Oxidation inhibitors occuring in bioproducers, recent sediments, ancient rocks and oils     

Valentina N. Burkova  Svetlana I. Pisareva 《Organic Geochemistry》1990,16(4-6)

Native antioxidants (AO) are involved in the transformation of organic matter (OM) in different stages of diagenesis. In the early stages, the geochemical significance of AO can be estimated by using AO consumption index (I). The positive I values suggest that the OM fossilization proceeded under reducing conditions which favoured the formation of oil-source rocks, while the negative I values indicate oxidizing conditions which are characterized by the formation of rocks having a low oil-generation potential. In the late stages of diagenesis, the AO content is indicative of the degree of catagenic (thermal) or biodegradation (oxidative) transformation of oils. The AO contents of Paleogenic, Mesozoic and Paleozoic oils have been found to differ approximately by one order of magnitude. A major portion of AO is concentrated in oil resins and asphaltenes. The ratio of AO to resins and asphaltenes can be used as criterion of catagenic transformation of OM.  相似文献   

Assessment of visual impact induced by surface mining with reference to a case study located in Sardinia (Italy)     

Valentina Dentoni  Giorgio Massacci 《Environmental Earth Sciences》2013,68(5):1485-1493

Surface mining and quarrying typically generate a considerable number of environmental impacts among which landscape alteration remains one of the most significant. Although landscape alteration does not directly affect public health, it may produce an adverse reaction among potential observers and compromise the use and potential growth of the surrounding territory. In order to assess the impact produced by surface excavation, some aspects of landscape modification can be objectively measured, such as the extent of the visible alteration, its shape and the chromatic contrast with the surroundings. With reference to a case study located in Sardinia, this article discusses the implementation of two different visual impact assessment methods, one defined by the EC decision 272/02 (Commission Decision 2002), the other previously proposed by the authors of the present article and based on the estimation of the impact indicator Lvi (level of visual impact). The comparison of the results proves that the method established by the EC decision leads to the underestimation of the visual impact for alterations which are significantly wider than their height. On the other hand, the implementation of the Lvi method clearly shows how the indicator is affected by the quarry’s lateral extent and suggests the possibility of calculating a global impact factor LVI to be associated to a given route, considering the variability of the visual impact with the curvilinear abscissa of the route itself.  相似文献   

Energy spectra of particles accelerated in a reconnecting current sheet with the guiding magnetic field     

Valentina V. Zharkova  Mykola Gordovskyy 《Monthly notices of the Royal Astronomical Society》2005,356(3):1107-1116

Electron and proton acceleration by a super-Dreicer electric field is investigated in the non-neutral reconnecting current sheet (RCS) with a non-zero longitudinal component of the magnetic field ('guiding field'). The guiding field is assumed parallel to the direction of electric field and constant within an RCS. The other two magnetic field components, transverse and tangential, are considered to vary with distances from the X null point of an RCS. The proton and electron energy spectra are calculated numerically from a motion equation using the test particle approach for model RCSs with constant and variable densities. In the presence of a strong or moderate guiding field, protons were found fully or partially separated from electrons at ejection from an RCS into the opposite, 'electron' and 'proton', semiplanes. In the case of a weak guiding field, both protons and electrons are ejected symmetrically in equal proportions as neutral beams. The particles ejected from an RCS with a very weak or very strong guiding field have power-law energy spectra with spectral indices of about 1.5 for protons and 2.0 for electrons. For a moderate guiding field, the energy spectra of electrons ejected into the opposite semiplanes are mixed, i.e. in the 'electron-dominated' semiplane power-law energy spectra for electrons and thermal-like for protons, while in the 'proton' semiplane they are symmetrically mirrored.  相似文献   

The role of tidal,wave and river currents in the evolution of mixed‐energy deltas: Example from the Lajas Formation (Argentina)          下载免费PDF全文

Valentina Marzia Rossi  Ronald J. Steel 《Sedimentology》2016,63(4):824-864

Many modern deltas show complex morphologies and architectures related to the interplay of river, wave and tidal currents. However, methods for extracting the signature of the individual processes from the stratigraphic architecture are poorly developed. Through an analysis of facies, palaeocurrents and stratigraphic stacking patterns in the Jurassic Lajas Formation, this paper: (i) separates the signals of wave, tide and river currents; (ii) illustrates the result of strong tidal reworking in the distal reaches of deltaic systems; and (iii) discusses the implications of this reworking for the evolution of mixed‐energy systems and their reservoir heterogeneities. The Lajas Formation, a sand‐rich, shallow‐marine, mixed‐energy deltaic system in the Neuquén Basin of Argentina, previously defined as a tide‐dominated system, presents an exceptional example of process variability at different scales. Tidal signals are predominantly located in the delta front, the subaqueous platform and the distributary channel deposits. Tidal currents vigorously reworked the delta front during transgressions, producing intensely cross‐stratified, sheet‐like, sandstone units. In the subaqueous platform, described for the first time in an ancient outcrop example, the tidal reworking was confined within subtidal channels. The intensive tidal reworking in the distal reaches of the regressive delta front could not have been predicted from knowledge of the coeval proximal reaches of the regressive delta front. The wave signals occur mainly in the shelf or shoreface deposits. The fluvial signals increase in abundance proximally but are always mixed with the other processes. The Lajas system is an unusual clean‐water (i.e. very little mud is present in the system), sand‐rich deltaic system, very different from the majority of mud‐rich, modern tide‐influenced examples. The sand‐rich character is a combination of source proximity, syndepositional tectonic activity and strong tidal‐current reworking, which produced amalgamated sandstone bodies in the delta‐front area, and a final stratigraphic record very different from the simple coarsening‐upward trends of river‐dominated and wave‐dominated delta fronts.  相似文献   

The geographics of patients transfers: the case of an Italian Regional Health System     

Valentina Evangelista 《GeoJournal》2016,81(5):771-778

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Geophysical investigation of the Sandalp rock avalanche deposits     

Laura Valentina Socco  Denis Jongmans  Daniele Boiero  Stefano Stocco  Margherita Maraschini  Ken Tokeshi  Didier Hantz 《Journal of Applied Geophysics》2010,70(4):277-291

In the study of rock avalanche phenomena, numerical modelling makes use of back analyses of the rock avalanche propagation for calibration of the modelling assumptions and parameters. The back analyses require knowledge of the run-out area boundaries and the thickness distribution of the deposit. Geophysical methods can be applied to retrieve the thickness distribution, but, due to strong heterogeneities and logistic problems they are seldom applied. The aim of this work is to assess the potential of integrated geophysical methods to recognise and characterise a deposit created by two rock avalanches which occurred in the Sandalp valley (Switzerland) in 1996. The topography of the site before and after the rock avalanche is known and can be used as a benchmark. Resistivity tomography, seismic P-wave tomography, and active and passive surface wave analysis have been applied on several profiles deployed both on the rock avalanche deposit and in the surrounding area. Innovative approaches for surface wave analysis based on laterally constrained inversion and multimodal inversion have been applied to the data. A comparison of the results of the geophysical investigations with the topographic benchmark has shown the capability of the geophysical methods to locate the bottom of the deposit in the areas where the contrast with the host sediments properties is significant. In these areas, the deposit has higher resistivities and lower seismic velocities than the underlying materials. In the areas where the deposit is thicker and richer in fine-grained materials the geophysical parameters are not able to discriminate between the rock avalanche deposit and the underlying sediments. As a secondary task, the geophysical methods also allowed the bedrock pattern to be outlined.  相似文献   

Assessing the ecological status of the North-western Adriatic Sea within the European Water Framework Directive: a comparison of Bentix, AMBI and M-AMBI methods     

Roberto Simonini  Valentina Grandi  Gloria Massamba-N'Siala  Mirko Iotti  Giuseppe Montanari  & Daniela Prevedelli 《Marine Ecology》2009,30(2):241-254

In this paper we looked for the most suitable method for benthic ecological quality status (EcoQS) assessment of the North-western Adriatic Sea. Taking into account the historical and present information, we inter-compared our expectations in terms of EcoQS, with the Bentix, AMBI and M-AMBI classification metrics results, and investigated the sensitivity of these indices to the spatial, seasonal and inter-annual variability of benthic communities. The sampling sites were located at increasing distances with respect to the Po River mouth, along an (inverse) gradient of eutrophication. Moreover, a 2-year monthly monitoring plan (October 2004–September 2006) was carried out at the CEBEB site, located in a central position with respect to the investigated area. The results highlighted that the three indices differed in the sensitivity to spatial and temporal variability of the benthic communities. The strong seasonal and inter-annual changes in the benthic communities had a significant effect on the Bentix, whereas no relevant modifications were observed on the EcoQS assignation obtained using the M-AMBI and AMBI methods. The environmental quality ratios (EQR) values and EcoQS classification obtained by the Bentix and AMBI did not match expectations, as they were not inversely correlated with the site distances with respect to the Po mouth, whereas the M-AMBI clearly discriminated the most and the least eutrophicated sites. It thus appears that the M-AMBI could be considered to be the most valuable method for the ecological-status assessment of the North-western Adriatic Sea benthic ecosystem.  相似文献   

Responses of a Northern Adriatic Ampelisca-Corbula community to seasonality and short-term hydrological changes in the Po river     

N'siala GM  Grandi V  Iotti M  Montanari G  Prevedelli D  Simonini R 《Marine environmental research》2008,66(4):466-476

During the 20th century, increased nutrient inflow has increased the frequency and intensity of eutrophication events in the North-western Adriatic Sea. More recently, evidence of a reduction in the Po river flow and a recovery of the benthic environment were reported. We examined the role played by Po river regime and seasonality in determining the temporal pattern of macrozoobenthos variation: samples were collected from a site located 10-12km off Cesenatico during two years from October 2004 to September 2006, when the mean Po discharge remained exceptionally low. 88 taxa were found, and the community was dominated by few species: Ampelisca diadema, Lumbrineris latreillii, Corbula gibba, Aricidea claudiae, Levinsenia gracilis and Nucula nucleus account for about 80% of total abundances. The density of these species exhibited a marked seasonal variability. Moreover, the total abundance and the density of the sensitive species, A. diadema, were negatively affected by several disturbance events (hypoxic conditions, frequent storms and an anomalous winter flood) that occurred between November 2005 and March 2006. The reduction of C. gibba and the increase of A. diadema densities observed in the investigated period, and verified recently by other authors could be related to the reduction in river inputs as a consequence of climatic changes.  相似文献   

Organic waste impact of capture-based Atlantic bluefin tuna aquaculture at an exposed site in the Mediterranean Sea     

Luigi Vezzulli  Mariapaola Moreno  Valentina Marin  Elisabetta Pezzati  Marco Bartoli  Mauro Fabiano 《Estuarine, Coastal and Shelf Science》2008

A variety of pelagic and benthic parameters were measured at an aquaculture farm used for the fattening of Atlantic bluefin tuna (Thunnus thynnus) which is located at an exposed site (700 m from the coast, average bottom depth of 45 m and average current speed of 6 cm s⁻¹) in the Mediterranean Sea. The objective was to test whether modern off-shore tuna fattening industries can exert a sustainable organic waste impact on the receiving environment as has been reported for the offshore culture of more traditional Mediterranean species such as sparids. In the water column, the concentration of phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of mesozooplankton (at the species level) were assessed. In the sediment, we assessed the concentration of reduced sulphur pools, phytopigments, organic matter, heterotrophic bacteria and the taxonomic abundance of meiofauna (at the taxa level) and nematodes (at the genus level). For most parameters, we found no substantial differences between farm and control sites. Deviations of farm values from control values, when they occurred, were small and did not indicate any significant impact on either the pelagic and benthic environment. Deviations were more apparent in the benthic compartment where lower redox potential values, higher bacterial production rates and a change in nematode genus composition pointed out to early changes in the sediment's metabolism. In addition, indigenous potential pathogenic bacteria showed higher concentration at the fish farm stations and were a warning of an undesirable event that may become established following aquaculture practice in oligotrophic environments. The overall data from this study provide extensive experimental evidence to support the sustainability of modern offshore farming technology in minimizing the hypertrophic-dystrophic risks associated with the rapidly-expanding tuna-fattening industry in the Mediterranean Sea.  相似文献   

A piecewise curve-fitting technique for vertical oceanographic profiles and its application to density distribution     

Viacheslav G. Makarov  Oleg V. Zaytsev  Valentina D. Budaeva  Felipe Salinas-Gonzalez 《Journal of Oceanography》2008,64(5):675-690

A unified method of approximation, extrapolation, and objective layering is offered for processing vertical oceanographic profiles. The method is demonstrated using seawater density and consists of adjustable splitting of each individual profile into N vertical layers based on tentative, piecewise linear homogeneous approximation with specified accuracy and a final fitting of an N-layered analytical model to data. A set of 3N coefficients of the model includes one density value at the sea surface; N−1 depths of layer interfaces; and N pairs of coefficients that describe a profile shape within the n-th layer—an asymptotic density value (a key parameter for extrapolation) and a vertical scale of maximum density variability (related to vertical gradient). Several distinctive characteristics of the technique are: (1) It can be used for the analysis of the vertical structure of individual profiles when N is an unknown parameter, and spatial interpolation when N should be equal for all profiles. (2) A justified downward extrapolation of incomplete data is possible with the model, especially if historical deepwater profiles are available. (3) Layer interfaces, as well as other coefficients, are derived with only one fitting to the entire profile. (4) The technique, using its general formulation, can serve as a parent for developing various types of models. The simpler step-like (with hyperbolic or exponential approximation) and more complicated smooth (continuous in gradient space) models were designed and tested against a large number of density profiles from the Sea of Okhotsk and the Gulf of California. Comparison of parametric, z-levels and isopycnal averaging was done for the region off the northeastern coast of Sakhalin.  相似文献