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41.
A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO3) is a function of the DMS flux, because the reaction of DMS with NO3 is the most important loss mechanism of NO3. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO3 in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO3. The calculated ratio of the MSA to SO2 production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO4 2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO4 2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO3 is likely to be a more important sink of NOx (NO+NO2) than the reaction of NO2 with OH, and to serve as a significant pathway of the HNO3 production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO4 2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO3 during winter.  相似文献   
42.
From the mathematical analysis of the rare-earth data on some of the Apollo 12 samples studied by Hubbard et al. (1971), the possible europium-normal primitive rare-earth pattern, in which europium is normal with respect to the adjacent rare-earth elements, has been estimated. A fact that the igneous rocks (Japanese geosynclinal basalts) appearing to reflect the analogous effect occur locally on the earth enhances our interests in the pattern resulting from the above estimation.  相似文献   
43.
Two foliated metagabbros from the Mid-Atlantic Ridge near 30° N were analyzed for rare earth elements. The chondrite-normalized rare earth pattern for one of them is quite similar to those for abyssal tholeiites. The pattern for another sample, however, is somewhat different from the above one. A new set of bulk partition coefficients for rare earth elements has been estimated correspondingly. This set throws a new light on the interpretation that many alkali olivine basalts were produced by a zone melting or partial melting of primary-liquid-type material. Also the same partition coefficients lead us to an inference that the high-temperature peridotite intrusion in the Lizard area, Cornwall, England, is a secondary-solid-type material which was once in equilibrium with a primary-solid-type material, whereas the pyroxenite, Canyon Mountain, Oregon, is a primary-solid-type material.Both of the metagabbros studied show positive europium anomaly.  相似文献   
44.
藏北高原D110点不同季节土壤温度的日变化特征   总被引:11,自引:0,他引:11  
利用1998年GAME-Tibet加强观测期间取得的一个年周期的土壤温度资料,对藏北高原D110点土壤温度日变化特征的月际变化进行了分析。结果表明,在夏半年(5-9)月土壤温度存在明显的日变化,且基本上按正弦曲线变化,但相位随深度的增加而滞后;冬半年土壤温度尽管也存在日变化,但变幅较小。  相似文献   
45.
The St.16 core obtained from the Academician Ridge of Lake Baikal in eastern Siberia may span about 260 000 years, and some physical properties of the core samples are closely related to aquatic paleoproductivity and climatic change. The median of grain size, grain density, and water content fluctuate synchronously. They also are connected with change in the abundance of biogenic silica (diatoms). The physical parameters indicate that there were high aquatic productivity periods around interglacial periods (MIS 5 and 7; 70 000-125 000 yr B.P. and 180 000-250 000 yr B.P.). Comparatively large clastics were transported from outside of the lake through various routes (ice rafting, etc.) in addition to fluvial routes during the glacials or 'stadials. There are ca. 20 000 yr, 40 000 yr and 100 000 yr periods in the variations of physical properties. These are related to the three Milankovitch parameters of solar insolation.  相似文献   
46.
The problem of the ionospheric formation in the Jovian upper atmosphere is examined. By adopting two plausible atmospheric models, we solve coupled time-dependent continuity equations for ions H2+, H5+, H+, H3+ and HeH+ simultaneously. It is shown that both radiative and three body association of H+ to H2 are important for the determination of the structure of the Jovian ionosphere. The maximum electron density in the daytime is found to be about 105 cm?3. It is also shown that diurnal variation with large-amplitude can exist in the Jovian ionosphere.  相似文献   
47.
高原地表的感热和潜热通量在亚洲季风系统中有很重要的作用。由于高原地域辽阔,且自然环境较严酷,不利于建立完善的地面观测系统。因此,卫星遥感观测就成为测算高原整体感热和潜热通量的有效工具。地面场地的观测结果作为地表通量的真实值,对于卫星遥感测算是非常重要的。它也为构建陆面—大气模型提供了科学依据,是卫星资料的资料同化系统中的重要组成部分。 计算场地热量通量有几种不同的处理方法。最简单的方法利用有效的观测和试验的参数,可以给出稳定连续的估计。愈精确的Bowen比或者廓线的观测能给出愈精确的信息。综合了湍流测量及辐射测量、土壤热通量的观测结果的估计对陆面—大气相互作用进行了详细的描述,以适应模式的发展。从1998年开始,这些方法联合应用到青藏高原;场地通量观测方面的成果以及目前对其理解将在本文中做一概述。  相似文献   
48.
Abstract   A continuous, well-preserved core was obtained from the Choshi area, on the Pacific side of Japan, to investigate paleoceanographic and paleoclimatic changes around the northwestern Pacific region during the middle Pleistocene. Siliciclastic sequences in the core are divided into five formations – the Obama, Yokone, Kurahashi and Toyosato Formations in the Inubo Group and the Katori Formation, in ascending order. Examination of calcareous nannofossils and magnetic polarities detected four datums in the core sediments of the Inubo Group: the top of Reticulofenestra asanoi , the base of Helicosphaera inversa , the top of Pseudoemiliania lacunosa and the Brunhes–Matuyama boundary. Fourteen marine isotope stages (MIS24–MIS11) were identified in the δ18O and δ13C records based on detected datums and the graphic correlation with the standard stack oxygen isotope curve. Magnetic susceptibility and gamma-ray attenuation porosity evaluator density were also measured and low values characterize the glacial intervals. Biogenic sedimentation by primary production may be larger during the glacial periods because of invasions of nutrient-rich northern surface-waters related to the southward shift of the Kuroshio front in the Choshi area.  相似文献   
49.
Climate Warming and Water Management Adaptation for California   总被引:1,自引:3,他引:1  
The ability of California's water supply system to adapt to long-term climatic and demographic changes is examined. Two climate warming and a historical climate scenario are examined with population and land use estimates for the year 2100 using a statewide economic-engineering optimization model of water supply management. Methodologically, the results of this analysis indicate that for long-term climate change studies of complex systems, there is considerable value in including other major changes expected during a long-term time-frame (such as population changes), allowing the system to adapt to changes in conditions (a common feature of human societies), and representing the system in sufficient hydrologic and operational detail and breadth to allow significant adaptation. While the policy results of this study are preliminary, they point to a considerable engineering and economic ability of complex, diverse, and inter-tied systems to adapt to significant changes in climate and population. More specifically, California's water supply system appears physically capable of adapting to significant changes in climate and population, albeit at a significant cost. Such adaptation would entail large changes in the operation of California's large groundwater storage capacity, significant transfers of water among water users, and some adoption of new technologies.  相似文献   
50.
In this study, we report the characteristics of clay minerals present in the Chelung-pu fault in Taiwan. In the 1999 Chi-Chi earthquake, different slip motions were recorded along the Chelung-pu fault in the northern and southern parts of the fault. The characteristics of clay minerals present in the fault zones can be attributed to the differences in motion. We analyzed the shallow drill core samples obtained from the northern and southern sites penetrating the fault. The clay minerals identified in most of the samples from both the sites are smectite, illite, and chlorite. There are illite–smectite mixed layers with a high illite content and no chlorite–smectite mixed layer. In some samples, no smectite is detected. We also examined the iron content and symmetry of iron and magnesium in the silicate and hydroxide layers in chlorite. At the northern site, the total iron content in chlorite of gouge is larger than that of the host rocks. On the other hand, at the southern site, the total iron content varies widely. It is hypothesized that the smectite consumption and differences in the characteristics of chlorite may be controlled by the differences in the lithology, fluid chemistry, fluid temperature, or fault activities (heating or breakage) between the northern and southern sites.  相似文献   
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