Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation     

Y. Thomas He  Arthur G. Fitzmaurice  Azra Bilgin  Sunkyung Choi  Peggy O’Day  John Horst  James Harrington  H. James Reisinger  David R. Burris  Janet G. Hering 《Applied Geochemistry》2010

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.  相似文献   

Magnetic fields in methanol maser condensations based on data for related regions. Seven sources: Astrophysical parameters     

O. S. Bayandina  A. V. Alakoz  I. E. Val’tts 《Astronomy Reports》2014,58(7):462-470

The astrophysical parameters of seven OH maser condensations are estimated based on magnetic fields obtained from polarization observations carried out on the Nan cay Radio Telescope (France) in the 1665 and 1667 MHz lines in four Stokes parameters. Regions in the studied sources containing the observed clusters of maser condensations, as well as clusters of Class I and II methanol masers, have been identified. The associations of the masers are real; i.e., the magnetic field in the clusters can also extend to groups of methanol masers. The linear dimensions of these associations have been found. The ratio of the mass to the magnetic flux, ratio of the thermal to the magnetic pressure, and virial relationships between energies (kinetic, magnetic, and gravitational) in the regions containing the OH andmethanol masers have been obtained. In sources whose magnetic fields have been determined fairly reliably, the ratio of the mass to the magnetic flux exceeds a critical value, and the energies of chaotic motions and of the magnetic field are considerably smaller than the gravitational binding energy. On the other hand, in all cases, the ratio of the thermal to the magnetic pressure is <1, suggesting that the clouds may be in amagnetically dominated regime. This inconsistency is related to probable uncertainties in the the magnetic field values and the estimated distances to the sources, which may lead to overestimation of the sizes of the regions studied.  相似文献   

Low dispersive modeling of Rayleigh waves on partly staggered grids     

O. Rojas  B. Otero  J. E. Castillo  S. M. Day 《Computational Geosciences》2014,18(1):29-43

In elastic media, finite-difference (FD) implementations of free-surface (FS) boundary conditions on partly staggered grid (PSG) use the highly dispersive vacuum formulation (VPSG). The FS boundary is embedded into a “vacuum” grid layer (null Lame’s constants and negligible density values) where the discretized equations of motion allow computing surface displacements. We place a new set of compound (stress-displacement) nodes along a planar FS and use unilateral mimetic FD discretization of the zero-traction conditions for displacement computation (MPSG). At interior nodes, MPSG reduces to standard VPSG methods and applies fourth-order centered FD along cell diagonals for staggered differentiation combined with nodal second-order FD in time. We perform a dispersion analysis of these methods on a Lamb’s problem and estimate dispersion curves from the phase difference of windowed numerical Rayleigh pulses at two FS receivers. For a given grid sampling criterion (e.g., six or ten nodes per reference S wavelength λ ^S), MPSG dispersion errors are only a quarter of the VPSG method. We also quantify root-mean-square (RMS) misfits of numerical time series relative to analytical waveforms. MPSG RMS misfits barely exceed 10 % when nine nodes sample the minimum S wavelength $\lambda _{\text {MIN}}^{\mathrm {S}}$ in transit (along distances $\sim $ 145 $\lambda _{\text {MIN}}^{\mathrm {S}}$ ). In same tests, VPSG RMS misfits exceed 70 %. We additionally compare MPSG to a consistently fourth-order mimetic method designed on a standard staggered grid. The latter equates the former’s dispersion errors on grids twice denser and shows higher RMS precision only on grids with six or less nodes per $\lambda _{\text {MIN}}^{\mathrm {S}}$ .  相似文献   

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions     

Philippe Besson  Jefferson Degboe  Benjamin Berge  Valérie Chavagnac  Sébastien Fabre  Gilles Berger 《Geostandards and Geoanalytical Research》2014,38(3):355-362

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.  相似文献   

Contribution of climatic and anthropogenic effects to the hydric deficit of peatlands     

Chrystelle Auterives  Luc Aquilina  Olivier Bour  Mélanie Davranche  Valérie Paquereau 《水文研究》2011,25(18):2890-2906

The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay‐rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two‐year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 1·10^?7 to 3·10^?9 m.s^?1) and does not form a hydraulic barrier. Moreover, the vertical hydraulic gradients are downward between the peat and the sand aquifer, leading to high flows of groundwater through the clay layer (20–48% of the precipitation). The observed hydric deficit of the peatland results from a combination of dry climatic conditions during the study period and groundwater extraction. The climatic effect is mainly expressed through drying out of the peatland, while the anthropogenic effect leads to an enhancement of the climatic effect on a global scale, and a modification of fluxes at a local scale. The drying out of the peatland can lead to its mineralisation, which thus gives rise to environmental impacts. The protection of such wetlands in the context of climate change should take account of anthropogenic pressures by considering the wetland‐aquifer interaction. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Advancing process‐based watershed hydrological research using near‐surface geophysics: a vision for,and review of,electrical and magnetic geophysical methods     

D. A. Robinson  A. Binley  N. Crook  F. D. Day‐Lewis  T. P. A. Ferré  V. J. S. Grauch  R. Knight  M. Knoll  V. Lakshmi  R. Miller  J. Nyquist  L. Pellerin  K. Singha  L. Slater 《水文研究》2008,22(18):3604-3635

We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Storm waves in Canadian waters: A major marine hazard     

Madhav L. Khandekar  Val R. Swail 《大气与海洋》2013,51(2):329-357

Abstract

In this paper, an overview of storm waves associated with intense weather systems affecting the east and west coasts of Canada is presented. The paper presents the wave climatology of the east and west coasts in terms of the 100‐year significant and maximum wave heights and further analyses the directional distribution of wave heights at selected locations in the Canadian east and west coasts offshore. The paper also analyses wave hazards associated with storm waves in the Beaufort Sea as well as the Canadian Great Lakes region. A section on ocean wave modelling provides a brief history of the development of ocean surface wave models and its present status. The paper further considers the impact of climate change scenarios on wave hazards and finally examines mitigation measures in terms of wave products available from operational wave models and related wave climatology.  相似文献   

Evolution of the Parisian urban climate under a global changing climate     

Aude Lemonsu  Raphaëlle Kounkou-Arnaud  Julien Desplat  Jean-Luc Salagnac  Valéry Masson 《Climatic change》2013,116(3-4):679-692

The evolution of the Parisian urban climate under a changing climate is analyzed from long-term offline numerical integrations including a specific urban parameterization. This system is forced by meteorological conditions based on present-climate reanalyses (1970–2007), and climate projections (2071–2099) provided by global climate model simulations following two emission scenarios (A1B and A2). This study aims at quantifying the impact of climate change on air temperature within the city and in the surroundings. A systematic increase of 2-meter air temperature is found. In average according to the two scenarios, it reaches +?2.0/2.4°C in winter and +?3.5/5.0°C in summer for the minimum and maximum daily temperatures, respectively. During summer, the warming trend is more pronounced in the surrounding countryside than in Paris and suburbs due to the soil dryness. As a result, a substantial decrease of the strong urban heat islands is noted at nighttime, and numerous events with negative urban heat islands appear at daytime. Finally, a 30% decrease of the heating degree days is quantified in winter between present and future climates. Inversely, the summertime cooling degree days significantly increase in future climate whereas they are negligible in present climate. However, in terms of accumulated degree days, the increase of the demand in cooling remains smaller than the decrease of the demand in heating.  相似文献   

Impact of justice and solidarity variables on the acceptability of managed realignment     

Bénédicte Rulleau  Hélène Rey-Valette  Valérie Clément 《Climate Policy》2013,13(3):361-377

Sea-level rise due to climate change will have significant effects on coastal areas and populations. Adaptation policies recommend the managed realignment of the most vulnerable assets and activities. Despite their medium- and long-term benefits, these policies face significant friction due to social acceptability in the communities where they are implemented.

This article investigates the hypothesis that respecting principles of justice in the implementation of managed realignment should increase its acceptability. We compare preferences of those people who are exposed to the risk of climate-change-induced flooding and those who are not, as regards funding managed retreat policies and defining compensation criteria for assets at risk. The main theories of social justice provide the four principles included in the analysis: efficiency, need, responsibility and priority assigned to property rights.

A choice experiment survey was conducted with 258 residents of coastal and hinterland communities in the south of France. Four attributes were selected to define the managed realignment policy: the dialogue arrangements, the implementation period, the policy implementation schedule and the cost. The results show support for a relatively fast launch of these policies (within 15 years) but in stages and through a process of dialogue with the population. People's perceptions of the funding criteria reveal a preference for national solidarity. Finally, national funding of managed retreat policies and compensation criteria based on market prices have a significant positive influence on the acceptability of managed realignment policies, whereas introducing responsibility-based compensation criteria tends to favour the status quo over the adaptation policy.

Policy relevance

Prioritization of the funding criteria reveals the preference for national solidarity. Preferences for the justice criteria underpinning compensation reveal a great diversity of values. Besides implantation modalities, preferences for managed realignment policies depend on which level they are implemented at, on the expropriation criteria (the emphasis given to property rights, i.e. market price), on the attachment (people perceived as worst off, i.e. the property is their main residence rather than a second home or they have lower levels of income) and on the degree of responsibility (related to the date of purchase, i.e. on the information given at the time on the risk).  相似文献   

Deep events in U.K. South Western Approaches     

R.R. Hillis  G.A. Day 《Geophysical Journal International》1987,89(1):243-250

Summary. Apparently planar dipping events are observed in seismic data off south-west Britain within otherwise essentially transparent upper and middle crust. These are believed to represent Variscan thrusts, some of which were re-activated during the post-Carboniferous phase of extension that affected the southern U.K. They can be seen in two extensive commercial seismic surveys recorded to 6 s two-way-time (TWT) and, where laterally persistent, they have been mapped to reveal their essentially planar nature. Commonly these dipping events are associated with deeper, near-horizontal, or gently convex upwards events with which they often appear to converge. Where 'real', these are thought to indicate a complex fault system or possibly the top of the reflective lower crust. The thrusts are seen over the whole area except where granite is known to occur, and commonly exert a major control on the position and subsequent deformation of overlying sedimentary basins.  相似文献