Synthesis and stability relations of wairakite,CaAl2 Si4 O12·2H2O     

J. G. Liou 《Contributions to Mineralogy and Petrology》1970,27(4):259-282

Hydrothermal investigation of the bulk composition CaO·Al₂O₃·4SiO₂ + excess H₂O has been conducted using conventional techniques over the temperature range 200–500° C and 500–5,000 bars P _fluid. The fully ordered wairakite was synthesized unequivocally in the laboratory, probably for the first time.The gradual, sluggish and continuous transformation from disordered to ordered wairakite evidently accounts for failure by previous investigators to synthesize ordered wairakite in runs of week-long duration. The dehydration of metastable disordered wairakite to metastable hexagonal anorthite, quartz and H₂O has been determined; this reaction takes place at temperatures exceeding 400° C, even at fluid pressures of 500 bars or less. The upper P _fluid-T boundary of the disordered phase is equivalent to the maximum temperature curve of synthetic wairakite presented by previous investigators. The hydrothermal breakdown of natural wairakite above its stability limit appears to be a very slow process.The equilibrium dehydration of wairakite to anorthite, quartz and H₂O occurs at 330±5° C at 500 bars, 348±5° C at 1,000 bars, 372±5° C at 2,000 bars and 385±5° C at 3,000 bars. Where fluid pressure equals total pressure, the thermal stability range of wairakite is about 100° C wide. At lower temperatures wairakite reacts with H₂O to form laumontite. Reconnaissance experiments dealing with the effect of CO₂ on stabilities of calcium zeolites suggest that wairakite or laumontite may be replaced by the assemblage calcite + montmorillonite in the presence of a CO₂-bearing fluid phase.The determined P _fluid -T field of wairakite is compatible with field observations in some metamorphic terrains where it is related to the shallow emplacement of granitic magma and with direct pressure-temperature measurements in certain active geothermal areas. Under inferred conditions of higher _CO2/_H2O ratios, essentially unmetamorphosed rocks grade directly into those characteristic of the greenschist facies; moderately high values of _CO2 in carbonate-bearing rocks result in the downgrade extension of the greenschist facies at the expense of zeolite-bearing assemblages.  相似文献   

Transition of UHP eclogites to gneissic rocks of low-amphibolite facies during exhumation: evidence from the Dabie terrane, central China   总被引：11，自引：0，他引：11  

Ru Y. Zhang  Juhn G. Liou  Yong F. Zheng  Bin Fu 《Lithos》2003,70(3-4):269-291

The Shuanghe ultrahigh-pressure (UHP) slab in the Dabie Mountains consists of layered coesite-bearing eclogite, jadeite quartzite, marble and biotite gneiss, and is fault bounded against hosting orthogneiss. Representative assemblages of eclogite are Grt+Omp+Coe+Rt±Ky±Phn±Mgs; it formed at P>27 kbar and 680–720±50 °C. During exhumation, these UHP rocks experienced multistage retrograde metamorphism. Coesite was overprinted by quartz aggregates, phengite by biotite±muscovite and rutile by titanite. Garnet was successively replaced by a thin rim of Amp, Amp+Pl, and Amp+Ep±Bt+Pl (minor). Omphacite and kyanite were replaced by Amp+Pl±Cpx (or ±Bt) and by Zo+Pl+Ms±Mrg±Bt, respectively. Secondary calcite occurs as irregular pockets in some layers. An outcrop near the UHP slab border is composed of 20 thin, concordant layers of foliated eclogites, amphibolite and gneissic rocks of variable bulk composition. These layers exhibit mineral assemblages and textures transitional from less altered through extensively retrograded eclogite to gneissic rock of low-amphibolite facies through hydration, metasomatism and recrystallization. Retrograde metamorphism has caused oxygen and hydrogen isotope disequilibria between some of the minerals, but the fluid for retrograde reactions was internally buffered in the stable isotope compositions. Retrograde metamorphism of variable extent may be attributed to selective infiltration of retrograde fluids of CO₂-rich and low-salinity aqueous, intensity of deformation and mineral resistance to alteration. The fluid phase for retrogression may have occurred either as discontinuous flow along grain boundaries in completely retrograded eclogites, and/or as isolated pockets in extensive or less altered eclogite layers.  相似文献   

Letter from the Guest Editor     

Yuei-An Liou 《GPS Solutions》2005,9(2):85-87

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Different mechanisms of the ionospheric influence on GPS occultation signals     

A. G. Pavelyev  J. Wickert  Y. A. Liou  Ch. Reigber  T. Schmidt  K. Igarashi  A. A. Pavelyev  S. S. Matyugov 《GPS Solutions》2005,9(2):96-104

A local mechanism for strong ionospheric effects on radio occultation (RO) global positioning satellite system (GPS) signals is described. Peculiar zones centered at the critical points (the tangent points) in the ionosphere, where the gradient of the electron density is perpendicular to the RO ray trajectory, strongly influence the amplitude and phase of RO signals. It follows from the analytical model of local ionospheric effects that the positions of the critical points depend on the RO geometry and the structure of the ionospheric disturbances. Centers of strong ionospheric influence on RO signals can exist, for example, in the sporadic E-layers, which are inclined by 3–6° relative to the local horizontal direction. Also, intense F2 layer irregularities can contribute to the RO signal variations. A classification of the ionospheric influence on the GPS RO signals is introduced using the amplitude data, which indicates different mechanisms (local, diffraction, etc.) for radio waves propagation. The existence of regular mechanisms (e.g., local mechanism) indicates a potential for separating the regular and random parts in the ionospheric influence on the RO signals.  相似文献   

Petrogenetic grid for ultrahigh-pressure metamorphism in the model system CaO-MgO-SiO₂-CO₂-H₂O     

Y. Ogasawara  J. G. Liou  R. Y. Zhang 《Island Arc》1995,4(4):240-253

Abstract Petrogenetic grids for ultrahigh-pressure (UHP) metamorphism were calculated at different X_co2 conditions in the model system CaO-MgO-SiO₂-CO₂-H₂O involving coesite (Co), diopside (Di), dolomite (Do), enstatite (En), forsterite (Fo), magnesite (Ms), quartz (Qz), talc (Tc), tremolite (Tr) using a published internally consistent thermodynamic data set. Two P-T grids at X_co2= 0.01 and 0.5 are described. In the calculated P-T grid at X_co2= 0.01, four out of 10 stable invariant points, Co-En-Ms-Tc, Co-Di-En-Tc-Tr, Co-Di-Ms-Tc-Tr and Di-En-Ms-Tc-Tr lie within the stability field of coesite. If the fluid phase has X_co2= 0.5, no invariant point is stable under UHP conditions. Some magnesite-bearing assemblages are stabilized by the following three reactions: Di + Ms = Do + Fo + CO₂, Ms + Tr = Do + Fo + CO₂+ H₂O and Ms + Tc = Fo+ CO₂+ H₂O at X_co2= 0.01 and by reaction Ms + Tc = Fo + CO₂+ H₂O together with these three at X_co2= 0.5. Ten possible UHP assemblages for mafic and ultramafic compositions at very low X_co2 conditions include the following: Co-Do-Ms, Co-Di-Ms, Co-Di-Tc, Di-Ms-Tc, Di-En-Tc-, Di-En-Ms, Co-Di-En, Di-En-Fo, Di-Fo-Ms, Di-Do-Fo. Among them, talc-bearing assemblages are restricted to X_co2 < 0.02 and their high-P limit is 31.7 kb (749°C) at X_co2= 0.01. Dolomite-magnesite-silica assemblages have large P-T stability fields even if X_co2 is as low as 0.1, and could occur in cold subduction zones with very low geothermal gradients. Reported UHP coesite-dolomite assemblage is restricted only to a calc-silicate rock interlayered with marble where X_co2 is relatively higher; no such assemblage appears for mafic and ultramafic rocks with low X_co2 evidenced by the occurrence of diopside (or omphacite) at the expense of dolomite + coesite. The effect of X_co2 on the stability of coesite-dolomite-magnesite, diopside-enstatite-magnesite, diopside-talc assemblages is examined and the occurrence of coesite-dolomite, magnesite-bearing and talc-bearing assemblages in the Dabie UHP rocks are interpreted by employing the calculated P-T grids.  相似文献   

Exploration of the remote sounding of infrared cooling rates due to water vapor     

Prof. Kuo-Nan Liou  Dr. Yongkang Xue 《Meteorology and Atmospheric Physics》1988,38(3):131-139

Summary We explore the feasibility of deriving atmospheric infrared cooling rates by direct inversion of radiances observed by satellites from space. In order to convert radiances to fluxes and achieve vertical profiling at the same time, we show that it is necessary to combine radiances from narrow channels with radiances averaged over spectral bands. We demonstrate that the vertical integral of the cooling rate in the spectral band, convolved with a kernel function associated with the narrow channel, can be related to a weighted sum of the channel and band radiances. The band radiance must be evaluated at a specific zenith angle, which is a result of use of the mean value theorem. With known kernel functions, the combined radiances may be inverted to obtain the cooling rate profile. These results are derived from use of a random model for the transmittance in its strong-and weak-line limits. The results are similar in the two limits leading us to conclude that there are expressions that are approximately valid over the entire range of transmittance. We show by numerical methods that this conclusion is correct and apply the retrieval technique successfully to get the cooling rate profile in the rotational band of water vapor.With 3 Figures  相似文献   

An experimental study on the process of zeolite formation     

Rona J. Donahoe  J.G. Liou 《Geochimica et cosmochimica acta》1985,49(11):2349-2360

Results are reported of an experimental study which examined the effect of solution composition on the composition, structure, and crystallization path of phillipsite and merlinoite in the system Na₂OK₂O-Al₂O₃-SiO₂H₂O at 80°C and $\text{pH = 13.34–13.71}$.At a fixed 3.5 M total dissolved silica concentration, zeolite Si/Al ratio was found to be a linear function of pH within the pH range of the experiments.²⁹Si NMR spectra of the initial solutions show that pH determines the distribution of aqueous aluminosilicate species and, as a result, the precipitated zeolite Si/Al ratio. SEM observations reveal that zeolites may precipitate with or without the presence of an intermediary gel phase, depending on solution composition. The growth rate of the zeolites was found to be dependent upon solution pH and total dissolved aluminum concentration. These observations are discussed in terms of their possible applications to natural zeolite paragenesis and serve to delineate the framework of a comprehensive theory for the mechanism of zeolite crystallization from highly alkaline solutions.  相似文献   

Remote sounding of the cirrus optical depth and temperature from 3.7 and 11 micrometer windows     

Huang Runheng  Kuo_Nan Liou 《大气科学进展》1984,1(2):150-178

On the basis of forward IR radiation transfer analyses for an atmosphere containing semi-transparent, non-black cirrus, parameterization equations are derived for the retrieval of the cloud optical depth and cloud temperature utilizing AVHRR 3.7 and 10.8 μum channels. The retrieval techniques developed involve the use of either dual-frequency or dual-scanning angle radiance observations. We show that the cloud optical depth and cloud temperature may be inferred successively from the observed brightness temperature differences using these two techniques. Numerical experiments anderror analyses demonstrate that the dual-frequency method is specifically appropriate for optically thin cirrus cases (τ <1). In case the optical depth of cirrus is close to 3, combination of dual-frequency and dual-scanning angle methods is shown to give reasonable accuracy for the cloud optical depth and temperature retrieval.  相似文献   

Ice microphysics and climatic temperature feedback     

Szu-cheng Ou  Kuo-Nan Liou 《Atmospheric Research》1995,35(2-4)

The potential effects of ice microphysics involving ice crystal size distribution and ice water path (IWP) on climatic temperature perturbations are investigated by using a one-dimensional radiative-turbulent climate model. We define a mean effective size, denoting the width of ice crystals weighted by the geometric cross section area, to represent ice crystal size distribution. Based on aircraft measurements, both the mean effective size and IWP are related to temperature and may be parameterized as functions of temperature. The radiative properties of cirrus clouds are further parameterized in terms of these two basic cloud physics parameters. Using CO₂ doubling as the radiative forcing, feedbacks among temperature, the mean effective size and IWP, and the radiative properties of clouds are analyzed from the model results. We show that overall, a positive feedback associated with ice microphysics and the coupled radiative transfer is produced by temperature increase.  相似文献   

Very-low-temperature record of the subduction process: A review of worldwide lawsonite eclogites   总被引：11，自引：0，他引：11  

Tatsuki Tsujimori  Virginia B. Sisson  Juhn G. Liou  George E. Harlow  Sorena S. Sorensen 《Lithos》2006,92(3-4):609-624

Lawsonite eclogites preserve a record of very-low-temperature conditions in subduction zones. All occur at active margin settings, typically characterized by accretionary complexes lithologies and as tectonic blocks within serpentinite-matrix mélange. Peak lawsonite-eclogite facies mineral assemblages (garnet + omphacite + lawsonite + rutile) typically occur in prograde-zoned garnet porphyroblasts. Their matrix is commonly overprinted by higher-temperature epidote-bearing assemblages; greenschist- or amphibolite-facies conditions erase former lawsonite-eclogite relics. Various pseudomorphs after lawsonite occur, particularly in some blueschist/eclogite transitional facies rocks. Coesite-bearing lawsonite-eclogite xenoliths in kimberlitic pipes and lawsonite pseudomorphs in some relatively low-temperature ultrahigh-pressure eclogites are known. Using inclusion assemblages in garnet, lawsonite eclogites can be classified into two types: L-type, such as those from Guatemala and British Columbia, contain garnet porphyroblasts that grew only within the lawsonite stability field and E-type, such as from the Dominican Republic, record maximum temperature in the epidote-stability field.

Formation and preservation of lawsonite eclogites requires cold subduction to mantle depths and rapid exhumation. The earliest occurrences of lawsonite-eclogite facies mineral assemblages are Early Paleozoic in Spitsbergen and the New England fold belt of Australia; this suggests that since the Phanerozoic, secular cooling of Earth and subduction-zone thermal structures evolved the necessary high pressure/temperature conditions. Buoyancy of serpentinite and oblique convergence with a major strike-slip component may facilitate the exhumation of lawsonite eclogites from mantle depths.  相似文献