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71.
This study determined the concentrations of major and trace elements in shellfish (oysters, clams and mussels) and conducted an assessment of the health risks due to the consumption of contaminated seafood. Samples were collected at 34 sites along Todos os Santos Bay, Brazil. The elements were determined by ICP OES and Hg by Direct Mercury Analysis. Relatively high concentrations of trace elements (As, Zn, Se and Cu) were found in seafood tissues. Potential daily intake of As, Co, Se, Zn and Cu associated to shellfish consumption suggested relevant non-carcinogenic risk for all studied locations. Copper was the element that posed the greatest non-carcinogenic risk, while Pb posed the highest carcinogenic risk. Health risks for humans were greatest from the consumption of mussels. Contaminated shellfish offer the greatest risk for children, subsistence fishers and subsistence shellfish consumers.  相似文献   
72.
A comprehensive 32 kHz multibeam bathymetry and backscatter survey of Cook Strait, New Zealand (∼8500 km2), is used to generate a regional substrate classification map over a wide range of water depths, seafloor substrates and geological landforms using an automated mapping method based on the textural image analysis of backscatter data. Full processing of the backscatter is required in order to obtain an image with a strongly attenuated specular reflection. Image segmentation of the merged backscatter and bathymetry layers is constrained using shape, compactness, and texture measures. The number of classes and their spatial distribution are statistically identified by employing an unsupervised fuzzy-c-means (FCM) clustering algorithm to sediment samples, independent of the backscatter data. Classification is achieved from the overlay of the FCM result onto a segmented image and attributing segments with the FCM class. Four classes are identified and uncertainty in class attribution is quantified by a confusion index layer. Validation of the classification map is done by comparing the results with the sediment and structural maps. Backscatter (BS) strength angular profiles are used to show acoustic class separation. The method takes us one step further in combining multibeam data with physical seabed data in a complementary analysis to seek correlations between datasets using object-based image analysis and unsupervised classification. Texture within these identified classes is then examined for correlation with typical backscatter angular responses for mud, sand and gravel. The results show a first order correlation between each of the classes and both the sedimentary properties and the geomorphological map.  相似文献   
73.
The Witputs section of the Gariep Belt (S Namibia) comprises a sequence of clastic and chemical sediments, which have been interpreted as representative of a Late Neoproterozoic global or near-global ice age event, and recent biostratigraphic work in the upper rocks of the Witputs suggest a Late Ediacaran age. To further characterise this sequence and provide additional age constraints, a detailed sedimentological and detrital zircon study has been carried out. The petrographic, sedimentological and geochemical characteristics of the Witputs diamictite determined in this study are homogenous and indicative of debris flow or palaeo-valley infill sediments, deposited in an oxic environment with no glaciogenic evidence. This homogeneity is also reflected in the detrital zircon age spectra with most ages falling between 1.0 and 1.3?Ga, representing the local geology, with the youngest grain at 1030.2?±?10.9 (2??) (n?=?92?<10% discordance), despite the fact that mid and Late Neoproterozoic volcanic activity is known in the local region. The overlying carbonate rocks, often considered to be ??cap carbonates??, show high Mn (up to 60% MnO), with base metal precipitation (Zn, V, Co), and are recrystallised. Their ??13CVPDB isotope ratios are homogeneous at around-3. Major and trace element ratios reach values which indicate that C?CO isotopes may be disturbed and might not reflect primary global seawater composition, thus questioning their use for global correlation and comparison with composite chemostratigraphic curves. The contact to the overlying Late Ediacaran Sanddrif Member is not exposed, and the rocks dip in a different direction than the underlying carbonate rocks. The c. 40-m-thick section is characterised by rapid lithology changes including shales, calcareous sandstones and wackes, fine-grained conglomerates and rare clean quartz-rich sandstones, all of which have strikingly similar detrital zircon populations, and the youngest zircon is dated at 1082.8?±?10?Ma (2?? errors, from 72 grains with <10% discordance). Acritarchs earlier found in the Sanddrif Member, however, indicate a post-570?Ma depositional age. If the diamictites are glacio-marine deposits, then an interesting conclusion is that the clastic sediments can display a very immature geochemical signature, indicating a localised provenance, with derivation purely from the local basement rocks, which is also reflected in the detrital zircon populations. However, we would hesitate to assign a glacial origin to the deposits as no glacial indicators, other than a diamictitic texture, were observed. Clearly, far more work on the detailed mapping and sedimentology of the Neoproterozoic Gariep Belt deposits is required, particularly as many are currently used for global correlation. Age constraints derived from extensive detrital zircon work can only constrain the deposits as being post 1.03?Ma with the detritus being purely locally derived.  相似文献   
74.
Continuous heavy rainfall hit northern Peru in the second half of the 2008/2009 summer season. From the end of January to the beginning of March, the Cordillera Huayhuash experienced abnormally high precipitations that exceeded 270?mm. The antecedent rainfall, aggravated with a severe rainstorm of 20?mm on March 7 triggered a large debris flow in the upper Carhuacocha Valley early in the morning on March 8. The debris flow interrupted drainage from the upper part of the valley damming a lake in the narrow depression between the trough slope and the lateral moraine. As a result of the drainage interruption, water percolated through the moraine dam of Cangrajanca Lake where a secondary mass movement occurred in its inner slope. In September 2009, we mapped the debris flow and related landforms and estimated the total area and volume of both mass movements using geodetic measurements. About 104,000?m3 of sediments was moved from the trough slope towards the moraine from which 534,000?m3 flowed to Cangrajanca Lake subsequently. We analysed the rainfall conditions that triggered the debris flow using rainfall data from the nearby stations. We also compared the precipitation preceding the event with the rainfall thresholds for debris flow initiation.  相似文献   
75.
Data from a mineral deposit are commonly obtained by core drilling. This kind of sampling involves high costs, limiting the number of drill holes. Additional holes should be located to bring the maximum benefit. The benefit can be evaluated by various ways and must take into account the goals of sampling. This article presents a case study where the deposit has been sampled and the new drillings must be added to reduce the uncertainty about a transfer function, Net Present Value (NPV) of the mining project. There are basically two ways to choose locations where new drillings should be placed for cases where the aim of sampling is to reduce uncertainty about a global function: the addition of new drillings outlining a quasi regular grid with previously collected drillings or the addition of new drillings on the locations of high uncertainty about the attribute of interest (or the attribute that is considered most influential in the transfer function). The performances of these patterns on reducing the uncertainty measured by the function selected are compared. The results point out that the most efficient pattern relates to the distribution (histogram) of the uncertainty about the attribute of interest. Thus, the choice of which sampling pattern should be adopted varies depending on data distribution and its influence on the transfer function.  相似文献   
76.
77.
Studies focusing on the effect of invasive species on the genetic diversity of native marine invertebrates remain scant. Here we report diversity among French populations of the intertidal gastropod Ocenebra erinacea (Linnaeus, 1758) sampled in the presence and absence of the invasive Ocenebra inornata (Recluz, 1851). Between 1999 and 2004, a total of 352 individuals of O. erinacea was collected from 15 sites (five of which had the invasive present) and was genotyped at the mitochondrial locus Cytochrome Oxidase 1 (cox1). No statistical difference was observed between polymorphism levels recorded within native populations exposed to the invasive, compared with populations sampled in the absence of O. inornata. No sign of native population decline was detected in response to the invader. While significant shifts in native O. erinacea population sizes have previously been reported in the literature, genetic effects may take longer to accumulate, or may be undetectable without a larger panel of genetic markers. By contrast, large genetic distances and significant population differentiation were recorded between Atlantic and Mediterranean O. erinacea samples, suggesting that these populations have distinct evolutionary histories. Comparison of genetic divergence within the closely related genus Nucella suggests that the Atlantic populations of O. erinacea and those from Thau Lagoon in the Mediterranean may belong to different species or subspecies.  相似文献   
78.
With increasing interest in climate change and other issues associated with the history of the environment and anthropogenic evolution there is an ongoing requirement to investigate the Earth's natural systems. A key approach is for scientists to look back into geological time, perhaps millions of years, to see how the world has reacted to natural climatic changes in the past. Using evidence from the fossil record, fluctuations in palaeoclimate can be assessed with reference to changes in global floral and faunal patterns. Phytoliths, Greek for 'plant stones', is a fossil group that is being increasingly utilized in the understanding of past climates and environments.  相似文献   
79.
The structure of the benthic macrofaunal assemblages of the estuarine portion of Paraguaçu River, NE, Brazil, and its relationship with surface sediment characteristics (trace metals, PAHs, nutrients and grain size) and physical variables were investigated at ten stations on two contrasting occasions, summer (dry season) and winter (rainy season). A total of 1258 individuals (632 in winter and 626 in summer) and 62 taxa representing polychaetes, crustaceans, bivalves, echinoderms, bryozoans, sponges, cnidarians and cephalochordates were collected. Benthic assemblages in the upper estuary were unlike those in the lower estuary and a clear substitution of benthic taxa along the estuary was observed. Macrofaunal invertebrates in the low salinity region, composed of coarse sediments, were dominated by tellinids, venerids (bivalves), cirolanids (isopods), cyclopoids (copepods), and nereidids (polychaetes). While the high salinity region, composed of fine sediments, were dominated by nuculids (bivalves), cirratulids (polychaetes), and by amphiurids (ophiuroids). The Paraguaçu estuarine system is not severely affected by anthropogenic activities. In the great majority of the study sites, concentrations of trace metals and PAHs in the sediments were near background values. Nutrients values were also low. We formulated new models of taxon distribution and suggested detailed studies on the effects of salinity variation and studies using functional approaches to better understand the processes causing the spatial patterns in tropical estuarine benthic assemblages.  相似文献   
80.
The Fundamentals of Radionuclide Migration (FUNMIG) project was organised in some Research and Technological Development Components (RTDCs) integrated by a number of Work Packages (WP’s) attempting to cover the key migration processes at different scales (laboratory to repository) and in different geological media, mainly clay and granite, but also some salt rock related work was performed. The main RTDCs of interest for this review paper are numbers 1 and 2, which concerned laboratory studies of well-established and less-established migration processes. Some additional interesting outcomes arise also from RTDCs 3, 4 and 5 devoted to the upscaling and applicability of migration processes to clay, granite and salt rock environments, respectively. This review discusses the contribution of the various parts of the FUNMIG project in the process oriented context of understanding the mechanistic approximation to what can be seen as the final and thermodynamically stable stage of the long chain of processes which are covered under the general term of sorption and that culminate in the formation of solid solutions.  相似文献   
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