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Coals are oil source rocks in many of the Tertiary basins of Southeast Asia. The precursors of these hydrogen rich and oxygen poor coals are coastal plain peats which have mainly developed in an everwet and tropical climate. In these environments water flow and reworking can concentrate liptinitic kerogen in preference to vitrinitic kerogen. The distribution, petrography and chemistry of the coaly Miocene source rocks present in the Kutai Basin are described. The recognition of environmental controls on the accumulation of potentially oil-prone coals and coaly shales in deltaic environments is an aid to predictive source bed recognition in petroleum exploration. Comments on the environment of deposition of coaly sediments in the basins of the Norwegian Sea are discussed with reference to their possible oil and/or gas sourcing potential. The Triassic - Jurassic coals of the Haltenbanken area may become more oil-prone towards the delta margins, and facies mapping could aid oil exploration in this area.  相似文献   
13.
Many stochastic process models for environmental data sets assume a process of relatively simple structure which is in some sense partially observed. That is, there is an underlying process (Xn, n 0) or (Xt, t 0) for which the parameters are of interest and physically meaningful, and an observable process (Yn, n 0) or (Yt, t 0) which depends on the X process but not otherwise on those parameters. Examples are wide ranging: the Y process may be the X process with missing observations; the Y process may be the X process observed with a noise component; the X process might constitute a random environment for the Y process, as with hidden Markov models; the Y process might be a lower dimensional function or reduction of the X process. In principle, maximum likelihood estimation for the X process parameters can be carried out by some form of the EM algorithm applied to the Y process data. In the paper we review some current methods for exact and approximate maximum likelihood estimation. We illustrate some of the issues by considering how to estimate the parameters of a stochastic Nash cascade model for runoff. In the case of k reservoirs, the outputs of these reservoirs form a k dimensional vector Markov process, of which only the kth coordinate process is observed, usually at a discrete sample of time points.  相似文献   
14.
Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.  相似文献   
15.
Montane (alpine) areas are generally of high value for nature conservation. Such environments and the habitats they support are dynamic and often fragile. They are vulnerable to disturbance from a range of human activities and are responsive to climate changes over short and long timescales. Biodiversity and conservation values are closely linked to geological history, geomorphological processes and soils, and it is crucial that management systems are based on understanding these links.
There are many similarities between the Cairngorm Mountains (Scotland), the Giant Mountains (Czech Republic) and Abisko Mountains (Sweden) in terms of geology, geomorphology, ecology, links with biodiversity and high conservation importance. Comparable pressures and management issues involve, to varying degrees, a history of human use and impacts from deforestation, pasturing, grazing, recreation and atmospheric pollution. Landscape change therefore involves a complex interplay between natural and anthropogenic factors. Managing such change requires better understanding of the geo–ecological processes involved and the factors that determine landscape sensitivity. This is illustrated through a simple framework and examples from the three areas. Comparison of landscape sensitivity between similar montane areas, but in different geographic locations and climatic environments, should allow more informed management planning and a precautionary approach in advance of further changes in human activity and from predicted global warming scenarios.  相似文献   
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High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser 40Ar/39Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (87Sr/86Sr?=?0.704 and 143Nd/144Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.  相似文献   
18.
Denitrification rates along a salinity gradient in the eutrophic Neuse River Estuary, North Carolina, were quantified using membrane inlet mass spectrometry (MIMS) within short-term batch incubations. Denitrification rates within the system were highly variable, ranging from 0 to 275 μmol N m−2 h−1. Intrasite variability increased with salinity, but no significant differences were observed across the salinity gradient. Denitrification rates were positively correlated with sediment oxygen demand at the upstream sampling site where sediment organic carbon levels were lowest. This relationship was not observed in the more saline sampling sites. Denitrification rates were highest during winter. On an annual basis, denitrification accounted for 26% of the dissolved inorganic nitrogen and 12% of the total nitrogen supplied to the system.  相似文献   
19.
Thermal impact of typical high‐density residential, industrial, and commercial land uses is a major concern for the health of aquatic life in urban watersheds, especially in smaller, cold, and cool‐water streams. This is the first study of its kind that provides simple easy‐to‐use equations, developed using gene expression programming (GEP) that can guide the assessment and the design of urban stormwater management systems to protect thermally sensitive receiving streams. We developed 3 GEP models using data collected during 3 years (2009–2011) from 4 urban catchments; the first GEP model predicts event mean temperature at the inlet of the pond; the second model predicts the stormwater temperature at the outlet of the pond; and the third model predicts the temperature of the stormwater after flowing through a cooling trench and before discharging to the receiving stream. The new models have high correlation coefficients of 0.90–0.94 and low prediction uncertainty of less than 4% of the median value of the predicted runoff temperatures. Sensitivity analysis shows that climatic factors have the highest influence on the thermal enrichment followed by the catchment characteristics and the key design variables of the stormwater pond and the cooling trench. The general method presented here is easily transferable to other regions of the world (but not necessarily the exact equations developed here); also through sensitivity and parametric analysis, we gained insight on the key factors and their relative importance in modelling thermal enrichment of urban stromwater runoff.  相似文献   
20.
Understanding hydrological processes in wetlands may be complicated by management practices and complex groundwater/surface water interactions. This is especially true for wetlands underlain by permeable geology, such as chalk. In this study, the physically based, distributed model MIKE SHE is used to simulate hydrological processes at the Centre for Ecology and Hydrology River Lambourn Observatory, Boxford, Berkshire, UK. This comprises a 10‐ha lowland, chalk valley bottom, riparian wetland designated for its conservation value and scientific interest. Channel management and a compound geology exert important, but to date not completely understood, influences upon hydrological conditions. Model calibration and validation were based upon comparisons of observed and simulated groundwater heads and channel stages over an equally split 20‐month period. Model results are generally consistent with field observations and include short‐term responses to events as well as longer‐term seasonal trends. An intrinsic difficulty in representing compressible, anisotropic soils limited otherwise excellent performance in some areas. Hydrological processes in the wetland are dominated by the interaction between groundwater and surface water. Channel stage provides head boundaries for broad water levels across the wetland, whilst areas of groundwater upwelling control discrete head elevations. A relic surface drainage network confines flooding extents and routes seepage to the main channels. In‐channel macrophyte growth and its management have an acute effect on water levels and the proportional contribution of groundwater and surface water. The implications of model results for management of conservation species and their associated habitats are discussed. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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