流体发生深部循环,淋滤Ca和M n元素,在早期矿化过程中形成钙菱镁矿、钙锰辉石.与浅成水混合的类型2流体沿新通道上升,富含Au、Ag元素.在晚期矿化过程中,流体上升至沸腾带( < 850 m),金、银在250℃沉淀成矿.  相似文献   
42.
It is being accepted that earthquakes in subducting slab are caused by dehydration reactions of hydrous minerals. In the context of this “dehydration embrittlement” hypothesis, we propose a new model to explain key features of subduction zone magmatism on the basis of hydrous phase relations in peridotite and basaltic systems determined by thermodynamic calculations and seismic structures of Northeast Japan arc revealed by latest seismic studies. The model predicts that partial melting of basaltic crust in the subducting slab is an inevitable consequence of subduction of hydrated oceanic lithosphere. Aqueous fluids released from the subducting slab also cause partial melting widely in mantle wedge from just above the subducting slab to just below overlying crust at volcanic front. Hydrous minerals in the mantle wedge are stable only in shallow (< 120 km) areas, and are absent in the layer that is dragged into deep mantle by the subducting slab. The position of volcanic front is not restricted by dehydration reactions in the subducting slab but is controlled by dynamics of mantle wedge flow, which governs the thermal structure and partial melting regime in the mantle wedge.  相似文献   
43.
Ultra-calcic melt inclusions (UCMI: CaO>13.5 wt% and/or CaO/Al2O3>0.9) are magnesian and near-primary liquids trapped in volcanic phenocrysts from mid-ocean ridges, arcs, back-arcs, and ocean islands. UCMI can be subdivided into two classes based on tectonic association and degree of silica saturation: those from arcs are nepheline normative and those from all other localities (silicic UCMI) are hypersthene normative. Silicic UCMI share a number of common features, including primitive host minerals, low alkali contents, and variable ratios of K2O/TiO2 ranging to high values. Their compositions are not easily derived by partial melting of mantle lherzolite. Accordingly, we have performed a series of partial melting experiments on three clinopyroxenite compositions at 1.0 to 2.0 GPa to investigate the role of partial melting of clinopyroxene-rich lithologies in silicic UCMI genesis. Estimated solidus temperatures for all three compositions are similar to those of normal peridotites, but 1.0 GPa isobaric melt productivities are higher for clinopyroxenite than for peridotite. High degree partial melts of the clinopyroxenites are ultra-calcic and have similarities to silicic UCMI, but the experiments produce ultra-calcic liquids only at melt fractions greater than 30% and temperatures higher than 1,350 °C at 1.0 GPa. Such temperatures are higher than those likely to be prevailing beneath normal mid-ocean ridges, which suggests that some or all silicic UCMI may originate by a process other than simple partial melting of clinopyroxene-rich lithologies. We consider a possible role for partial melting of depleted harzburgite in the genesis of silicic UCMI.  相似文献   
44.
Hydrothermal circulation beneath the spreading axis plays a significant role in the exchange of energy and mass between the solid Earth and the oceans. Deep-seated hydrothermal circulation down to the crust/mantle boundary in the fast-spreading axis has been introduced by a number of studies regarding geological investigations and numerical models. In order to assess a reaction between hydrothermal fluid and host rock around the crust/mantle boundary, we conducted bulk trace element and Sr isotope analyses with a series of in situ investigations for crustal anorthosite, a reaction product between hydrothermal fluid and gabbro in the lowermost crustal section along Wadi Fizh, northern Oman ophiolite. In addition, we conducted titanite U–Pb isotope analyses to evaluate timing of the crustal anorthosite formation in the framework of the evolutional process of the Oman ophiolite. We estimated the formation age of the crustal anorthosite at 97.5 Ma ± 5.0 Ma, overlapping with the timing of the crust formation in the paleo spreading axis. The crustal anorthosite shows high-Th/U ratio (~2.5) and high-initial 87Sr/86Sr ratio (0.7050) due to seawater-derived hydrothermal fluid ingress into the precursor gabbro. With using analytical technique of micro-excavation at cryo-temperature, we detected Cl from a few micrometer-sized inclusion of aqueous fluid and chromite grains. The solubility of Cr was enhanced by complexation reactions with Cl in the hydrothermal fluid. Regarding reconstructed three-dimensional mass distribution of the inclusion and chromite composition, maximum Cr content of parental fluid was estimated at ~69 000 μg/g. The exceptionally high-Cr content was achieved locally by leaking of fluid and synchronous chromite crystallization during fluid entrapment. Presence of the deep-seated hydrothermal circulation could be assigned to the segment end, where cold seawater penetrates into the lowermost crust and extract heat along widely spaced network-like fluid channel.  相似文献   
45.
Oshika  Miki  Tachibana  Yoshihiro  Nakamura  Tetsu 《Climate Dynamics》2015,45(5-6):1355-1366
Climate Dynamics - On the basis of a 51-year statistical analysis of reanalysis data, we propose for the first time that the positive phase of the Western Pacific (WP) pattern in the winter is...  相似文献   
46.
The Sr, Ba, and rare earth elements (REEs) concentrations and Sr isotopic composition of anhydrite and gypsum have been determined for samples from the Matsumine, Shakanai, and Hanaoka Kuroko-type massive sulfide–sulfate deposits of northern Japan to evaluate the mechanisms of sekko (anhydrite and gypsum) ore formation. The Sr isotopic compositions of the samples fall in the range of 0.7077–0.7087, intermediate between that for middle Miocene (13–15 Ma) seawater (0.7088) (Peterman et al., Geochim Cosmochim Acta, 34:105–120, 1970) and that for country rocks (e.g., 0.7030–0.7050) (Shuto, Assn Geol Collab Japan Monograph 18:91–105, 1974). The Kuroko anhydrite samples exhibit two types of chondrite-normalized REE patterns: one with a decrease from light REEs (LREEs) to heavy REEs (HREEs) (type I), and another with a LREE-depleted pattern (type II). Based on the Sr content and isotopic ratio (assuming an Sr/Ca (mM/M) of 8.7 for seawater), anhydrite is considered to have formed by mixing of preheated seawater with a hydrothermal solution of Sr/Ca (mM/M) = ca. 0.59–1.36 under the condition in which the partition coefficient (Kd) ranges between ca. 0.5 and 0.7. This results in the formation of anhydrite with higher Sr content with an Sr isotopic value close to that of seawater under seawater-dominant conditions. Larger crystals of type II anhydrite are partly replaced by smaller ones, indicating that anhydrite dissolution and recrystallization occurred after or during the formation of sekko ore. Gypsum, which partially replaces anhydrite in the Kuroko deposits, also exhibits two distinct chondrite-normalized REE patterns. Because LREEs are likely to be more readily mobilized during dissolution and recrystallization, it is hypothesized that LREEs are leached from type I anhydrite, resulting in the formation of type II anhydrite with LREE-depleted profiles.  相似文献   
47.
Effects of spilled oil on microbial communities in tidal flats were examined by use of a simulator for a tidal flat ecosystem. The simulator is composed of a wave generator, a tide control device, and a tidal flat. Sediment for the tidal flat was obtained at a natural tidal flat in Hiroshima Bay, Japan. After stabilizing the benthic organisms, fuel oil C was added to the surface of the flat at 1 lm(-2). Although the total number of micro-organisms remained at 1.5-3.5 x 10(9) cells g(-1) dry sediment irrespective of the addition of oil, bacterial communities which were analyzed based on the 16S rDNA showed clear changes after the addition of fuel oil C and after a subsequent recovery period. Bacterial colonies were randomly isolated from the oil-supplemented sediment during the experiments, and the isolates were examined for susceptibility to hydrocarbons in order to screen the oil-susceptible bacteria. The proportion of oil-susceptible bacteria in the isolates decreased with the addition of the oil. Oil-susceptible bacteria showed an inability to assimilate petroleum compounds as well as an inhibition of growth. The possibility of using oil-susceptible bacteria as an indicator of bioremediation in tidal flats was discussed.  相似文献   
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