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221.
222.
Ronny Boch Xianfeng Wang Tobias Kluge Albrecht Leis Ke Lin Hannes Pluch Florian Mittermayr Andre Baldermann Michael E. Bttcher Martin Dietzel 《Sedimentology》2019,66(2):604-635
The well‐known Erzberg site represents the largest siderite (FeCO3) deposit in the world. It consists of various carbonates accounting for the formation of prominent CaCO3 (dominantly aragonite) precipitates filling vertical fractures of different width (centimetres to decimetres) and length (tens of metres). These commonly laminated precipitates are known as ‘erzbergite’. This study focuses on the growth dynamics and environmental dependencies of these vein fillings. Samples recovered on‐site and from mineral collections were analyzed, and these analyses were further complemented by modern water analyses from different Erzberg sections. Isotopic signatures support meteoric water infiltration and sulphide oxidation as the principal hydrogeochemical mechanism of (Ca, Mg and Fe) carbonate host rock dissolution, mobilization and vein mineralization. Clumped isotope measurements revealed cool formation temperatures of ca 0 to 10°C for the aragonite, i.e. reflecting the elevated altitude Alpine setting, but unexpectedly low for aragonite nucleation. The 238U–234U–230Th dating yielded ages from 285·1 ± 3·9 to 1·03 ± 0·04 kyr bp and all samples collected on‐site formed after the Last Glacial Maximum. The observed CaCO3 polymorphism is primarily controlled by the high aqueous Mg/Ca ratios resulting from dissolution of Mg‐rich host rocks, with Mg/Ca further evolving during prior CaCO3 precipitation and CO2 outgassing in the fissured aquifer. Aragonite represents the ‘normal’ mode of erzbergite formation and most of the calcite is of diagenetic (replacing aragonite) origin. The characteristic lamination (millimetre‐scale) is an original growth feature and mostly associated with the deposition of stained (Fe‐rich) detrital particle layers. Broader zonations (centimetre‐scale) are commonly of diagenetic origin. Petrographic observations and radiometric dating support an irregular nature for most of the layering. Open fractures resulting from fault tectonics or gravitational mass movements provide water flow routes and fresh chemical reaction surfaces of the host rock carbonates and accessory sulphides. If these prerequisites are considered, including the hydrogeochemical mechanism, modern water compositions, young U‐Th ages and calculated precipitation rates, it seems unlikely that the fractures had stayed open over extended time intervals. Therefore, it is most likely that they are geologically young. 相似文献
223.
Occurrence of selected estrogens in mangrove sediments 总被引:1,自引:0,他引:1
Froehner S Machado KS Stefan E Bleninger T da Rosa EC Martins Cde C 《Marine pollution bulletin》2012,64(1):75-79
This paper presents results related to the occurrence and distribution of estrogens along the Brazilian coast. Three mangrove areas were chosen to evaluate the presence of estrogens in surface sediments of mangrove forests. The presence of estrogens was observed in all studied sites. 17-α-Ethinylestradiol (EE2), a synthetic estrogen, was the most common and has been found in higher concentration (0.45-129.78 ng/g) compared to 17-β-estradiol (E1) and estrone (E2) (both being natural estrogens). The concentrations of E1 and E2 ranged from 0.02 to 49.27 ng/g and 0.03 to 39.77 ng/g, respectively. Theoretically, under anaerobic conditions EE2 can be reduced to E1 even in environments such as sediments of mangrove forests, which are essentially anaerobic. Even if the concentrations of estrogens seem to be insignificant in some samples, the effects remain uncertain. 相似文献
224.
225.
Christina Flechsig Tobias Fabig Carsten Rücker Claudia Schütze 《Studia Geophysica et Geodaetica》2010,54(3):443-463
The Cheb Basin, located in the western Eger (Ohře) Rift, is part of the European Cenozoic Rift system. Although presently
non-volcanic, it is the most active area within the European Rift with signs of recent geodynamic activity like emanations
of mantle derived CO2, and the repeated occurrence of swarm earthquakes, which are common features in active volcanic regions. It is assumed that
the fluids, uprising in permeable channels, play a key role for the genesis of these earthquake swarms. 相似文献
226.
Tobias Vogt Eduard Hoehn Philipp Schneider Anja Freund Mario Schirmer Olaf A. Cirpka 《Advances in water resources》2010
A key parameter used in the assessment of bank filtration is the travel time of the infiltrated river water during the passage through groundwater. We analyze time series of electrical conductivity (EC) in the river and adjacent groundwater observation wells to investigate travel times of young hyporheic groundwater in adjoining channelized and restored sections of River Thur in North-East Switzerland. To quantify mixing ratios and mean residence times we perform cross-correlation analysis and non-parametric deconvolution of the EC time series. Measurements of radon-222 in the groundwater samples validate the calculated residence times. A simple relationship between travel time and distance to the river has not been observed. Therefore, we speculate that the lateral position and depth of the thalweg as well as the type of bank stabilization might control the infiltration processes in losing rivers. Diurnal oscillations of EC observed in the river and in nearby observation wells facilitate analyzing the temporal variation of infiltration. The diurnal oscillations are particularly pronounced in low flow situations, while the overall EC signal is dominated by individual high-flow events. Differences in travel times derived from diurnal and overall EC signals thus reflect different infiltration regimes. 相似文献
227.
Boris Gurevich Miroslav Brajanovski Robert J. Galvin Tobias M. Müller Julianna Toms-Stewart 《Geophysical Prospecting》2009,57(2):225-237
Natural fractures in hydrocarbon reservoirs can cause significant seismic attenuation and dispersion due to wave induced fluid flow between pores and fractures. We present two theoretical models explicitly based on the solution of Biot's equations of poroelasticity. The first model considers fractures as planes of weakness (or highly compliant and very thin layers) of infinite extent. In the second model fractures are modelled as thin penny-shaped voids of finite radius. In both models attenuation is a result of conversion of the incident compressional wave energy into the diffusive Biot slow wave at the fracture surface and exhibits a typical relaxation peak around a normalized frequency of about 1. This corresponds to a frequency where the fluid diffusion length is of the order of crack spacing for the first model and the crack diameter for the second. This is consistent with an intuitive understanding of the nature of attenuation: when fractures are closely and regularly spaced, the Biot's slow waves produced by cracks interfere with each other, with the interference pattern controlled by the fracture spacing. Conversely, if fractures are of finite length, which is smaller than spacing, then fractures act as independent scatterers and the attenuation resembles the pattern of scattering by isolated cracks. An approximate mathematical approach based on the use of a branching function gives a unified analytical framework for both models. 相似文献
228.
229.
Georg F. Zellmer Tobias P. Fischer Chang-Hwa Chen 《Journal of Volcanology and Geothermal Research》2008
In this introduction, recent progress in the study of the evolution, transfer and release of magmas and volcanic gases is briefly reviewed, based on discussions at the MAG2007 international conference held in Taipei, Taiwan, in April 2007. The meeting pooled the diverse expertise of igneous and volcanic gas geochemists. This special issue, which presents six case studies covering a range of topics from variations in mantle source compositions to the nature of volcanic degassing, reflects that diversity. 相似文献
230.
Sofia Lopes Maxim Lebedev Tobias M. Müller Michael B. Clennell Boris Gurevich 《Geophysical Prospecting》2014,62(5):1126-1142
Quantitative interpretation of time‐lapse seismic data requires knowledge of the relationship between elastic wave velocities and fluid saturation. This relationship is not unique but depends on the spatial distribution of the fluid in the pore‐space of the rock. In turn, the fluid distribution depends on the injection rate. To study this dependency, forced imbibition experiments with variable injection rates have been performed on an air‐dry limestone sample. Water was injected into a cylindrical sample and was monitored by X‐Ray Computed Tomography and ultrasonic time‐of‐flight measurements across the sample. The measurements show that the P‐wave velocity decreases well before the saturation front approaches the ultrasonic raypath. This decrease is followed by an increase as the saturation front crosses the raypath. The observed patterns of the acoustic response and water saturation as functions of the injection rate are consistent with previous observations on sandstone. The results confirm that the injection rate has significant influence on fluid distribution and the corresponding acoustic response. The complexity of the acoustic response —‐ that is not monotonic with changes in saturation, and which at the same saturation varies between hydrostatic conditions and states of dynamic fluid flow – may have implications for the interpretation of time‐lapse seismic responses. 相似文献