Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska   总被引：2，自引：0，他引：2  

Diana C. Roman  Katharine V. Cashman  Cynthia A. Gardner  Paul J. Wallace  John J. Donovan 《Bulletin of Volcanology》2006,68(3):240-254

Compositional heterogeneity (56–64 wt% SiO₂ whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO₂) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.  相似文献   

Enzyme leach anomalies associated with deep Mississippi Valley-type zinc ore bodies at the Elmwood Mine, Tennessee   总被引：1，自引：0，他引：1  

James R. Yeager  J. Robert Clark  Wallace Mitchell  Roy Renshaw 《Journal of Geochemical Exploration》1998,61(1-3)

Deeply buried Mississippi Valley-type deposits that have been or are currently being mined in North America were initially discovered by drilling. Conventional geochemical methods are ineffective for detecting these ‘blind' deposits when they occur deep within sequences of stable-platform carbonates and shales. The ‘enzyme' leach is a selective analytical technique for determining trace elements associated with amorphous Mn oxide coatings in soils. In many areas of the world, the enzyme leach method is useful for detecting low-level geochemical anomalies in soils, which are associated with blind mineral deposits. Enzyme leach analysis of soils, collected at the Elmwood Mine, Tennessee, revealed high-contrast anomalies over ore bodies 370 m below the surface. In areas where the soils are in chemical equilibrium, ‘combination' anomalies occur over Zn ore bodies. These are characterized by asymmetrical halogen halos which occur around a halogen ‘central low'. Commodity metals (Zn and Pb) and trace elements associated with the ore (Cd, Ba, and Mn) form apical anomalies, which occur over the ore bodies and within the halogen halo. Under most circumstances, agricultural practices do not affect enzyme leach results. However, agricultural activity in central Tennessee appears to have altered the proportion of amorphous Mn oxides in the soils in some locations. Where the MnO₂-form equilibrium of the soil has been disturbed, enzyme leach data are erratic. In the one instance where this was encountered, ratioing the data to Mn reveals anomalies which bracket the blind ore bodies.  相似文献   

冬季大气环流对北太平洋海冰和黑潮暖流海温的强迫作用   总被引：1，自引：0，他引：1  

方之芳  J. M. Wallace 《大气科学》1996,20(5):541-546

本文应用奇异值分解等统计方法，探讨冬季北太平洋海冰浓度、海温与大尺度大气环流型间的联系。分析结果表明:冬季北太平洋海域海冰存在一个主要的分布型，即鄂霍次克海和白令海的海冰呈反位相。海冰的该种分布特征是与大气中的WP型紧密联系的，并以大气超前海冰一个月最为明显。同时，WP型强迫作用于黑潮暖流区的海温，海温滞后大气一个月。具体表现为在东亚冬季风较弱的年份，鄂霍次克海海冰增多，白令海海冰减少，黑潮暖流区海温增高，反之则相反。  相似文献   

Relationship between subcellular cadmium distribution in prey and cadmium trophic transfer to a predator   总被引：1，自引：0，他引：1  

William G. Wallace  Glenn R. Lopez 《Estuaries and Coasts》1996,19(4):923-930

We tested the hypothesis that exposure-related alterations in the subcellular Cd distribution in prey relate to changes in Cd absorption by a predator. Oligochaete worms,Limnodrilus hoffmeisteri were exposed for 1 wk or 6 wk to 0.5 μg Cd 1^?1, 47 μg Cd 1^?1, or 140 μg Cd 1^?1 (including¹⁰⁹Cd as a tracer) and relationships between oligochaete subcellular Cd distribution and Cd absorption by a predator, the grass shrimp (Palaemonetes pugio), were determined. Concentration and duration of Cd exposure had direct effects on oligochaete subcellular Cd distribution. Changes in oligochaete subcellular Cd distribution were characterized by increases in both the amount and proportion of Cd bound to the cytosolic fraction. The induction of Cd-binding proteins (e.g., metallothioneins) were suspected to be responsible for these changes. We found 1∶1 relationships between the amount and percentage of Cd in oligochaete cytosol and the amount and percentage of Cd adsorbed by shrimp. These results demonstrate that only metal bound to the soluble fraction of prey is available to higher trophic levels, and that factors influencing subcellular metal distribution in prey will directly alter metal trophic transfer to predators.  相似文献   

Experimental Investigation of Surfactant-Enhanced Dissolution of Residual NAPL in Saturated Soil     

Lizette R. Chevalier  Susan J. Masten  Roger B. Wallace  David C. Wiggert 《Ground Water Monitoring & Remediation》1997,17(4):89-98

Nonaqueous phase liquid (NAPL) is a long-term source of ground water contamination as the pollutant slowly partitions into the air and water phases. The objective of this work was to study the efficacy of aqueous surfactant solution to enhance the dissolution of a residual NAPL below the capillary fringe, hence reducing the time needed for aquifer restoration. An analytical technique was developed to measure the concentration of NAPL in a nonionic surfactant. Soil column experiments simulated conditions in the saturated soil where a NAPL may become trapped as a discontinuous immobile phase. Experimental results indicate that dissolution was a rate-limited process, approaching equilibrium concentrations after 24 hours. The relative permeability of the aqueous phase initially decreased as surfactant was injected, but increased over time as the saturation of residual NAPL was reduced through mass transfer into the surfactant-enhanced aqueous phase. These findings suggest that enhancing the aqueous phase with a nonionic surfactant may significantly enhance the in situ recovery or residual NAPL.  相似文献   

The radiocarbon budget for Mono Lake: an unsolved mystery     

Wallace S. Broecker  Rik Wanninkhof  Guy Mathieu  Tsung-Hung Peng  Scott Stine  Steve Robinson  Andy Herczeg  Minze Stuiver 《Earth and Planetary Science Letters》1988,88(1-2)

Since 1957 the ¹⁴C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced¹⁴C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO₂ exchange rate, and (4) biological enhancement of the CO₂ exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity.  相似文献   

Introduction toelectrical properties of the Earth's mantle     

Wallace H. Campbell 《Pure and Applied Geophysics》1987,125(2-3):193-204

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Heat flow and depth versus age for the Mesozoic northwest Atlantic Ocean: results from the Sohm abyssal plain and implications for the Bermuda Rise     

K.E. Louden  Derek O. Wallace  Robert C. Courtney   《Earth and Planetary Science Letters》1987,83(1-4)

Heat flow in the Sohm abyssal plain is measured to be 53 mW/m² at an age of 163 Ma. This is 25% higher than predicted by conductive cooling models, even though the sediment-corrected basement depth of 6.5 km at this location is normal for its age. An analysis of existing heat flow, depth and geoid anomalies in the northwest Atlantic shows that there is little correlation between heat flow and depth throughout the entire region. Depth and geoid are clearly related to the Bermuda swell while the associated heat flow anomaly, once adjusted for variations with age, is limited to 5 mW/m² and only decays to the south. This means that the Bermuda swell is probably not caused by extensive thermal reheating within the lithosphere, but instead by dynamic uplift at its lower boundary due to the convective upwelling of a mantle plume. The regionally high heat flow in the northwest Atlantic may be a thermal remanent of previous plumes which passed beneath this region early in its history. Therefore, depth and heat flow anomalies from this region cannot be used to provide constraints on steady-state parameters of the lithosphere, such as the presence or absence of a long-term boundary layer at its base.  相似文献   

    

Wallace H. MacLean 《Contributions to Mineralogy and Petrology》2004,146(6):779

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Magma degassing and basaltic eruption styles: a case study of 2000 year BP Xitle volcano in central Mexico   总被引：1，自引：0，他引：1  

Pablo Cervantes  Paul Wallace   《Journal of Volcanology and Geothermal Research》2003,120(3-4):249-270

To investigate the relationship between volatile abundances and eruption style, we have analyzed major element and volatile (H₂O, CO₂, S) concentrations in olivine-hosted melt inclusions in tephra from the 2000 yr BP eruption of Xitle volcano in the central Trans-Mexican Volcanic Belt. The Xitle eruption was dominantly effusive, with fluid lava flows accounting for 95% of the total dense rock erupted material (1.1 km³). However, in addition to the initial, Strombolian, cinder cone-building phase, there was a later explosive phase that interrupted effusive activity and deposited three widespread ash fall layers. Major element compositions of olivine-hosted melt inclusions from these ash layers range from 52 to 58 wt.% SiO₂, and olivine host compositions are Fo_84–86. Water concentrations in the melt inclusions are variable (0.2–1.3 wt.% H₂O), with an average of 0.45±0.3 (1σ) wt.% H₂O. Sulfur concentrations vary from below detection (50 ppm) to 1000 ppm but are mostly ≤200 ppm and show little correlation with H₂O. Only the two inclusions with the highest H₂O have detectable CO₂ (310–340 ppm), indicating inclusion entrapment at higher pressures (700–900 bars) than for the other inclusions (≤80 bars). The low and variable H₂O and S contents of melt inclusions combined with the absence of less soluble CO₂ indicates shallow-level degassing before olivine crystallization and melt inclusion formation. Olivine morphologies are consistent with the interpretation that most crystallization occurred rapidly during near-surface H₂O loss. During cinder cone eruptions, the switch from initial explosive activity to effusive eruption probably occurs when the ascent velocity of magma becomes slow enough to allow near-complete degassing of magma at shallow depths within the cone as a result of buoyantly rising gas bubbles. This allows degassed lavas to flow laterally and exit near the base of the cone while gas escapes through bubbly magma in the uppermost part of the conduit just below the crater. The major element compositions of melt inclusions at Xitle show that the short-lived phase of renewed explosive activity was triggered by a magma recharge event, which could have increased overpressure in the storage reservoir beneath Xitle, leading to increased ascent velocities and decreased time available for degassing during ascent.  相似文献