Factors controlling seasonal groundwater and solute flux from snow‐dominated basins          下载免费PDF全文

Rosemary W. H. Carroll  Wendy Brown  Wenming Dong  Markus Bill  Kenneth H. Willlams 《水文研究》2018,32(14):2187-2202

Critical zone influences on hydrologic partitioning, subsurface flow paths and reactions along these flow paths dictate the timing and magnitude of groundwater and solute flux to streams. To isolate first‐order controls on seasonal streamflow generation within highly heterogeneous, snow‐dominated basins of the Colorado River, we employ a multivariate statistical approach of end‐member mixing analysis using a suite of daily chemical and isotopic observations. Mixing models are developed across 11 nested basins (0.4 to 85 km²) spanning a gradient of climatological, physical, and geological characteristics. Hydrograph separation using rain, snow, and groundwater as end‐members indicates that seasonal contributions of groundwater to streams is significant. Mean annual groundwater flux ranges from 12% to 33% whereas maximum groundwater contributions of 17% to 50% occur during baseflow. The direct relationship between snow water equivalent and groundwater flux to streams is scale dependent with a trend toward self‐similarity when basins exceed 5.5 km². We find groundwater recharge increases in basins of high relief and within the upper subalpine where maximum snow accumulation is coincident with reduced conifer cover and lower canopy densities. The mixing model developed for the furthest downstream site did not transfer to upstream basins. The resulting error in predicted stream concentrations points toward weathering reactions as a function of source rock and seasonal shifts in flow path. Additionally, the potential for microbial sulfate reduction in floodplain sediments along a low‐gradient, meandering portion of the river is sufficient to modify hillslope contributions and alter mixing ratios in the analysis. Soil flushing in response to snowmelt is not included as an end‐member but is identified as an important mechanism for release of solutes from these mountainous watersheds. End‐member mixing analysis used in combination with high‐frequency observations reveals important aspects of catchment hydrodynamics across scale.  相似文献   

Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy     

Angela L. Doherty  Robert J. Bodnar  Benedetto De Vivo  Wendy A. Bohrson  Harvey E. Belkin  Antonia Messina  Robert J. Tracy 《Central European Journal of Geosciences》2012,4(2):338-355

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo_72?84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo_57?78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO₂ of 49.8 wt %) in the pumices and basaltic-andesite (average SiO₂ of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.  相似文献   

Geoarchaeological Investigations of Midden‐Formation Processes in the Early to Late Ceramic Neolithic Levels at Çatalhöyük,Turkey ca. 8550–8370 cal BP     

Lisa‐Marie Shillito  Wendy Matthews 《Geoarchaeology》2013,28(1):25-49

Anthropogenic midden deposits are remarkably well preserved at the Neolithic settlement of Çatalhöyük and provide significant archaeological information on the types and nature of activities occurring at the site. To decipher their complex stratigraphy and to investigate formation processes, a combination of geoarchaeological techniques was used. Deposits were investigated from the early ceramic to late Neolithic levels, targeting continuous sequences to examine high resolution and broader scale changes in deposition. Thin‐section micromorphology combined with targeted phytolith and geochemical analyses indicates they are composed of a diverse range of ashes and other charred and siliceous plant materials, with inputs of decayed plants and organic matter, fecal waste, and sedimentary aggregates, each with diverse depositional pathways. Activities identified include in situ burning, with a range of different fuel types that may be associated with different activities. The complexity and heterogeneity of the midden deposits, and thus the necessity of employing an integrated microstratigraphic approach is demonstrated, as a prerequisite for cultural and palaeoenvironmental reconstructions.  相似文献   

Web 2.0 collaborations address uncertainty in climate reconstructions of the past millennium     

David Morrill Anderson  Bruce A. Bauer  Charles R. Buckner  Edward Gille  Wendy S. Gross  Michael Hartman  Carrie Morrill  Anju M. Shah  Eugene R. Wahl 《Earth Science Informatics》2011,4(4):161-167

Reducing uncertainty in global temperature reconstructions of the past millennium remains the key issue in applying this record to society’s pressing climate change problem. Reconstructions are collaborative, built on the research of hundreds of scientists who apply their diverse scientific expertise and field and laboratory skill to create the individual proxy reconstructions that underlie the multi-proxy, global average temperature time series. Web 2.0 features have enabled collaborative efforts that improve the characterization of uncertainty. Raw data shared via a repository (the World Data Center for Paleoclimatology) enable new reconstructions from the collection of user-generated data. Standards propagated by expert communities facilitate quality control and interoperability. Open access to data and computer code promote transparency and make the science accessible to a broader audience. Blogs, wikis, and listservs share background information and highlight contentious as well as unique aspects of paleo science. A novel approach now underway, titled the Paleoclimate Reconstruction Challenge, and based on the sharing of simulated data (pseudo-proxies) and reconstruction results, seeks to facilitate method development, further reducing uncertainty. Broadly-useful aspects of the Challenge may find application in other fields.  相似文献   

Fundamentals of glacier dynamics: C.J. van der Veen, A.A. Balkema, Rotterdam, Netherlands, 1999. 462 pp. ISBN 90-5410-471-6 (Paper US$42.00), 90-5410-470-8 (Hardback US$88.00).     

Wendy Bigler 《Geomorphology》2001,36(3-4)

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Anaerobic Metabolism in Tidal Freshwater Wetlands: II. Effects of Plant Removal on Archaeal Microbial Communities     

David Emerson  Wendy Bellows  Jason K. Keller  Craig L. Moyer  Ariana Sutton-Grier  J. Patrick Megonigal 《Estuaries and Coasts》2013,36(3):471-481

The interaction of plant and microbial communities are known to influence the dynamics of methane emission in wetlands. Plant manipulations were conducted in an organic rich (JB-organic) and a mineral rich (JB-mineral) site in a tidal freshwater wetland to determine if plant removal impacted archaeal populations. In concert, a suite of process-based measurements also determined the effects of plant removal on rates of methanogenesis and Fe-reduction. The microbial populations were analyzed with clone libraries of the SSU ribosomal RNA (rRNA) gene from selected plots, and terminal restriction length polymorphism (tRFLP) of the SSU rRNA and the methyl-coenzyme M reductase (mcrA) gene. Overall, methanogenesis dominated anaerobic carbon mineralization at both sites during the most active growing season. A total of 114 SSU rRNA clones from four different plots revealed a diversity of Euryarchaeota including representatives of the Methanomicrobiales, Methanosarcinales and Thermoplasmatales. The clone libraries were dominated by the Thaumarchaeota, accounting for 65 % of clones, although their diversity was low. A total of 112 tRFLP profiles were generated from 56 samples from 25 subplots; the patterns for both SSU rRNA and mcrA showed little variation between sites, either with plant treatment or with the growing season. Overall these results suggest that wetland soil archaeal populations were resilient to changes in the associated surface plant communities. The work also revealed the presence of novel, mesophilic Thaumarchaeota of unknown metabolic function.  相似文献   

Impacts of rising air temperatures and emissions mitigation on electricity demand and supply in the United States: a multi-model comparison   总被引：2，自引：2，他引：0  

James McFarland  Yuyu Zhou  Leon Clarke  Patrick Sullivan  Jesse Colman  Wendy S. Jaglom  Michelle Colley  Pralit Patel  Jiyon Eom  Son H. Kim  G. Page Kyle  Peter Schultz  Boddu Venkatesh  Juanita Haydel  Charlotte Mack  Jared Creason 《Climatic change》2015,132(1):111-125

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Silica grain catalysis of methanol formation     

T. P. M. Goumans  Adrian Wander  C. Richard A. Catlow  Wendy A. Brown 《Monthly notices of the Royal Astronomical Society》2007,382(4):1829-1832

The specific catalytic effect of a silica grain on the formation of methanol via the sequential addition of H atoms to CO adsorbed on the surface is investigated. A negatively charged defect on a siliceous edingtonite surface is found to reduce the gas phase barriers for the H + CO_ads and H + H₂C=O_ads reactions by 770 and 399 K, respectively, when compared to the same reactions in the gas phase. The catalytic effect of negatively charged surface sites could also be applicable to the hydrogenation of other adsorbed unsaturated species. However, the activation energies on the surface defect are still too large (1150 and 2230 K) for CH₃OH to form efficiently at 10–20 K in the interstellar medium via a classical mechanism. It is therefore suggested that quantum mechanical tunnelling through the activation barrier is required for these hydrogen addition reactions to proceed at such temperatures. The calculations show that because the adsorption energies of CO and H₂C=O on the negatively charged defect are substantial, CH₃OH may form efficiently during the warm-up period in star-forming regions.  相似文献   

Fundamental data on the desorption of pure interstellar ices     

Wendy A. Brown  Amandeep S. Bolina 《Monthly notices of the Royal Astronomical Society》2007,374(3):1006-1014

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Otolith measurement as a method of identifying factors affecting first-year growth and stock separation of mackerel (Scomber scombrus L.)     

Dawson  Wendy A. 《ICES Journal of Marine Science》1991,47(3):303-317

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