Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy     

Lisa K. Whalley  Kate L. Furneaux  Tom Gravestock  Helen M. Atkinson  Catherine S. E. Bale  Trevor Ingham  William J. Bloss  Dwayne E. Heard 《Journal of Atmospheric Chemistry》2007,58(1):19-39

A Laser Induced Fluorescence (LIF) instrument has been developed to detect iodine monoxide (IO) radicals in the atmosphere. An all solid-state Nd:YAG pumped Ti:Sapphire laser operating at approximately 445 nm was used to excite the (2,0) band of the IO A²Π_3/2 ← X²Π_3/2 electronic transition, with off-resonance fluorescence in the (2,5) band detected at 521 nm. The sensitivity of the instrument was determined by calibration. IO (between 10 and 150 pptV) was generated following the 184.9 nm photolysis of N₂O/CF₃I/N₂ mixtures with O₃ actinometry used to determine the photolysis flux. The detection limit was determined to be 0.3 pptV for a 300 s integration period, with an uncertainty of 23% (1σ). The instrument was deployed in August/September 2006 during the RHaMBLe (Reactive Halogens in the Marine Boundary Layer) campaign in Roscoff, France. Located on a small jetty, a few metres from the water’s edge at high tide, the instrument measured significant levels of IO on 11 days, with a maximum of 27.6 ± 3.2 pptV observed on one day (averaged over 10 s) representing the highest IO mixing ratio recorded in the marine boundary layer to date. IO displayed a clear diurnal profile with a maximum at low tide during the daytime. These results represent the first point measurements of IO in the atmosphere by LIF.  相似文献   

Archaean greenstone belts: A structural test of tectonic hypotheses — Reply     

J.P. Platt 《Tectonophysics》1981,72(1-2)

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What to do with the oil when it is scraped up     

Trevor R. Dixon 《Marine pollution bulletin》1981,12(1):3

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Experimental duplication of a high-pressure megacryst/cumulate assemblage in a near-saturated hawaiite     

Janice Knutson  Trevor H. Green 《Contributions to Mineralogy and Petrology》1975,52(2):121-132

The occurrence of corroded megacrysts and cumulates of olivine, clinopyroxene, orthopyroxene, plagioclase, ilmenite and apatite in near-saturated hawaiites from the mid-north coast of New South Wales point to the derivation of these hawaiites at elevated pressures. In an experimental study on one of these hawaiites under conditions ranging from 5–15 kb and 0–5% H₂O, orthopyroxene was identified in only one run with 2% H₂O at 1040° C and 6.5 kb. In this run it was associated with olivine, clinopyroxene and Fe-Ti oxide. The early appearance of plagioclase in the “dry” experimental runs and amphibole in runs with 5% H₂O, indicates that the water content in the natural hawaiite was intermediate to these values. The near-duplication of the natural megacryst-cumulate assemblage suggests that the hawaiite host precipitated these phases at a depth of approximately 20–24 km, prior to rapid eruption to higher crustal levels.  相似文献   

Extensional structures in anisotropic rocks   总被引：2，自引：0，他引：2  

J.P. Platt  R.L.M. Vissers 《Journal of Structural Geology》1980,2(4):397-410

A distinct class of structures can form as a result of extension along a plane of anisotropy (foliation). The effect of the foliation is to decrease the ductility of the material in this orientation so that brittle fractures or shear-bands develop. Foliation boudinage is caused by brittle failure; extensional fractures cause symmetric boudinage, and shear fractures cause asymmetric boudinage.Extensional crenulation cleavage is defined by sets of small-scale ductile shear-bands along the limbs of very open microfolds in the foliation. The sense of movement on the shear-bands is such as to cause a component of extension along the older foliation. Conjugate cleavage sets indicate coaxial shortening normal to the foliation; the shortening axis bisects the obtuse angle between the sets. A single set indicates oblique or non-coaxial deformation.Extensional crenulation cleavage is microstructurally and genetically distinct from other types of cleavage. It does not occur as an axial plane structure in folds, and has no fixed relationship to the finite strain axes. It is common in mylonite zones, and may be favoured by crystal-plastic and cataclastic deformational mechanisms. These cause grain-size reduction, and hence softening, which favour the development of shear-bands.  相似文献   

Mineral chemistry of layered Archaean anorthosite at Majorqap qâva,near Fiskenæsset,southwest Greenland   总被引：1，自引：0，他引：1  

J.S. Myers  R.G. Platt 《Lithos》1977,10(1):59-72

Variations of mineral chemistry are described in a layered sheet of partly metamorphosed anorthosite, leucogabbro, gabbro and peridotite. The rocks appear to represent part of two major cycles of crystal deposition in which the anorthite content of plagioclases decreases upwards from An_98?94 to An_90?75 and hornblendes show upward iron enrichment. The composition of corona minerals formed by subsolidus reaction between plagioclase and olivine in gabbro, suggests that these coronas formed under pressures of between 6 and 9 kb and at a temperature of about 800°C during a late magmatic or early metamorphic stage.  相似文献   

Cordierite breakdown under high-pressure,hydrous conditions     

Trevor H. Green  R. H. Vernon 《Contributions to Mineralogy and Petrology》1974,46(3):215-226

Clear evidence exists for a cordierite breakdown reaction to amphibole-kyanite-quartz in high-grade metamorphic rocks of the Arunta Complex, Australia. Using the natural minerals this reaction has been duplicated experimentally. It proceeds over a divariant band with a slope of 12±4 bars/°C, occurring between 8 and 10.4 kb at 750° C and between 9.5 and 11.3 kb at 850°C. The reaction is cut off at low temperature by the appearance of talc and at high temperature by the appearance of orthopyroxene. The maximum pressure stability of the amphibole-kyanite-quartz assemblage is about 20 kb. These data suggest that the natural rock was subjected to pressures of at least 8 kb at 750–850° C for high water fugacities. Other experimental data on the hydration of hypersthene and cordierite-hypersthene stability, point to a temperature below 820° C and an upper pressure limit of 9.5 kb at 750–820°C. Experiments at \(P_{{\text{H}}_{\text{2}} {\text{O}}}\) total indicate that the breakdown of cordierite to amphibole-kyanite-quartz is a hydration reaction, and occurred in the natural rock as a result of an increase of water fugacity at constant total pressure (8–9.5 kb) and temperature (750–820°C).  相似文献   

Bayesian modelling of the cool core galaxy group NGC 4325     

Paul A. Russell  Trevor J. Ponman  Alastair J. R. Sanderson 《Monthly notices of the Royal Astronomical Society》2007,378(4):1217-1228

We present an X-ray analysis of the radio-quiet cool-core galaxy group NGC 4325  ( z = 0.026)  based on Chandra and ROSAT observations. The Chandra data were analysed using xspec deprojection, 2D spectral mapping and forward-fitting with parametric models. Additionally, a Markov Chain Monte Carlo method was used to perform a joint Bayesian analysis of the Chandra and ROSAT data. The results of the various analysis methods are compared, particularly those obtained by forward-fitting and deprojection. The spectral mapping reveals the presence of cool gas displaced up to 10 kpc from the group centre. The Chandra X-ray surface brightness shows the group core to be highly disturbed, and indicates the presence of two small X-ray cavities within 15 kpc of the group core. The xspec deprojection analysis shows that the group has a particularly steep entropy profile, suggesting that an active galactic nucleus (AGN) outburst may be about to occur. With the evidence of prior AGN activity, but with no radio emission currently observed, we suggest that the group in a pre-outburst state, with the cavities and displaced gas providing evidence of a previous, weak AGN outburst.  相似文献   

Towards improving the framework for probabilistic forecast evaluation   总被引：1，自引：0，他引：1  

Leonard A. Smith  Emma B. Suckling  Erica L. Thompson  Trevor Maynard  Hailiang Du 《Climatic change》2015,132(1):31-45

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Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer     

John A. Izbicki  Christen E. Petersen  Kenneth J. Glotzbach  Loren F. Metzger  Allen H. Christensen  Gregory A. Smith  David O’Leary  Miranda S. Fram  Trevor Joseph  Heather Shannon 《Applied Geochemistry》2010

About 1.02 × 10⁶ m³ of chlorinated municipal drinking water was injected into a confined aquifer, 94–137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 × 10⁶ m³ of water were extracted between July 2007 and February 2008. On the basis of Cl⁻ data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with free-chlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction phase. Haloacetic acids (HAAs) were completely sorbed or degraded within 10 months of injection.  相似文献