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81.
The coprecipitation of Na and K was experimentally investigated in aragonite. The distribution functions were determined at pH 6.8 and 8.8 over aqueous Na and K concentrations of between 5 × 10?4and 2.0 M and temperatures of between 25 and 75°C.The mole fractions of Na and K in aragonite are related to the aqueous ratios of Na and Ca by a function of the form
log XNa2CO3,K2CO3 = C0 + C1loga2Na ? ,K?aCa2+
where C0 and C1 are constants at a given temperature. This equation was derived by a statistical model assuming a heterogeneous energy distribution for the sites of incorporation. The independence of the coprecipitation process from aqueous anion activities suggests that carbonate is the only anionic species in the solid solution.  相似文献   
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83.
The Parkes–MIT–NRAO (PMN) radio survey has been used to generate a quasi all-sky study of Galactic Supernova Remnants (SNRs) at a common frequency of 4.85 GHz (λ=6 cm). We present flux densities estimated for the sample of 110 Southern Galactic SNRs (up to δ=−65°) observed with the Parkes 64-m radio telescope and an additional sample of 54 from the Northern PMN (up to δ=+64°) survey undertaken with the Green Bank 43-m (20 SNRs) and 91-m (34 SNRs) radio telescopes. Out of this total sample of 164 selected SNRs (representing 71% of the currently 231 known SNRs in the Green catalogue) we consider 138 to provide reliable estimates of flux density and surface brightness distribution. This sub-sample represents those SNRs which fall within carefully chosen selection criteria which minimises the effects of the known problems in establishing reliable fluxes from the PMN survey data. Our selection criteria are based on a judicious restriction of source angular size and telescope beam together with careful evaluation of fluxes on a case by case basis. Direct comparison of our new fluxes with independent literature values gives excellent overall agreement. This gives confidence in the newly derived PMN fluxes when the selection criteria are respected. We find a sharp drop off in the flux densities for Galactic SNRs beyond 4 Jy and then a fairly flat distribution from 5 to 9 Jy, a slight decline and a further flat distribution from 9 to 20 Jy though the numbers of SNR in each Jy bin are low. We also re-visit the contentious ΣD (radio surface brightness–SNRs diameter) relation to determine a new power law index for a sub-sample of shell type SNRs which yields β=−2.2±0.6. This new evaluation of the ΣD relation, applied to the restricted sample, provides new distance estimates and their Galactic scale height distribution. We find a peak in the SNR distribution between 7–11 kpc with most restricted to ±100 pc Galactic scale height.  相似文献   
84.
A similitude parameter is derived which is based on theoretical considerations of erosion due to sand in saltation. This parameter has been used to correlate wind tunnel experiments of particle flow over model craters. The characteristics of the flow field in the vicinity and downstream of a crater are discussed and it is shown that erosion is initiated in areas lying under a pair of trailing vortices. The erosion rate parameter is used to calculate erosion rates on Mars, reported in Part 2, to be published later.  相似文献   
85.
The coupling of photons and baryons by Thomson scattering in the early universe imprints features in both the cosmic microwave background (CMB) and matter power spectra. The former have been used to constrain a host of cosmological parameters, the latter have the potential to strongly constrain the expansion history of the universe and dark energy. Key to this program is the means to localize the primordial features in observations of galaxy spectra which necessarily involve galaxy bias, non-linear evolution and redshift space distortions. We present calculations, based on mock catalogs produced from high-resolution N-body simulations, which show the range of behaviors we might expect of galaxies in the real universe. We investigate physically motivated fitting forms which include the effects of non-linearity, galaxy bias and redshift space distortions and discuss methods for analysis of upcoming data. In agreement with earlier work, we find that a survey of several Gpc3 would constrain the sound horizon at z  1 to about 1%.  相似文献   
86.
Survey and Geographic Information System (GIS) data analysis describes the relative influence of biophysical and human variables on site choices made by marine farmers in New Zealand. Community conflicts have grown in importance in determining farm location and different government planning strategies leave distinct signature patterns. Recent legislation empowers local governments to choose among three strategies for future regional aquaculture development. This paper suggests each strategy could result in different spatial outcomes. Simulation modelling of the type described here can provide a better understanding of farmer responses to management approaches and the range of futures that could result from planning choices made today.  相似文献   
87.
To enable detailed investigations of early stage hydrothermal plume formation and abiotic and biotic plume processes we developed a new oceanographic tool. The Suspended Particulate Rosette sampling system has been designed to collect geochemical and microbial samples from the rising portion of deep-sea hydrothermal plumes. It can be deployed on a remotely operated vehicle for sampling rising plumes, on a wire-deployed water rosette for spatially discrete sampling of non-buoyant hydrothermal plumes, or on a fixed mooring in a hydrothermal vent field for time series sampling. It has performed successfully during both its first mooring deployment at the East Pacific Rise and its first remotely-operated vehicle deployments along the Mid-Atlantic Ridge. It is currently capable of rapidly filtering 24 discrete large-water-volume samples (30–100 L per sample) for suspended particles during a single deployment (e.g. >90 L per sample at 4–7 L per minute through 1 μm pore diameter polycarbonate filters). The Suspended Particulate Rosette sampler has been designed with a long-term goal of seafloor observatory deployments, where it can be used to collect samples in response to tectonic or other events. It is compatible with in situ optical sensors, such as laser Raman or visible reflectance spectroscopy systems, enabling in situ particle analysis immediately after sample collection and before the particles alter or degrade.  相似文献   
88.
Some remarks on the Gaussian beam summation method   总被引:1,自引:0,他引:1  
Summary. Recently, a method using superposition of Gaussian beams has been proposed for the solution of high-frequency wave problems. The method is a potentially useful approach when the more usual techniques of ray theory fail: it gives answers which are finite at caustics, computes a nonzero field in shadow zones, and exhibits critical angle phenomena, including head waves. Subsequent tests by several authors have been encouraging, although some reported solutions show an unexplained dependence on the 'free' complex parameter ε which specifies the initial widths and phases of the Gaussian beams.
We use methods of uniform asymptotic expansions to explain the behaviour of the Gaussian beam method. We show how it computes correctly the entire caustic boundary layer of a caustic of arbitrary complexity, and computes correctly in a region of critical reflection. However, the beam solution for head waves and in edge-diffracted shadow zones are shown to have the correct asymptotic form, but with governing parameters that are explicitly ε-dependent. We also explain the mechanism by which the beam solution degrades when there are strong lateral inhomogeneities. We compare numerically our predictions for some representative, model problems, with exact solutions obtained by other means.  相似文献   
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90.
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