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391.
In this study we examine the calibration of wind speed measured by a sonic anemometer, with an orthogonal probe configuration, with regard to the approximation of the flow angle, and the wind-speed dependence of the flow attenuation attributed to the transducer shadow. The flow angle should be calculated by the iterative method when the attenuation is relatively high. For a probe manufactured by Kaijo Co. TR-61C, the wind-speed dependence of the transducer shadow effect is formulated from the results of the wind-tunnel experiment. Assuming the equation is applicable to field observations, significant errors possibly remain especially when the wind speed is low, and /or the angle between the flow vector and the sonic path is small, if the wind-speed dependence in measurement errors is neglected.  相似文献   
392.
The density of liquid Fe–S was measured at 4 GPa and 1,923 K using a sink/float method with a composite density marker. The density marker consisted of a Pt rod core and an Al2O3 tube surrounding. The uncertainty in the density of the composite marker is much smaller than that of the composite sphere, which had been used in previous density measurements. The density of liquid Fe–S decreases nonlinearly with increasing sulfur content at 4 GPa and 1,923 K. This tendency is consistent with the results measured at ambient pressure. The molar volume of FeS calculated from the measured density gradually increases with sulfur content. The excess molar volume from ideal mixing of Fe and S at 4 GPa was negative value. The new method proposed here is applicable to the density measurement of other Fe alloys at high pressure. The tendency of the molar volume and the excess molar volume with sulfur content at ambient pressure is consistent with these at high pressure at least up to 4 GPa. The excess molar volume at high pressure is essential for estimating the amount of light elements in the outer core.  相似文献   
393.
The Central African Belt in the Nkambe area, northwestern Cameroon represents a collisional zone between the Saharan metacraton and the Congo craton during the Pan-African orogeny, and exposes a variety of granitoids including foliated and massive biotite monzogranites in syn- and post-kinematic settings. Foliated and massive biotite monzogranites have almost identical high-K calc-alkaline compositions, with 73–67 wt.% SiO2, 17–13 wt.% Al2O3, 2.1–0.9 wt.% CaO, 4.4–2.7 wt.% Na2O and 6.3–4.4 wt.% K2O. High concentrations of Rb (264–96 ppm), Sr (976–117 ppm), Ba (3680–490 ppm) and Zr (494–99 ppm), with low concentrations of Y (mostly< 20 ppm with a range 54–6) and Nb (up to 24 ppm) suggest that the monzogranites intruded in collisional and post-collisional settings. The Sr/Y ratio ranges from 25 to 89. K, Rb and Ba resided in a single major phase such as K-feldspar in the source. Garnet was present in the source and remained as restite at the site of magma generation. This high K2O and Sr/Y granitic magma was generated by partial melting of a granitic protolith under high-pressure and H2O undersaturated conditions where garnet coexists with K-feldspar, albitic plagioclase. CHIME (chemical Th–U-total Pb isochron method) dating of zircon yields ages of 569 ± 12–558 ± 24 Ma for the foliated biotite monzogranite and 533 ± 12–524 ± 28 Ma for the massive biotite monzogranite indicating that the collision forming the Central African Belt continued in to Ediacaran (ca 560 Ma).  相似文献   
394.
The Higo Complex of west-central Kyushu, western Japan is a 25 km long body of metasedimentary and metabasic lithologies that increase in metamorphic grade from schist in the north to migmatitic granulite in the south, where granitoids are emplaced along the southern margin. The timing of granulite metamorphism has been extensively investigated and debated. Previously published Sm–Nd mineral isochrons for garnet-bearing metapelite yielded ca.220–280 Ma ages, suggesting high-grade equilibration older than the lower grade schist to the north, which yielded ca.180 Ma K–Ar muscovite ages. Ion and electron microprobe analyses on zircon have yielded detrital grains with rim ages of ca.250 Ma and ca.110 Ma. Electron microprobe ages from monazite and xenotime are consistently 110–130 Ma. Two models have been proposed: 1) high-grade metamorphism and tectonism at ca.115 Ma, with older ages attributed to inheritance; and 2) high-grade metamorphism at ca.250 Ma, with resetting of isotopic systems by contact metamorphism at ca.105 Ma during the intrusion of granodiorite. These models are evaluated through petrographic investigation and electron microprobe Th–U–total Pb dating of monazite in metapelitic migmatites and associated lithologies. In-situ investigation of monazite reveals growth and dissolution features associated with prograde and retrograde stages of progressive metamorphism and deformation. Monazite Th–U–Pb isochrons from metapelite, diatexite and late-deformational felsic dykes consistently yield ca.110–120 Ma ages. Earlier and later stages of monazite growth cannot be temporally resolved. The preservation of petrogenetic relationships, coupled with the low diffusion rate of Pb at < 900 °C in monazite, is strong evidence for timing high-temperature metamorphism and deformation at ca.115 Ma. Older ages from a variety of chronometers are attributed to isotopic disequilibrium between mineral phases and the preservation of inherited and detrital age components. Tentative support is given to tectonic models that correlate the Higo terrane with exotic terranes between the Inner and Outer tectonic Zones of southwest Japan, possibly derived from the active continental margin of the South China Block. These terranes were dismembered and translated northeastwards by transcurrent shearing and faulting from the beginning to the end of the Cretaceous Period.  相似文献   
395.
Constraining physical parameters of tephra dispersion and deposition from explosive volcanic eruptions is a significant challenge, because of both the complexity of the relationship between tephra distribution and distance from the vent and the difficulties associated with direct and comprehensive real-time observations. Three andesitic subplinian explosions in January 2011 at Shinmoedake volcano, Japan, are used as a case study to validate selected empirical and theoretical models using observations and field data. Tephra volumes are estimated using relationships between dispersal area and tephra thickness or mass/area. A new cubic B-spline interpolation method is also examined. Magma discharge rate is estimated using theoretical plume models incorporating the effect of wind. Results are consistent with observed plume heights (6.4–7.3 km above the vent) and eruption durations. Estimated tephra volumes were 15–34?×?106 m3 for explosions on the afternoon of 26 January and morning of 27 January, and 5.0–7.6?×?106 m3 for the afternoon of 27 January; magma discharge rates were in the range 1–2?×?106 kg/s for all three explosions. Clast dispersal models estimated plume height at 7.1?±?1 km above the vent for each explosion. The three subplinian explosions occurred with approximately 12-h reposes and had similar mass discharge rates and plume heights but decreasing erupted magma volumes and durations.  相似文献   
396.
The Utanobori gold deposit is a low‐sulfidation, epithermal vein‐type deposit located in northern Hokkaido, Japan. The deposit is hosted by conglomerate, sandstone, and tuff of the Middle to Late Miocene Esashi Formation. These rocks were hydrothermally altered. Silica sinters and quartz‐adularia veins are common in the deposit. The quartz‐adularia veins either contain a ginguro band, which corresponds to the main gold‐bearing vein (Type 1 Veins), or do not contain a ginguro band but contain minor adularia (Type 2 Veins). Type 1 Veins are divided into three stages with 12–14 substages. Ore minerals identified include electrum, naumannite, chlorargyrite, bromargyrite, an unidentified Fe‐Sb mineral, and an Fe‐(Sb)‐As mineral. These ore minerals formed in the main mineralization stages I (bands I‐b and I‐d) and II (band II‐a). Scanning electron microscopy with cathodoluminescence images show that cathodoluminescence‐dark microcrystalline quartz exhibiting colloform (ghost‐sphere) texture is closely associated with ore minerals in the Type 1 Vein and Type 2 Vein, and the Al and K contents of such quartz are commonly >1000 ppm. This indicates that the ore minerals were crystallized from alkaline, silica‐saturated fluids at temperatures <200°C, which initially deposited amorphous silica that was recrystallized to microcrystalline quartz. The average Au content of electrum is 52.5 at% Au (n = 10), 65.7 at% Au (n = 20), and 55.5 at% Au (n = 5) in bands I‐b, I‐d, and II‐a, respectively, of Type 1 Veins. The δ34SCDT values of two fine‐grained disseminated pyrites in the altered conglomerate and bedded tuff in the argillic altered zone are ?4.3 and ?4.2‰. Ar‐Ar dating on adularia yielded 13.6 ± 0.06 Ma, 13.6 ± 0.07 Ma, and 13.6 ± 0.06 Ma for the stages I, II, and III of the Type 1 Vein, respectively. K‐Ar ages determined on adularia in the silica sinter and on whole‐rock of glassy rhyolite of the Esashi Formation are 15.0 ± 0.4 Ma and 14.6 ± 0.4 Ma, respectively. These radiometric ages indicate that silica sinter associated with the rhyolitic volcanic rocks formed prior to the main gold mineralization.  相似文献   
397.
The Jiayin area along the Heilongjiang River in Northeast China has attracted stratigraphic and sedimentological interests recently because the Cretaceous--Tertiary (K/T) boundary should be located in this non-marine succession.Dinosaur remains disappear suddenly at the upper part of the Maastrichtian,whereas plants gradually evolved throughout the succession.Analysis of sedimentary facies has been carried out and paleo-environments through Upper Cretaceous to lower Paleocene sections are reconstructed.Fluvial to lacustrine sedimentary environments are inferred from the facies.Several debris flow events have been identified,and it is in these deposits that the dinosaur fossils are concentrated.  相似文献   
398.
Whale carcasses (whale falls) deposited on the deep seafloor are associated with a distinctive biotic community. A fossil whale bone recovered from São Paulo Ridge, South Atlantic Ocean, during cruise YK13–04 Leg 1 of R/V Yokosuka was covered by a ferromanganese (Fe–Mn) crust approximately 9 mm thick. Here, we report an age constraint for this fossil bone on the basis of Os isotopic stratigraphy (187Os/188Os ratio) of the Fe–Mn crust. Major‐ and trace‐element compositions of the crust are similar to those of Fe–Mn crusts of predominantly hydrogenous origin. Rare earth element concentrations in samples of the crust, normalized with respect to Post‐Archean average Australian Shale, exhibit flat patterns with positive Ce and negative Y anomalies. These results indicate that the Fe–Mn crust consists predominantly of hydrogenous components and that it preserves the Os isotope composition of seawater at the time of its deposition. 187Os/188Os ratios of three Fe–Mn crust samples increased from 0.904 to 1.068 in ascending stratigraphic order. The value of 1.068 from the surface slice (0–3 mm depth in the crust) was identical to that of present‐day seawater within error (~1.06). The value of 0.904 from the basal slice (6–9 mm) equaled seawater values from ca. 4–5 Ma. Because it is unknown how long the bone lay on the seafloor before the Fe–Mn crust was deposited, the Os stratigraphic age of ca. 5 Ma is a minimum age of the fossil. This is the first application, to our knowledge, of marine Os isotope stratigraphy for determining the age of a fossil whale bone. Such data may offer valuable insights into the evolution of the whale‐fall biotic community.  相似文献   
399.
In the present study, we used catalyzed reporter deposition-fluorescence in situ hybridization to quantify the abundance of five bacterial (Alphaproteobacteria, SAR11, Gammaproteobacteria, SAR86, and Bacteroidetes) and two archaeal (Crenarchaeota and Euryarchaeota) phylotypes in the epipelagic layer (0–200 m) of the Central South Pacific Ocean along 170°W from 0° to 40°S. We found that the distribution patterns of these phylotypes differed from each other. All phylotypes except Gammaproteobacteria were particularly abundant at the surface water of the equatorial region, whereas Gammaproteobacteria was relatively abundant in the area from the southern part of the South Pacific Ocean. SAR11, affiliated with Alphaproteobacteria was the dominant phylotype at all depths, throughout the study area. The abundance of SAR11 significantly increased with chlorophyll a concentration, suggesting that phytoplankton could affect their distribution pattern. There was a positive correlation between Bacteroidetes abundance and water temperature, suggesting that the temperature gradient could be a critical factor determining their distribution in the South Pacific Ocean. Crenarchaeota and Euryarchaeota were more abundant at the equatorial region than in other study areas. Euryarchaeota abundance significantly decreased with depth, and increased with chlorophyll a concentration. This suggests that there was ecological interaction between Euryarchaeota and phytoplankton in the equatorial surface. Our data indicate that distinct hydrographic properties such as seawater temperature, salinity, and the concentrations of chlorophyll a and nutrients can principally control the basin-scale distribution of different prokaryotic phylotypes in the epipelagic layer of the Central South Pacific Ocean.  相似文献   
400.
A global survey of perfluorinated acids in oceans   总被引:26,自引:0,他引:26  
Perfluorinated acids and their salts have emerged as an important class of global environmental contaminants. Biological monitoring surveys conducted using tissues of marine organisms reported the occurrence of perfluorooctanesulfonate (PFOS) and related perfluorinated compounds in biota from various seas and oceans, including the Arctic and the Antarctic Oceans. Occurrence of perfluorinated compounds in remote marine locations is of concern and indicates the need for studies to trace sources and pathways of these compounds to the oceans. Determination of sub-parts-per-trillion (ng/L) or parts-per-quadrillion (pg/L) concentrations of aqueous media has been impeded by relatively high background levels arising from procedural or instrumental blanks. Our research group has developed a reliable and highly sensitive analytical method by which to monitor perfluorinated compounds in oceanic waters. The method developed is capable of detecting PFOS, perfluorohexanesulfonate (PFHS), perfluorobutanesulfonate (PFBS), perfluorooctanoate (PFOA), perfluorononanoate (PFNA), and perfluorooctanesulfonamide (PFOSA) at a few pg/L in oceanic waters. The method was applied to seawater samples collected during several international research cruises undertaken during 2002–2004 in the central to eastern Pacific Ocean (19 locations), South China Sea and Sulu Seas (five), north and mid Atlantic Ocean (12), and the Labrador Sea (20). An additional 50 samples of coastal seawater from several Asian countries (Japan, China, Korea) were analyzed. PFOA was found at levels ranging from several thousands of pg/L in water samples collected from coastal areas in Japan to a few tens of pg/L in the central Pacific Ocean. PFOA was the major contaminant detected in oceanic waters, followed by PFOS. Further studies are being conducted to elucidate the distribution and fate of perfluorinated acids in oceans.  相似文献   
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