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131.
Predictability of the subtropical dipole modes is assessed using the SINTEX-F coupled model. Despite the known difficulty in predicting subtropical climate due to large internal variability of the atmosphere and weak ocean–atmosphere coupling, it is shown for the first time that the coupled model can successfully predict the South Atlantic Subtropical Dipole (SASD) 1 season ahead, and the prediction skill is better than the persistence in all the 1–12 month lead hindcast experiments. There is a prediction barrier in austral winter due to the seasonal phase locking of the SASD to austral summer. The prediction skill is lower for the Indian Ocean Subtropical Dipole (IOSD) than for the SASD, and only slightly better than the persistence till 6-month lead because of the low predictability of the sea surface temperature anomaly in its southwestern pole. However, for some strong IOSD events in the last three decades, the model can predict them 1 season ahead. The co-occurrence of the negative SASD and IOSD in 1997/1998 austral summer can be predicted from July 1st of 1997. This is because the negative sea level pressure anomalies over the South Atlantic and the southern Indian Ocean in September–October (November–December) that trigger the occurrence of the negative SASD and IOSD are related to the well predicted tropical Indian Ocean Dipole (El Niño/Southern Oscillation). Owing to the overall good performances of the SINTEX-F model in predicting the SASD, some strong IOSD, and El Niño/Southern Oscillation, the prediction skill of the southern African summer precipitation is high in the SINTEX-F model.  相似文献   
132.
A recently identified climate mode called Ningaloo Niño (Niña) is associated with positive (negative) sea surface temperature (SST) anomalies off the west coast of Australia and negative (positive) sea level pressure (SLP) anomalies in the overlying atmosphere. By conducting a series of numerical experiments with an atmospheric general circulation model, generation mechanisms of the atmospheric circulation anomalies accompanied by Ningaloo Niño/Niña are examined. Even when SST is allowed to vary interannually only in the eastern South Indian Ocean, negative (positive) SLP anomalies are formed off the west coast of Australia in Ningaloo Niño (Niña) years, supporting the existence of local ocean–atmosphere interaction. When the model is forced by SST anomalies outside of the eastern South Indian Ocean, negative (positive) SLP anomalies are also generated in Ningaloo Niño (Niña) years owing to a Matsuno–Gill type response to atmospheric convection anomalies in the tropical Pacific. It is found that the latter impact is stronger in the current atmospheric general circulation model. Regarding climatic impacts, it is shown that Ningaloo Niño (Niña) induces wet (dry) anomalies over the northwestern part of Australia even when SST anomalies outside of the eastern South Indian Ocean are excluded from the SST forcing.  相似文献   
133.
A profiling float equipped with a fluorimeter, a dissolved oxygen (DO) sensor, and temperature and salinity sensors was deployed in the subtropical mode water (STMW) formation region of the North Pacific. It acquired quasi-Lagrangian, 5-day-interval time-series records from March to July 2006. The time-series distribution of chlorophyll showed a sustained and sizable subsurface maximum at 50–100 m, just above the upper boundary of the STMW, throughout early summer (May–July). The DO concentration in this lower euphotic zone (50–100 m) was almost constant and supersaturated in the same period, becoming more supersaturated with time. On the other hand, the DO concentration at 100–150 m near the upper boundary of the STMW decreased much more slowly compared with the main layer of STMW below 150 m, even though oxygen consumption by organisms was expected to be larger in the former depth range. The small temporal variations of DO in the lower euphotic zone and near the upper boundary of the STMW were reasonably explained by downward oxygen transport because of large diapycnal diffusion near the top of the STMW. Assuming that the oxygen consumption rate at 100–150 m was the same as that in the main layer of STMW and compensated by the downward oxygen flux, the diapycnal diffusivity was estimated to be 1.7 × 10−4 m2 s−1. Nitrate transport into the euphotic zone by the same large diffusion was estimated to be 0.8 mmol N m−2 day−1. All of the transported nitrate could have been used for photosynthesis by the phytoplankton; net community production was estimated to be 5.3 mmol C m−2 day−1.  相似文献   
134.
The Blue Dot gold deposit, located in the Archean Amalia greenstone belt of South Africa, is hosted in an oxide (± carbonate) facies banded iron formation (BIF). It consists of three stratabound orebodies; Goudplaats, Abelskop, and Bothmasrust. The orebodies are flanked by quartz‐chlorite‐ferroan dolomite‐albite schist in the hanging wall and mafic (volcanic) schists in the footwall. Alteration minerals associated with the main hydrothermal stage in the BIF are dominated by quartz, ankerite‐dolomite series, siderite, chlorite, muscovite, sericite, hematite, pyrite, and minor amounts of chalcopyrite and arsenopyrite. This study investigates the characteristics of gold mineralization in the Amalia BIF based on ore textures, mineral‐chemical data and sulfur isotope analysis. Gold mineralization of the Blue Dot deposit is associated with quartz‐carbonate veins that crosscut the BIF layering. In contrast to previous works, petrographic evidence suggests that the gold mineralization is not solely attributed to replacement reactions between ore fluid and the magnetite or hematite in the host BIF because coarse hydrothermal pyrite grains do not show mutual replacement textures of the oxide minerals. Rather, the parallel‐bedded and generally chert‐hosted pyrites are in sharp contact with re‐crystallized euhedral to subhedral magnetite ± hematite grains, and the nature of their coexistence suggests that pyrite (and gold) precipitation was contemporaneous with magnetite–hematite re‐crystallization. The Fe/(Fe+Mg) ratio of the dolomite–ankerite series and chlorite decreased from veins through mineralized BIF and non‐mineralized BIF, in contrast to most Archean BIF‐hosted gold deposits. This is interpreted to be due to the effect of a high sulfur activity and increase in fO2 in a H2S‐dominant fluid during progressive fluid‐rock interaction. High sulfur activity of the hydrothermal fluid fixed pyrite in the BIF by consuming Fe2+ released into the chert layers and leaving the co‐precipitating carbonates and chlorites with less available ferrous iron content. Alternatively, the occurrence of hematite in the alteration assemblage of the host BIF caused a structural limitation in the assignment of Fe3+ in chlorite which favored the incorporation of magnesium (rather than ferric iron) in chlorite under increasing fO2 conditions, and is consistent with deposits hosted in hematite‐bearing rocks. The combined effects of reduction in sulfur contents due to sulfide precipitation and increasing fO2 during progressive fluid‐rock interactions are likely to be the principal factors to have caused gold deposition. Arsenopyrite–pyrite geothermometry indicated a temperature range of 300–350°C for the associated gold mineralization. The estimated δ34SΣS (= +1.8 to +2.5‰) and low base metal contents of the sulfide ore mineralogy are consistent with sulfides that have been sourced from magma or derived by the dissolution of magmatic sulfides from volcanic rocks during fluid migration.  相似文献   
135.
The assessment of surface water resources (SWRs) in the semi‐arid Yongding River Basin is vital as the basin has been in a continuous state of serious water shortage over the last 20 years. In this study, the first version of the geomorphology‐based hydrological model (GBHM) has been applied to the basin over a long period of time (1956–2000) as part of an SWR assessment. This was done by simulating the natural hydrological processes in the basin. The model was first evaluated at 18 stream gauges during the period from 1990 to 1992 to evaluate both the daily streamflows and the annual SWRs using the land use data for 1990. The model was further validated in 2000 with the annual SWRs at seven major stream gauges. Second, the verified model was used in a 45‐year simulation to estimate the annual SWRs for the basin from 1956 to 2000 using the 1990 land use data. An empirical correlation between the annual precipitation and the annual SWRs was developed for the basin. Spatial distribution of the long‐term mean runoff coefficients for all 177 sub‐basins was also achieved. Third, an additional 10‐year (1991–2000) simulation was performed with the 2000 land use data to investigate the impact of land use changes from 1990 to 2000 on the long‐term annual SWRs. The results suggest that the 10‐year land use changes have led to a decrease of 8·3 × 107 m3 (7·9% of total) for the 10‐year mean annual SWRs in the simulation. To our knowledge, this work is the first attempt to assess the long‐term SWRs and the impact of land use change in the semi‐arid Yongding River Basin using a semi‐distributed hillslope hydrological model. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
136.
Anomalous shocked quartz with high density (less than 1 % of density-deviation) is considered to be a relict of ultra high-pressure at meteoritic impact. The shocked quartz grains can be found only in terrestrial and artificial impact craters, meteorites and the Cretaceous-Tertiary (K/T) boundary samples. Volcanic activity is considered to be started or accelerated by enormous impact event.  相似文献   
137.
Abstract— The Y-86751 chondrite (CV3) consists of fine-grained Ca- and Al-rich inclusions (CAIs), amoeboid olivine inclusions (AOIs), spinel-rich inclusions, chondrules with and without dark rims, dark inclusions, isolated minerals, metal-sulfide aggregates, and matrix. Olivines in chondrules without dark rims and AOIs coexist with magnetite and show strong zoning from a magnesian core to a ferroan rim. Spinels in spinel-rich inclusions show similar zoning. This zoning seems to be caused by exchange reaction of olivine and spinel with an oxidized nebular gas prior to the accretion onto the parent body, and the Mg/Fe diffusion in olivines and spinels took place at a temperature of about 830–860 K. At the same time, enstatite in chondrules without dark rims was replaced by ferroan olivine at the grain boundaries. This feature suggests that chondrules without dark rims, fine-grained CAIs, spinel-rich inclusions, and AOIs have experienced oxidation in an oxidizing nebular gas. The oxygen fugacity of the oxidized nebular gas was >10?27.3 bars at about 830 K, being more than 104x larger than that of the canonical nebular gas. Magnetite occurs in the Y-86751 matrix in close association with Ni-rich taenite and Co-rich metal, and it was produced under a condition with the oxygen fugacity of ~10?38 bars at a temperature of about 620–650 K. On the other hand, olivines in chondrules with dark rims and dark inclusions are magnesian and rich in MnO. They do not show such strong zoning. Probably they were in equilibrium with a nebular gas under a redox condition different from the oxidized nebular gas that produced the zoned olivines in chondrules without dark rims.  相似文献   
138.
Potentially toxic metals, such as Cu, Pb and Zn, are leached from weathered rocks at many closed mine sites due to the acidic environments and mineralogical modifications. The mobilized toxic metals may cause contamination of surrounding water bodies. In this study, both laboratory column experiments and field observations at a former mine located in the north of Japan were carried out to compare the leaching behavior of Cu, Pb and Zn. The thickness of the surface weathered rock was varied (10, 20 and 30 cm) for the columns experiments while porous cups for porewater sampling were set up at different depths (GL-15, -45, -70, and -95 cm) for the field observations. Deionized water was added once a week over 75 weeks to the columns to simulate rainfall while porewater was extracted by a vacuum pump in several sampling campaigns (over 18 months). Similar low pH and leaching behavior of potentially toxic metals were observed for column experiments and field observations. A moderate increase in concentration with depth was observed for Cu and Zn. However, no increase in concentration was observed for Pb. This suggests that the leaching of Cu and Zn is enhanced by the length of the flow pathway through the weathered rock layer while Pb concentration is restricted by the precipitation of insoluble Pb sulfate. Thus, the thickness of the weathered rock layer is an important parameter that should be taken into consideration to estimate the loads of some potentially toxic metals, which is important when designing remediation schemes.  相似文献   
139.
High-time resolution 14C dating of Lake Baikal sediment cores indicates negative and positive anomalies of calculated linear sedimentation rate (LSR; 1.1 and 35.6 cm/ka, respectively) during the period of climate transition from the last glacial to Holocene. The timing of the Lake Baikal apparent LSR anomalies is consistent with that of the changes in the atmospheric radiocarbon concentration (Δ14C) during Younger Dryas rapid cooling event. 14C dating of lipids in the Lake Baikal surface sediments revealed that the sources of sedimentary lipids were different in each basin. In the Northern Basin of Lake Baikal, the 14C age of total lipids from the surface sediment (4.0 14C ka) was found to be older than that of TOC (1.6 14C ka). By contrast, the 14C age of total lipids in the Southern Basin was younger than that of the TOC by ca. 0.7–3.0 ka.In the Lake Hovsgol sediment cores, ages of the main lithologic boundaries during the last glacial–interglacial transition were estimated based on new 14C data sets. TOC concentration in the cores started to rapidly increase at 13.8 ± 0.3 14C ka at the base of the basinwide finely laminated layer deposited during Bølling/Allerød. The base of the layer diatomaceous mud corresponds to the end of Younger Dryas event (10.6 ± 0.1 14C ka).  相似文献   
140.
δ13C data from Tethyan sections provide evidence of profound changes in the carbon cycle during the Lower Triassic. Sections from the Panthalassa realm were investigated to establish whether these variations are also present there. In the Jurassic accretionary wedges in Japan, exotic blocks having a Panthalassan affinity, have been incorporated. The majority of the blocks are pelagic cherts but rare shallow-water carbonates are also present. We present a δ13C study on the Lower Triassic of a shallow-water carbonate succession deposited on a mid-oceanic seamount and accreted to the Chichibu Belt, Japan. Two sections have been measured at Kamura, central Kyushu Island. The carbon isotope curve shows depleted values across the Permian–Triassic boundary (PTB), subsequently followed by an increase to heavier values into the Dienerian, culminating in a maximum of almost +4‰ V-PDB, before a steep drop at a stratigraphic gap. Low values are recorded in the Smithian, but rise to enriched δ13C values > +3.5‰ near the Smithian–Spathian boundary. The observed trend of the stable carbon isotope curve from Japanese sediments mirrors the curves derived from sections in the Tethys (e.g. Italy, Iran, Turkey, Oman and the South China Nanpanjing Basin). Our results support the interpretation of this curve as representing a global trend across the PTB and in the Lower Triassic, although some distinct features are absent around the Dienerian/Smithian boundary. Profound variations of the carbon isotope curve in the Lower Triassic are presented for the first time from a marine section outside of the Tethys. They indicate severe, global changes in the Lower Triassic carbon cycle, and the causative processes must have significantly contributed to the delayed biotic recovery after the PTB. Large amounts of carbon were shifted between carbon reservoirs, most probably between shallow- and deep-ocean waters, and/or ocean and sediment. Anoxia followed by overturn of the ocean water masses may have been the mechanism which quickly altered ecological conditions in the ocean leading to variable availability of nutrients and oxygen, and changes in isotope composition of the available carbon in the surface waters that was incorporated in the precipitated carbonate.  相似文献   
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