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21.
Sulfur isotope compositions of pumice and adsorbed volatiles on ash from the first historical eruption of Anatahan volcano (Mariana arc) are presented in order to constrain the sources of sulfur erupted during the period 10-21 May, 2003. The isotopic composition of S extracted from erupted pumice has a narrow range, from δ34SV-CDT +2.6‰ to +3.2‰, while the composition of sulfur adsorbed onto ash has a larger range (+2.8‰ to +5.3‰). Fractionation modeling for closed and open system scenarios suggests that degassing of SO2 raised the δ34SV-CDT value of S dissolved in the melt from an initial composition of between +1.6‰ and +2.6‰ for closed-system degassing, or between −0.5‰ and +1.5‰ for open-system degassing, however closed-system degassing is the preferred model. The calculated values for the initial composition of the magma represent a MORB-like (δ34SV-CDT ∼ 0‰) mantle source with limited contamination by subducted seawater sulfate (δ34SV-CDT +21‰). Modeling also suggests that the δ34SV-CDT value of SO2 gas in closed-system equilibrium with the degassed magma was between +0.9‰ and +2.5‰. The δ34SV-CDT value of sulfate adsorbed onto ash in the eruption plume (+2.8‰ to +5.1‰) is consistent with sulfate formation by oxidation of magmatic SO2 in the eruption column. The sulfur isotope composition of sulfate adsorbed to ash changes from lower δ34S values for ash erupted early in the eruption to higher δ34S values for ash erupted later in the eruption. We interpret the temporal/stratigraphic change in sulfate isotopic composition to primarily reflect a change in the isotopic composition of magmatic SO2 released from the progressively degassing magma and is attributed to the expulsion of an accumulated gas phase at the beginning of the eruption. More efficient oxidation of magmatic SO2 gas to sulfate in the early water-rich eruption plume probably contributed to the change in S isotope compositions observed in the ash leachates.  相似文献   
22.
Mean daily streamflow records from 44 river basins in Romania with an undisturbed runoff regime have been analyzed for trends with the nonparametric Mann‐Kendall test for two periods of study: 1961–2009 (25 stations) and 1975–2009 (44 stations). The statistical significance of trends was tested for each station on an annual and seasonal basis, for different streamflow quantiles. In order to account for the presence of serial correlation that might lead to an erroneous rejection of the null hypothesis, a trend‐free prewhitening was applied to the original data series. The regional field significance of trends is tested by a bootstrap procedure. Changes in the streamflow regime in Romania are demonstrated. The main identified trends are an increase in winter and autumn streamflow since 1961 and a decrease in summer flow since 1975. The streamflow trends are well explained by recent changes in temperature and precipitation that occurred in the last 50 years. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
23.
Viorel Ilinca 《Landslides》2014,11(3):505-512
This paper focuses on characteristics of debris flows from the lower part of the Lotru River basin (South Carpathians, Romania). The damage produced by these debris flows has included burial of agricultural land, roads covered by debris flows, and even the obstruction of the Lotru River. Simple statistical analysis has been used to emphasize the characteristics of the debris flow sites. The collected data show that heavy rainfall is the main triggering mechanism of debris flow events in the Lotru hydrographic basin. The daily rainfall data for this region show that important debris flow events generally occur when rainfall exceeds 40 mm in 24 h, while rainfall levels between 25 and 40 mm in 24 h result in hyperconcentrated flows. For 11 of 14 studied debris flow sites, the fan area is greater than the source area, probably due to the thickness of the regolith, which is up to 5–10 m deep. Both source area and deposition area are very dynamic. The retreat rate calculated for five debris flow sites ranges from 5 to 30 m in 30 years (from 1975 to 2005). Channel cross section measurements on one of the debris flows show that velocity values vary from 1.31 to 2.64 m/s; corresponding discharge values vary from 4 to 10.03 m3/s.  相似文献   
24.
Abstract

The Northern part of Great-India underwent an early rifting phase in the late Paleozoic, just at the end of the large scale Gondwanian glaciation. The beginning of the rifting processes is marked by large hiatus and discontinuities (para- conformities) between the early or middle Paleozoic sedimentary succession and the discontinuous middle-late Permian Traps and transgressive sediments. The Northern Indian passive margin consists of the present High and Lower Himalaya and a small part of the Indian craton and their sedimentary cover. The Permian rift shoulder is located in the Higher Himalaya, with part being in the underthrusted Lower Himalaya. The rim basin (landward of the shoulder) is well developed in the Pottawar- Salt Range area. From the rifting to the beginning of the drifting stages (early late Permian to late early Triassic time), the sedimentary evolution is characterised by three transgressive- regressive (T-R) second order cycles, two in the late Permian and one in the early Triassic. The break-up of the rift occurred during the second cycle (late Dzhulfian).

In the Salt Range area, these three T-R cycles have been subdivided in eight third order sequences, five sequences for the upper Permian and three for the lower Triassic.

At the end of Permian, hiatuses, gaps and local erosion of part of the margin are direct consequences of a first order relative sea-level fall; this is also the time of the largest extinction event of the Phanerozoic that deeply affected the carbonate productivity and the stratal patterns. With the following worldwide sea-level rise, a rapid and large scale transgression occurred in the early Triassic, well dated and recorded on the whole margin. High rate thermal subsidence gave way to generalized pelagic deposits about 2 My after the transgression.

Profiles of whole rock inorganic carbon and oxygen isotopes from Guryul Ravine and Palgham sections in Kashmir, Nammal Gorge and Landu sections in Trans Indus Ranges (Pakistan), Thini Chu section in Kali Gandaki Valley, Central Nepal are presented in connection with the sequence stratigraphic analysis. The upper Permian record of high positive δ13C values are closely correlated with the second order T-R cycles and the third order sequences. The results presented in this study confirm the drastic drop of δ13C from the high positive values that characterised the upper Permian to lower values in the lower Triassic time. Stratigraphic correlation problems in the lower Triassic using carbon isotope geochemistry are briefly discussed. A positive δ13C excursion of 4–5% near the Smithian - Spathian substages boundary is observed for the first time. The δ18O values of samples from all the sections display major variations suggesting that the oxygen isotope record has been significantly affected by meteoric diagenesis, deep burial diagenesis or/and monsoon signature.  相似文献   
25.
Oxygen and hydrogen isotope analyses were made of Jurassic-age chert nodules from the Holy Cross Mountains, SE Poland, along radial transects at high spatial resolution. There is a radial “sigmoidal” periodicity for both isotope ratios, but the two are out of phase, with high δD values corresponding to low δ18O values. Periodicity for a 100- to 120-mm diameter nodule is approximately 16 mm, increasing slightly toward the rim, with amplitudes approaching 20 and 3.0‰ for hydrogen and oxygen, respectively. The combined hydrogen-oxygen isotope data for one nodule fall on a published curve for chert forming in equilibrium with seawater (Knauth and Epstein, 1976); the range of delta values corresponds to temperature variations of ∼10°C. Data for a second chert fall on a subparallel δD-δ18O line with δD values that are almost 50‰ lower. The δD-δ18O patterns for the nodules cannot be explained by periodic mixing of meteoric and ocean water because the hydrogen and oxygen isotope data are out of phase. Two possible explanations for the antiphase periodicity are (a) cyclical temperature variations, perhaps related to an unstable convection system (e.g., Bolton et al., 1999), and (b) self-organizing catalytic precipitation (e.g., Wang and Merino, 1990). The systematic isotopic variations are difficult to explain by diagenesis and strongly suggest that primary isotopic compositions are preserved. The isotopic data provide important information on the thermal history of the sedimentary basin, if temperature variations are the cause of the isotopic periodicity.  相似文献   
26.
Theoretical and Applied Climatology - This study presents evaluation of the ability of Rossby Centre Regional Climate Model (RCA4) driven by nine global circulation models (GCMs), to skilfully...  相似文献   
27.
Theoretical and Applied Climatology - The Ångström–Prescott equation defines generically the relationship between solar energy available at ground level and sunshine duration. From...  相似文献   
28.
29.
This paper proposes a new approach for forecasting continuous indoor air quality time series and in particular the concentration of a common air pollutant in offices like formaldehyde. Forecasting is achieved through the combination of the spectral band decomposition using fast Fourier transform and nonlinear time series modeling. Two nonlinear models have been tested: a threshold autoregressive (TAR) model and a Chaos dynamics-based modeling. This study shows the benefit of the Fourier decomposition coupled with nonlinear modeling of each extracted component, compared to forecasting applied directly on the raw data. Both TAR and Chaos dynamics models are able to reproduce nonlinearities, with slightly better performance in the case of the second model. These hybrid models provide good performance on forecast time horizon up to 12 h ahead.  相似文献   
30.
Sub-brown dwarfs (SBD) might originate either around a star or in solitary fashion. These bodies can retain atmospheres composed of molecular gases, which, upon cooling, have basal pressures of tens of bars or more. Pressure-induced opacity of these gases prevents such a body from eliminating its internal radioactive heat and its surface temperature can exceed the melting point of the life-supporting solvent for an extended period of time. Earth life uses water as a solvent but synthesis of observational data makes it possible to conceive chemical reactions that might support life involving non-carbon compounds, occurring in solvents other than water. In this paper a non-polar solvent is considered: ethane. Thermodynamic requirements to be fulfilled by a hypothetic gas constituent of a life-supporting SBD atmosphere are studied. Three gases are analyzed: nitrogen, carbon dioxide and methane. For thermodynamic reasons carbon dioxide is excluded from the list of candidate gases. We show that bodies with ethane oceans are possible in interstellar space. This may happen on SBD of (significantly) smaller or larger mass than the Earth. Generally, in case of SBD smaller in size than the Earth, the atmosphere exhibits a convective layer near the surface and a radiative layer at higher altitudes while the atmosphere of SBDs larger in size than Earth does not exhibit a convective layer. The prescribed thermodynamic state of ethane on the surface has some influence on the features of the atmosphere. The atmospheric mass of a life-hosting SBD of Earth size is two or three orders of magnitude larger than the mass of Earth atmosphere.  相似文献   
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