Chemical Mechanism Development: Laboratory Studies and Model Applications     

Harald Geiger  Ian Barnes  Karl H. Becker  Birger Bohn  Theo Brauers  Birgit Donner  Hans-Peter Dorn  Manfred Elend  Carlos M. Freitas Dinis  Dirk Grossmann  Heinz Hass  Holger Hein  Axel Hoffmann  Lars Hoppe  Frank Hülsemann  Dieter Kley  Björn Klotz  Hans G. Libuda  Tobias Maurer  Djuro Mihelcic  Geert K. Moortgat  Romeo Olariu  Peter Neeb  Dirk Poppe  Lars Ruppert  Claudia G. Sauer  Oleg Shestakov  Holger Somnitz  William R. Stockwell  Lars P. Thüner  Andreas Wahner  Peter Wiesen  Friedhelm Zabel  Reinhard Zellner  Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

Petrologic, isotopic, and radiometric age constraints on the origin and tectonic history of the Malino Metamorphic Complex, NW Sulawesi, Indonesia     

Theo van Leeuwen  Charlotte M. Allen  Ade Kadarusman  Marlina Elburg  J. Michael Palin  Muhardjo  Suwijanto 《Journal of Asian Earth Sciences》2007,29(5-6):751-777

The Malino Metamorphic Complex (MMC) is located at the western end of the north arm of Sulawesi. It consists of mica schists and gneisses (derived from proximal turbidite and granitoid protoliths), with intercalations of greenschist, amphibolite, marble, and quartzite, forming an E-W elongated dome-like structure bounded on all sides by faults. The age of the MMC is constrained between Devonian and Early Carboniferous. This Paleozoic age, the presence of Archean and Proterozoic inherited zircons, and the isotopic signature of the mica schists and gneisses indicate that the terrane was derived from the New Guinea-Australian margin of Gondwana. Similarities with basement rocks in the Bird’s Head suggests a common origin. Greenschists forming a discontinuous selvage (metamorphic carapace) around the complex were derived from adjacent autochthonous Paleogene formations. The rocks of the MMC show a Barrovian-type progression from greenschist through epidote-amphibolite to amphibolite facies. P–T estimations suggest a depth of burial of up to 27–30 km. K/Ar and 40Ar/39Ar cooling ages of 23–11 Ma, and a 7 Ma age for unconformably overlying volcanic rocks, indicate that the complex was exhumed during the Miocene. Two tectonic scenarios are considered: 1. the continental fragment docked with Sulawesi during the Mesozoic and was exhumed as a metamorphic core complex during the Miocene; 2. it was subducted beneath the north arm during the late Oligocene and then rapidly returned back to the surface.  相似文献   

A New Operational Paradigm for Small‐Scale ASR in Saline Aquifers     

Marloes van Ginkel  Theo N. Olsthoorn  Mark Bakker 《Ground water》2014,52(5):685-693

A new operational paradigm is presented for small‐scale aquifer storage and recovery systems (ASR) in saline aquifers. Regular ASR is often not feasible for small‐scale storage in saline aquifers because fresh water floats to the top of the aquifer where it is unrecoverable. In the new paradigm, fresh water storage is combined with salt water extraction from below the fresh water cone. The salt water extraction counteracts the buoyancy due to the density difference between fresh water and salt water, thus preventing the fresh water from floating up. The proposed approach is applied to assess the feasibility of ASR for the seasonal storage of fresh water produced by desalination plants in tourist resorts along the Egyptian Red Sea coast. In these situations, the continuous extraction of salt water can be used for desalination purposes. An analytical Dupuit solution is presented for the steady flow of salt water toward a well with a volume of fresh water floating on top of the cone of depression. The required salt water discharge for the storage of a given volume of fresh water can be computed with the analytical solution. Numerical modeling is applied to determine how the stored fresh water can be recovered. Three recovery approaches are examined. Fresh water recovery rates on the order of 70% are achievable when salt water is extracted in high volumes, subsurface impermeable barriers are constructed at a distance from the well, or several fresh water recovery drains are used. The effect of ambient flow and interruptions of salt water pumping on the recovery efficiency are reported.  相似文献   

Calculating residual flows through a multiple-inlet system: the conundrum of the tidal period     

Matias Duran-Matute  Theo Gerkema 《Ocean Dynamics》2015,65(11):1461-1475

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An institutional analysis of the evolution of inland waterway transport and inland ports on the Pearl River     

J. Y. Li  Theo E. Notteboom  James J. Wang 《GeoJournal》2017,82(5):867-886

Inland waterway transport (IWT) is the most appropriate means of transportation in the pursuit of a sustainable development strategy. The development of IWT varies per region. Public entities and institutions play an important role in the development of IWT. This paper analyses the development of IWT on the Pearl River from an institutional perspective. Chinese national fiscal reforms, land use reforms and the transfer of power from the central government to local governments impact the governance of IWT. The paper demonstrates that the privatization of inland ports was triggered by the mismatch between the objectives of IWT operators and either public objectives or market demand. This process unfolded while top-level governors did not aim for privatization. The paper shows how formal institutional changes of IWT on the Pearl River are both the result of deliberate design and a path creation in the transformation from the Chinese planned economy to the Chinese market economy. It also shows how institutional changes resulted in a dual development path (i.e. a rapid development of inland terminals but underdevelopment of inland waterways) of IWT in the Pearl River. Policy recommendations are provided based on the research findings with specific attention to the factors hindering IWT development on the Pearl River at the level of the waterway infrastructure and inland ports.  相似文献   

Design of a view-based DSS for location planning     

Theo A. Arentze  Aloys W. J. Borgers  Harry J. P. Timmermans 《International journal of geographical information science》2013,27(2):219-236

Abstract.

The traditional approach in DSS falls short of providing a highly interactive problem solving environment for planning. Often, cumbersome procedures are required to implement optional plans and obtain feedback information. In dynamic graphic systems, the user is able to view different linked graphic representations (e.g., spatial or statistical graphs) of statistical data and interact (e.g., selecting items) with these graphics. In this paper we describe the design of a DSS for planning facility locations, which uses principles of dynamic graphics to achieve a highly interactive problem solving environment. As in dynamic graphic systems, the user interacts with the DSS through active and linked views. However, where views in dynamic graphics are different representations of a given dataset, the views in the DSS are active data structures describing the facility system to be planned from different perspectives. The declarative and procedural forms of knowledge involved are identified by a logical analysis of planning problems. A frame-based formalism is proposed to represent the knowledge contained in the views. The main advantage of this view-based approach is that it offers the user a highly flexible and interactive environment for performing ‘what-if’ analyses.  相似文献   

Constructing personalized transportation networks in multi-state supernetworks: a heuristic approach     

Feixiong Liao  Theo A. Arentze 《International journal of geographical information science》2013,27(11):1885-1903

An integrated view encompassing the networks for public and private transport modes as well as the activity programs of travelers is essential for accessibility analysis. In earlier research, the multi-state supernetwork has been put forward by the authors as a suitable technique to model the system in such an integrated fashion. An essential part of a supernetwork involving multi-modal and multi-activity is the personalized transportation network, which is an under-researched topic in the academic community. This article attempts to develop a heuristic approach to construct personalized transportation networks for an individual's activity program. In this approach, the personalized network consists of two types of network extractions from the original transportation system: public transport network and private vehicle network. Three examples are presented to illustrate that the public transport network and private vehicle network can represent an individual's attributes and be applied in large-scale applications for analyzing the synchronization of land-use and transportation systems.  相似文献   

Negotiating on location, timing, duration, and participant in agent-mediated joint activity-travel scheduling     

Huiye Ma  Nicole Ronald  Theo A. Arentze  Harry J. P. Timmermans 《Journal of Geographical Systems》2013,15(4):427-451

Agent-based simulation has become an important modeling approach in activity-travel analysis. Social activities account for a large amount of travel and have an important effect on activity-travel scheduling. Participants in joint activities usually have various options regarding location, participants, and timing and take different approaches to make their decisions. In this context, joint activity participation requires negotiation among agents involved, so that conflicts among the agents can be addressed. Existing mechanisms do not fully provide a solution when utility functions of agents are nonlinear and non-monotonic. Considering activity-travel scheduling in time and space as an application, we propose a novel negotiation approach, which takes into account these properties, such as continuous and discrete issues, and nonlinear and non-monotonic utility functions, by defining a concession strategy and a search mechanism. The results of experiments show that agents having these properties can negotiate efficiently. Furthermore, the negotiation procedure affects individuals’ choices of location, timing, duration, and participants.  相似文献   

Distributions of microcanonical cascade weights of rainfall at small timescales     

Paweł Licznar  Theo G. Schmitt  David E. Rupp 《Acta Geophysica》2011,59(5):1013-1043

Empirical frequency distributions of multiplicative cascade weights, or breakdown coefficients, at small timescales are analyzed for 5-min precipitation time series from four gauges in Germany. It is shown that histograms of the weights, W, are strongly deformed by the recording precision of rainfall amounts. A randomization procedure is proposed to statistically remove the artifacts due to precision errors in the original series. Evolution of the probability distributions of W from beta-like for large timescales to combined beta-normal distribution with a pronounced peak at W ≈ 0.5 for small timescales is observed. A new 3N-B distribution built from 3 separate normal, N, distributions and one beta, B, distribution is proposed for reproduction of the empirical histograms of W at small timescales. Parameters of the 3N-B distributions are fitted for all gauges and analyzed timescales. Microcanonical cascades models with a generator based on 3N-B distributions are developed and their performance at disaggregating precipitation at 1280-min intervals down to 5-min intervals is evaluated.  相似文献   

The influence of equilibrium partitioning, biotransformation and lipid depletion on patterns of chlorinated biphenyls in marine mammals     

Jan P. Boon  Ina Oostingh  M. Theo  J. Hillebrand 《Marine environmental research》1995,39(1-4)

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