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51.
Recent variations in the precipitation regime across southern Europe have led to changes in river fluxes and salinity gradients affecting biological communities in most rivers and estuaries. A sampling programme was developed in the Mondego estuary, Portugal, from January 2003 to December 2008 at five distinct sampling stations to evaluate spatial, seasonal and inter-annual distributions of fish larvae. Gobiidae was the most abundant family representing 80% of total catch and Pomatoschistus spp. was the most important taxon. The fish larval community presented a clear seasonality with higher abundances and diversities during spring and summer seasons. Multivariate analysis reinforced differences among seasons but not between years or sampling stations. The taxa Atherina presbyter, Solea solea, Syngnathus abaster, Crystallogobius linearis and Platichthys flesus were more abundant during spring/summer period while Ammodytes tobianus, Callionymus sp., Echiichthys vipera and Liza ramada were more abundant in autumn/winter. Temperature, chlorophyll a and river flow were the main variation drivers observed although extreme drought events (year 2005) seemed not to affect ichthyoplankton community structure. Main changes were related to a spatial displacement of salinity gradient along the estuarine system which produced changes in marine species distribution.  相似文献   
52.
Anomalously high levels of mercury in sediment in the Lenga estuary, Chile are comparable to the most contaminated sites previously reported elsewhere. Total mercury (Hgtotal) concentrations range from 0.5 to 129 mg kg−1 and organic mercury (Hgorg) from 11 to 53 μg kg−1. The highest levels are in areas near the previous wastewater outfall of a chlo-alkali plant. The results show that the proportion of Hgorg/Hgtotal in the sediment varies by more than two orders of magnitude (0.02–5.7%) according to the concentration of Hgtotal. No correlation between the concentration of Hgorg and Hgtotal was found. The lack of correlation does contrast with the findings of other authors in culture media. Our results indicate that even at very high concentrations of Hgtotal and organic matter do not influence organic mercury formation in estuary sediments. The disparity in Hgtotal and Hgorg concentrations also attests to environmental differences in the formation.  相似文献   
53.
In 1996, after 150 years of relative calm, Turrialba Volcano was reawakening. A visible plume and serious damage to surrounding vegetation due to acid rain are the most obvious signals. As part of the Network for Observation of Volcanic and Atmospheric Change project, four gas-monitoring stations were initially installed on the west flank of the volcano with the purpose of measuring sulphur dioxide emissions during this period of increased activity using the scanning-differential optical absorption spectroscopy technique. We present here the results of semicontinuous gas flux measurements over a period of 5 years (from 2008 to 2012), providing a novel data set that documents a relatively rapid increase in SO2 fluxes from around 350 t day?1 to around 4,000 t day?1 leading up to an eruptive period, followed by a gradual return to the former baseline values. Gas flux data were also compared with seismic data for selected periods of interest, providing insights into the link between degassing and seismicity. The most important result from this comparison is the identification of an inflexion point in the gas emissions followed by a clearly increasing trend in seismic activity, distinguishable 6 months prior to a phreatic eruptive event that occurred on 5 January 2010. This signal can be interpreted as a possible indicator of future eruptive events. Monitoring of SO2 thus complements seismic monitoring as a forecasting tool for eruptive events. Such monitoring is critical considering the proximity of Turrialba to the Central Valley, an area inhabited by more than 50 % of Costa Rica’s population.  相似文献   
54.
Theoretical and Applied Climatology - The climate change endangers many species of the Amazon Forest. An example, in the endangered medicinal species Pilocarpus microphyllus (popularly known as...  相似文献   
55.
In the present study, activated carbons were prepared from sisal fiber (Agave sisalana sp.) and pomegranate peel (Punica granatum sp.) using phosphoric acid as the activating agent. Both sisal fiber activated carbon (SFAC) and pomegranate peel activated carbon (PPAC) were characterized using methylene blue number, iodine number, BET surface area, SEM, and FTIR. The BET surface area of the SFAC and PPAC were 885 and 686 m2/g, respectively. The adsorption studies using C.I. Reactive Orange 4 dye on the SFAC and PPAC were carried out. The effects of time, initial adsorbate concentration, pH, and temperature on the adsorption were studied. The isotherm studies were carried and it was found that the Langmuir and Freundlich isotherms fit well for the adsorption of RO 4 on SFAC, while adsorption of RO 4 on PPAC is better represented by the Langmuir and Temkin isotherms. Adsorption kinetics of adsorption was determined using pseudo first order, pseudo second order, Elovich and intraparticle diffusion models and it was found that the adsorption process follows pseudo second order model. Thermodynamics parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were determined by using van't Hoff equation. The positive ΔH value indicates that RO 4 dye adsorption on SFAC and PPAC is endothermic in nature.  相似文献   
56.
In this work Data Mining tools are used to develop new and innovative models for the estimation of the rock deformation modulus and the Rock Mass Rating (RMR). A database published by Chun et al. (Int J Rock Mech Min Sci 46:649–658, 2008) was used to develop these models. The parameters of the database were the depth, the weightings of the RMR system related to the uniaxial compressive strength, the rock quality designation, the joint spacing, the joint condition, the groundwater condition and the discontinuity orientation adjustment, the RMR and the deformation modulus. As a modelling tool the R program environment was used to apply these advanced techniques. Several algorithms were tested and analysed using different sets of input parameters. It was possible to develop new models to predict the rock deformation modulus and the RMR with improved accuracy and, additionally, allowed to have an insight of the importance of the different input parameters.  相似文献   
57.
58.
In scintillometry Monin–Obukhov similarity theory (MOST) is used to calculate the surface sensible heat flux from the structure parameter of temperature (CT2){(C_{T^2})} . In order to prevent saturation a scintillometer can be installed at an elevated level. However, in that case the observation level might be located outside the atmospheric surface layer (ASL) and thus the validity of MOST questioned. Therefore, we examine two concepts to determine the turbulent surface sensible heat flux from the structure parameter at elevated levels with data obtained at 60-m height on the Cabauw tower (the Netherlands). In the first concept (MOSTs) CT2{C_{T^2}} is still scaled with the surface flux, whereas in the second (MOSTl) CT2{C_{T^2}} is scaled with the local sensible heat flux. The CT2{C_{T^2}} obtained from both concepts is compared with direct observations of CT2{C_{T^2}} using a sonic anemometer/thermometer. In the afternoon (when the measurement height is located within the ASL) both concepts give results that are comparable to the directly observed values of CT2{C_{T^2}} . In the morning (data outside the ASL), our data do not unequivocally support either of the two concepts. First, the peak in CT2{C_{T^2}} that occurs when the measurement height is located in the entrainment zone disqualifies the use of MOST. Second, during the morning transition, local scaling shows the correct pattern (zero flux and a minimum in CT2{C_{T^2}}) but underestimates CT2{C_{T^2}} by a factor of ten. Third, from the best linear fit a we found that the slope of MOSTl gave better results, whereas the offset is closer to zero for MOSTs. Further, the correlation between the direct observations and MOST-scaled results is low and similar for the two concepts. In the end, we conclude that MOST is not applicable for the morning hours when the observation level is above the ASL.  相似文献   
59.

In the last decades, floods have increased in frequency all over the world due to diverse phenomena such as climate change, extended urbanization, land use, etc. Their social, cultural, economic and environmental impacts have also grown significantly, highlighting the need for the development of further studies and improved methods to manage and mitigate flood risk, mainly in urban areas. Historic sites need particular attention in this field, not only because the high and irreplaceable cultural value of these areas, but also taking into account that the constructive typologies that they host are particularly vulnerable to natural hazards. In consequence of that, the analysis of the phenomena, the evaluation of their consequences and the adoption of adequate mitigation and preparedness measures are presently a fundamental societal challenge. Having this in mind, the present paper aims at proposing an innovative methodology focused on the assessment of flood vulnerability in historic sites through the evaluation of a set of exposure and sensitivity indicators. From the analysis of these indicators, it is possible to obtain a Flood Vulnerability Index capable of measuring the spread of flood vulnerability over an extended area. The historic centre of Guimarães, in Portugal, declared by UNESCO as a World Heritage Site in 2001, is used here as a pilot case study to apply and discusses the preliminary version of the approach. Although some improvements are still needed, this approach can be already used to provides preliminary vulnerability scenarios and to point the way to the definition of more efficient and customized strategies for managing and mitigating flood risk in historic sites. Moreover, with further improvements and calibrations resorting to larger and more diverse data, it will be possible to reduce some of the uncertainties currently involved in the assessment process and to make its application wider and more robust.

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60.
The work considers critical slopes located at regions with high danger and proposes a method which approximately predicts the risk of earthquake-induced excessive movement of these slopes, in the case where relevant soil strength data along their slip surface do not exist. The method utilizes (1) simplified constitutive equations predicting soil response along slip surfaces and (2) a multi-block sliding system model, both recently proposed. It involves the following steps: (a) collect relevant topographic information and laboratory test results of past landslides at the region of interest, (b) (i) analyze the relevant laboratory tests to estimate the soil constitutive parameters and (ii) estimate the mobilized residual soil strength by back analysis of relevant past landslides, (c) select constitutive model parameters for future applications at the region based on step (b) and validate them based on analysis of the triggering of the past landslides and (d) apply the selected constitutive model parameters in critical slopes in the region under consideration to predict not only whether triggering occurs, but also the post-triggering slide deformation. The paper, after describing in detail the proposed method, applies it at the Wenchuan region, where the 12th May 2008 earthquake triggered many landslides. During the application, four ring shear test results and twelve landslides of the 12th May 2008 earthquake were considered. The application was successful and the following were observed: (i) in the back analyses, the multi-block model predicted reasonably well the final configuration of all slides, (ii) apart from two significantly larger back-estimated values of the residual soil strength, small scatter existed in the other back-estimated values and (iii) the selected model parameters were duly validated under step (c). Furthermore, as the back-estimated friction angle of most landslides was less than 18°, and the materials along the slip surface have a Liquid Limit value less than 25 %, it is inferred that some, or all of the slip surface during these slides, was sheared in an undrained manner.  相似文献   
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