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21.
Stiffness variations in carbonates may be described as resulting from different concentrations of flat compliant pores or cracks, which can have a significant effect on the effective stiffness and acoustic properties (e.g., velocities and attenuations) of dry as well as saturated carbonates, although they carry extremely little porosity. As shown in this paper, the effects of dual porosity and wave-induced fluid flow or pore pressure communication may also play a significant role. On the basis of a previously published T-matrix approach to model the effective viscoelastic properties of cracked porous media, we illustrate the (frequency-dependent) effects of wave-induced fluid flow (mainly squirt flow) or pore pressure communication for a model structure consisting of a mixture of fluid-saturated porous grains and fluid-saturated cavities (vugs, etc.) that are embedded in a solid matrix associated with carbonates. We assume that the pores within the porous grains are decoupled from the pores in the solid matrix (and possibly saturated with different fluids) but that each pore system at the micro and/or mesoscale may or may not be connected. For each of four different connectivity models, we present numerical results for four different cases of microstructure (that emphasize the importance of cracks and flat compliant pores). Our numerical results indicate that the velocity and attenuation spectra of carbonates vary significantly, even when the crack density and all other volume concentrations are constant.  相似文献   
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Rock, soil, and plant (terrestrial moss, European mountain ash leaves, mountain birch leaves, bark and wood, and spruce needles and wood) samples, collected at 3 km intervals along a 120 km long transect (40 sites) cutting the city of Oslo, Norway, were analysed for their Pb concentration and Pb-isotope ratios. A general decrease in 206Pb/207Pb, 208Pb/207Pb and 206Pb/208Pb ratios, with a characteristic low variability in all plant materials and the plant-derived O-horizon of soil profiles, compared to rocks and mineral soils, is observed along the transect. It is demonstrated that minerogenic and biogenic sample materials belong to two different spheres, the lithosphere and biosphere, and that geochemical processes determining their chemical and isotopic compositions differ widely. Background variation for both sample materials needs to be established and documented at the continental and global scale before the anthropogenic influence on the geochemistry of the earth’s surface can be reliably estimated.  相似文献   
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The aim of this article is to analyse the influence of commodified cotton production on soil fertility in southern Mali. From the late 1950s and until recently, production of both cash-crop cotton and food crops have increased rapidly in this region, giving it a reputation of being an African ‘success story’. The flip side of this economic success is, however, said to be environmental degradation especially in terms of loss of soil fertility. We collected 273 soil samples in 19 villages located in various zones of land use intensity. In each village, the samples were collected on up to six different land use types varying with intensification. The analysis of the soil samples showed that soil fertility was highest in the sacred groves that have been protected and never cultivated. However, comparing soils under continuous cultivation and soils under fallow no clear trends in soil fertility were found. Cotton yields have declined since the early 1990s, while the total use of fertilisers has increased. This is often interpreted as proof of soil exhaustion, but there is no clear indication in this study that cotton-cereal rotation as practiced by smallholders in southern Mali reduces soil fertility. We argue that the decline in yields has been caused by an extensification process. Cotton fields expanded rapidly, due to attractive cotton prices in the 1990s, leading to falling investments per ha and cultivation of more marginal lands. These findings also have implications for a political ecology of commodity production and lead us to argue for an open-ended and empirically based ‘critical political ecology’.  相似文献   
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This chapter provides a lithostratigraphic correlation and the present knowledge of the depositional history of the Tertiary succession of the Scandinavian countries. The succession records an initial phase of carbonate deposition in the early Paleocene. This was succeeded by deposition of deep marine clays with intercalation of sand-rich mass-flow deposits during most of the Paleocene and Eocene. Volcanic activity in the North Atlantic was extensive at the transition from the Paleocene to the Eocene resulting in widespread sedimentation of ash-rich layers in the North Sea area. During the Oligocene, the first prograding deltaic complex developed, sourced from the Fennoscandian Shield. Late Oligocene-Early Miocene inversion and uplift of Norway and the Shetland Platform resulted in major progradation of coastal and delta plain systems. At the end of the Tertiary most of the North Sea basin was filled and the Fennoscandian Shield was flanked to the west by a broad, coalesced coastal plain.  相似文献   
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Geochemical patterns in two, correlative, Ordovician, basaltic greenstone formations from the central Norwegian Caledonides corroborate field indications of a tripartite stratigraphic subdivision of the units. Lower and upper members show similar chemical traits and are transitional to LREE-enriched, high-magnesia to low-magnesia basalts. The thicker, more massive, middle member carries the geochemical signature of LREE-depleted, normal mid-oceanic ridge tholeiites. Stratigraphic-upward petrochemical variation discerned within the individual members points to processes of either closed or open-system low-P fractional crystallization. The geochemical trends can be ascribed to a mechanism of spreading accompanied by lithospheric thinning in a marginal ocean basin situation, followed by renewed crustal thickening. Geochemical and lithovolcanic polarity indicators denote that the basin was located to the east of an Arenig-Llanvirn magmatic arc sited within the Caledonian Iapetus Ocean.  相似文献   
28.
Talc-rich rocks in Altermark occur as rims around magnetite bearing serpentinite lenses which are up to about 1 km wide. The content of magnetite in the serpentinite makes magnetic measurements possible as a method for talc-prospecting. In 1991 a helicopter-borne geophysical survey combined with geological and petrophysical mapping was carried out in the Altermark area. Several positive magnetic anomalies were detected. Positive magnetic anomalies with oval shapes, well defined boundaries and smooth anomaly curves were interpreted to be caused by serpentinite lenses. Laboratory measurements revealed susceptibilities for the serpentinites between 0.006−0.36 SI and a Q-value of approximately 0.3. Magnetic modelling of the Nakkan anomaly and subsequent drilling revealed that it was indeed a serpentinite body surrounded by talc rocks which was the cause of the anomaly. The shallowest part was located about 150 m below surface. The geophysical exploration led to the discovery of a talc-carbonate deposit with an anticipated in situ tonnage of more than 1 million tons. The present study consequently proved to be a classical case study where we were able to locate and establish the three-dimensional form of serpentinite bodies associated with talc deposits. We conclude that helicopter-borne geophysical surveying is an effective tool in the exploration of serpentinite cored talc bearing rocks in complex geological areas where exposures are poor or absent and accessibility difficult. The rough topography and dense vegetation in the Altermark area make this type of survey very cost effective.  相似文献   
29.
The acoustic signature of fluid flow in complex porous media   总被引:2,自引:0,他引:2  
Effective medium approximations for the frequency-dependent and complex-valued effective stiffness tensors of cracked/porous rocks with multiple solid constituents are developed on the basis of the T-matrix approach (based on integral equation methods for quasi-static composites), the elastic–viscoelastic correspondence principle, and a unified treatment of the local and global flow mechanisms, which is consistent with the principle of fluid mass conservation. The main advantage of using the T-matrix approach, rather than the first-order approach of Eshelby or the second-order approach of Hudson, is that it produces physically plausible results even when the volume concentrations of inclusions or cavities are no longer small. The new formulae, which operates with an arbitrary homogeneous (anisotropic) reference medium and contains terms of all order in the volume concentrations of solid particles and communicating cavities, take explicitly account of inclusion shape and spatial distribution independently. We show analytically that an expansion of the T-matrix formulae to first order in the volume concentration of cavities (in agreement with the dilute estimate of Eshelby) has the correct dependence on the properties of the saturating fluid, in the sense that it is consistent with the Brown–Korringa relation, when the frequency is sufficiently low. We present numerical results for the (anisotropic) effective viscoelastic properties of a cracked permeable medium with finite storage porosity, indicating that the complete T-matrix formulae (including the higher-order terms) are generally consistent with the Brown–Korringa relation, at least if we assume the spatial distribution of cavities to be the same for all cavity pairs. We have found an efficient way to treat statistical correlations in the shapes and orientations of the communicating cavities, and also obtained a reasonable match between theoretical predictions (based on a dual porosity model for quartz–clay mixtures, involving relatively flat clay-related pores and more rounded quartz-related pores) and laboratory results for the ultrasonic velocity and attenuation spectra of a suite of typical reservoir rocks.  相似文献   
30.
The Lower Ordovician Løkken ophiolite fragment shows a tripartite subdivision of its thick volcanic sequence into: (1) an Upper Volcanic Member (UVM) of transitional MORB/IAT character, comprising basalts or, in a related, thrust-bounded sequence, a bimodal basalt-rhyolite assemblage; (2) a Middle Volcanic Member (MVM) derived from widely variable, generally MORB-related magmas; and (3) a Lower Volcanic Member (LVM) of N-type MORB basalts which locally passes into an underlying sheeted dyke complex. The UVM and LVM were fed from relatively deep-seated magma chambers, and lavas were erupted at moderate flow rates to form predominantly pillow lavas. The whole sequence is interpreted as having formed in a marginal basin setting. The MVM is characterized by abundant voluminous sheet basalts thought to have been erupted at high flow rates. The volcanites had their source, through extensive dyke swarms, in high-level magmas which intruded the sheeted dyke complex and parts of the LVM, possibly in a near-axial seamount setting. The magmas differentiated to form plagiogranitic melts, with a wide range of conjunctive, mafic to intermediate cumulates. This plutonic assemblage, possibly in crystal mush form, was subsequently intruded by new, mafic magma, leading partly to large-scale remelting or assimilation of cumulus phases. These processes are reflected in the MVM by common hybrid flows, as well as local intermediate lavas having the geochemical characteristics of cumulates, erupted during a period of intense faulting. Major tapping of the primary, mafic magma occurred toward the end of the period of MVM volcanism. A predominance of voluminous, apparently fluid, massive flows in the MVM is mainly ascribed to the shallow depth of magma reservoirs.  相似文献   
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