Laboratory and field evaluation of a flushable oxic limestone drain for treatment of net-acidic drainage from a flooded anthracite mine, Pennsylvania, USA   总被引：1，自引：0，他引：1  

Charles A. Cravotta III   《Applied Geochemistry》2008,23(12):3404-3422

This paper demonstrates the use of dissolution-rate data obtained in the laboratory to indicate the potential quality of effluent from a field-scale oxic limestone drain (OLD) treatment system for neutralization of dilute acidic mine drainage (AMD). Effluent from the Reevesdale Mine South Dip Tunnel, a large source of AMD and base flow to the Wabash Creek and Little Schuylkill River in the Southern Anthracite Coalfield of east-central Pennsylvania, is representative of AMD with low concentrations but high loadings of dissolved Fe, Al and other metals because of a high flow rate. In January 2003, rapid neutralization of the AMD from the Reevesdale Mine was achieved in laboratory tests of its reaction rate with crushed limestone in closed, collapsible containers (Cubitainers). The tests showed that net-alkaline effluent could be achieved with retention times greater than 3 h and that effluent alkalinities and associated dissolution rates were equivalent for Fe(OH)₃-coated and uncoated limestone. On the basis of the laboratory results, a flushable OLD containing 1450 metric tons of high-purity calcitic limestone followed by two 0.7-m deep wetlands were constructed at the Reevesdale Mine. During the first year of operation, monthly data at the inflow, outflow and intermediate points within the treatment system were collected (April 2006–2007). The inflow to the treatment system ranged from 6.8 to 27.4 L/s, with median pH of 4.7, net acidity of 9.1 mg/L CaCO₃, and concentrations of dissolved Al, Fe and Mn of 1.0, 1.9 and 0.89 mg/L, respectively. The corresponding effluent from the OLD had computed void-volume retention times of 4.5–18 h, with median pH of 6.6, net acidity of −93.2 mg/L CaCO₃, and concentrations of dissolved Al, Fe and Mn of <0.1, 0.08 and 0.52 mg/L, respectively. The wetlands below the OLD were effective for retaining metal-rich solids flushed at monthly or more frequent intervals from the OLD, but otherwise had little effect on the effluent quality. During the first year of operation, approximately 43 metric tons of limestone were dissolved and 2 metric tons of Al, Fe and Mn were precipitated within the OLD. However, because of the accumulation of these metals within the OLD and possibly other debris from the mine, the effectiveness of the treatment system declined. Despite the installation of a flush-pipe network at the base of the OLD to remove precipitated solids, the limestone bed clogged near the inflow. Consequently, a large fraction of the AMD bypassed the treatment system. To promote flow through the OLD, the flush pipes were open continuously during the last 4 months of the study; however, this effluent was only partially treated because short-circuiting through the pipes decreased contact between the effluent and limestone. A reconfiguration of the flow path through the limestone bed from horizontal to vertical upward could increase the limestone surface area exposed to the metal-laden influent, increase the cross-sectional area perpendicular to flow, decrease the flow path for solids removal, and, consequently, decrease potential for clogging.  相似文献   

Dissolved metals and associated constituents in abandoned coal-mine discharges,Pennsylvania, USA. Part 1: Constituent quantities and correlations     

Charles A. Cravotta III 《Applied Geochemistry》2008

Complete hydrochemical data are rarely reported for coal-mine discharges (CMD). This report summarizes major and trace-element concentrations and loadings for CMD at 140 abandoned mines in the Anthracite and Bituminous Coalfields of Pennsylvania. Clean-sampling and low-level analytical methods were used in 1999 to collect data that could be useful to determine potential environmental effects, remediation strategies, and quantities of valuable constituents. A subset of 10 sites was resampled in 2003 to analyze both the CMD and associated ochreous precipitates; the hydrochemical data were similar in 2003 and 1999. In 1999, the flow at the 140 CMD sites ranged from 0.028 to 2210 L s⁻¹, with a median of 18.4 L s⁻¹. The pH ranged from 2.7 to 7.3; concentrations (range in mg/L) of dissolved (0.45-μm pore-size filter) SO₄ (34–2000), Fe (0.046–512), Mn (0.019–74), and Al (0.007–108) varied widely. Predominant metalloid elements were Si (2.7–31.3 mg L⁻¹), B (<1–260 μg L⁻¹), Ge (<0.01–0.57 μg L⁻¹), and As (<0.03–64 μg L⁻¹). The most abundant trace metals, in order of median concentrations (range in μg/L), were Zn (0.6–10,000), Ni (2.6–3200), Co (0.27–3100), Ti (0.65–28), Cu (0.4–190), Cr (<0.5–72), Pb (<0.05–11) and Cd (<0.01–16). Gold was detected at concentrations greater than 0.0005 μg L⁻¹ in 97% of the samples, with a maximum of 0.0175 μg L⁻¹. No samples had detectable concentrations of Hg, Os or Pt, and less than half of the samples had detectable Pd, Ag, Ru, Ta, Nb, Re or Sn. Predominant rare-earth elements, in order of median concentrations (range in μg/L), were Y (0.11–530), Ce (0.01–370), Sc (1.0–36), Nd (0.006–260), La (0.005–140), Gd (0.005–110), Dy (0.002–99) and Sm (<0.005–79). Although dissolved Fe was not correlated with pH, concentrations of Al, Mn, most trace metals, and rare earths were negatively correlated with pH, consistent with solubility or sorption controls. In contrast, As was positively correlated with pH.  相似文献   

Ground-Water Studies— Chicagoland Deep Tunnel System     

Istavros S. Papadopulos  William R. Larsen  Forrest C. Neil 《Ground water》1969,7(5):3-15

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APPROACHES TOWARD AN UNDERSTANDING OF TRADITIONAL SOUTH ASIAN PEASANT DWELLINGS*     

William A. Noble 《The Professional geographer》1969,21(4):264-271

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Ionospheric conditions     

Marcel Nicolet  William Swider  Jr. 《Planetary and Space Science》1963,11(12):1459-1482

A general analysis of ionospheric conditions has been made in the light of possible ionic reactions occurring in the upper atmosphere. Data obtained on various parameters, such as ionic production and recombination, show that precise knowledge of the spectral distribution of solar radiation is needed and that other experimental determinations on dissociative recombinations are required.

The ionic complexity of the ionosphere is underlined by describing how the atomic ions O⁺ and N⁺ react with N₂, O₂ and NO molecules. The behavior of the molecular ions N⁺₂, O⁺₂and NO⁺depends on a group of simultaneous processes involving charge transfers and ionatom interchanges which are more important than dissociative recombinations. The altitude distribution of ions is exemplified by discussing the relative importance of various loss coefficients in the D-, E- and F-regions. It is seen that molecular nitrogen ions are subject to important charge transfer processes, that nitric oxide ions are always final products destroyed only by dissociative recombination. Additionally, the entire production of atomic oxygen ions is related to the photoionization of molecular nitrogen. Some information is also given on possible anomalies in the ratio of O⁺₂ and NO⁺ densities in the lower ionosphere. From the lack of sufficient experimental information on ionic processes it is shown that a precise analysis of ionospheric behavior remains highly speculative.  相似文献   

A digital event-recording ocean bottom seismometer capsule     

William A. Prothero Jr. 《Marine Geophysical Researches》1977,3(1):119-141

The ocean bottom seismometer capsule contains a 1 Hz. vertical seismometer and triggerable or programmable digital recording system. The output of the seismometer is continuously digitized at a preselected rate of 64, 128, or 256 samples/sec. The digital data words are mixed with a time code and synchronization characters, serialized and passed through a 1536 sample shift register which acts as a delay line. The serial output bits are then encoded and recorded on a SONY TC800B tape recorder which is turned on when a seismic event occurs. The event trigger occurs when the seismic signal jumps to 8 times the time averaged input signal. A memory may be programmed to run the recorder on a schedule so that small amplitude signals from refraction shots are sure to be recorded. Data are recovered using the same recorder for playback and a decoder which provides an analog output for field data interpretation or a digital output for computer analysis. An acoustic transponder allows precise ranges between the capsule and ship to be determined. In addition, commands for the capsule to release or to transmit diagnostic data may be given from the surface ship. The capsule falls freely to the ocean bottom. After a predetermined time or when a release command is received, it is released from a 68 kg steel tripod and floats to the surface. A dual timer and explosive bolt system is used to increase recovery reliability.The first capsules were designed and constructed between October 1972 and October 1973. Good results were obtained from 38 out of 43 launchings made on six expeditions in 1974, 1975, and 1976. Four capsules have been lost.  相似文献   

Deep tow studies of the Tamayo transform fault     

Ken C. MacDonald  Kim Kastens  F. N. Spiess  S. P. Miller 《Marine Geophysical Researches》1979,4(1):37-70

The Tamayo transform fault occurs at the north end of the East Pacific Rise where it enters the Gulf of California. The two deep-tow surveys reported here show that the transform fault zone changes significantly as a function of distance from the spreading center intersections. At site 1, near the intersection, one side of the fault is young and the fault zone is narrow and well-defined. Strike slip occurs in a zone approximately 1-km wide suggesting a correspondingly narrow zone of decoupling between the Pacific and North American plates. On the young side of the strike-slip zone, normal faults occur along shear zones which are 45°–50° oblique to the transform strike. They occur parallel to the short axis of the strain ellipse for transform fault strain here, i.e., perpendicular to the least compressive stress. The transform walls are formed by normal faulting as has been pointed out in previous detailed surveys. Here, however, the age contrast of 2.5 m.y. across the transform valley is apparent in the morphology of the normal fault scarps. While the scarps are steep and well-defined on the young side, the scarps on the older side have gradual 10°–30° slopes and appear to be primarily talus ramps. Apparently, the scarps have been tectonically eroded by continued strike slip activity after the initial stages of normal faulting. Thus, transform valleys should be quite asymmetric in cross-section where there is a significant age contrast and one side is less than approximately 0.5 m.y. old. Also, along older sections of the transform valley walls, normal faulting may not be at all obvious due to degradation of the scarps by tectonic erosion. This phenomenon makes the likelihood of transform faults providing windows into the oceanic crust most unlikely except in special cases.The picture of transform deformation is more complex at site 2 in the central portion of the fault where both sides of the fault are greater than 1 m.y. old. Here the transform valley is wider (25–30 km as opposed to 2–5 km). There is no clear simple zone of strike slip tectonics. In fact, the only clear evidence for deformation is the intrusion of magmatic or serpentinite diapirs through the sediments of the transform valley floor. The diapirs have deformed the turbidite layers flooring the valley and in one carefully studied case the turbidite sequence has been uplifted, perched atop the diapir. The pattern of deformation on this outcropping diapir shows radial and concentric fractures which can be modeled by a vertical intrusion circular in plan view. Magnetic studies limit the possible composition to basalt or serpentinite. A 60-km-long median ridge is also likely to be the product of intrusion along the transform fault. The survey at site 2 pointed out the importance of vertical tectonics in the transform valley floor and in particular the importance of diapiric intrusions of either basaltic or serpentinite composition.Based on initial boundary conditions and present tectonic elements in the Tamayo fault zone, a possible history of the mouth of the Gulf of California is outlined. The median ridge was emplaced starting approximately 0.8 m.y. ago by regional extension across the transform fault, the result of leaky transform faulting. The diapirs occur along a possible relay zone of extension midway along the fault which began approximately 0.15 m.y. ago. The extension in this case is parallel to the trend of the transform fault, is still occurring at present, and may evolve into a true spreading center.Contribution of the Scripps Institution of Oceanography, new series.  相似文献   

Mussels document loss of bioavailable polycyclic aromatic hydrocarbons and the return to baseline conditions for oiled shorelines in Prince William Sound, Alaska     

Page DS  Boehm PD  Brown JS  Neff JM  Burns WA  Bence AE 《Marine environmental research》2005,60(4):422-436

Polycyclic aromatic hydrocarbons (PAH) were measured in mussels (Mytilus trossulus) collected between 1990 and 2002 from 11 sites on the shores of Prince William Sound (PWS), Alaska, that were heavily oiled by the 1989 Exxon Valdez oil spill (EVOS). This study, utilizing the methods of the NOAA Status and Trends Mussel Watch Program, found that concentrations of PAH released from spill remnants have decreased dramatically with time and by 2002 were at or near the range of total PAH (TPAH) of 3-355 ng/g dry weight obtained for mussels from unoiled reference sites in PWS. Time-series TPAH data indicate a mean TPAH half-life in mussel tissues of 2.4 years with a range from 1.4 to 5.3, yielding an annual mean loss of bioaccumulated TPAH of 25%. The petroleum-derived TPAH fraction in mussel tissues has decreased with time, reflecting the decreasing release of EVOS residues in shoreline sediments. These results show that PAH from EVOS residues that remain buried in shoreline sediments after the early 1990s are in a form and at locations that have a low accessibility to mussels living in the intertidal zone.  相似文献   

Distribution, texture and composition of modern phosphate pellets in Peru shelf muds     

K. Bryan Baker  William C. Burnett 《Marine Geology》1988,80(3-4):195-213

Textural analysis, including estimates of concentrations of authigenic phosphate pellets, were made for eight sediment cores from the Peru continental margin. Phosphatic pellets separated from these modern organic-rich sediments are black, spherical-ovoidal in shape, and in thin section often display a concentric structure around a nucleus consisting of inorganic mineral grains. Some pellets have a gray-white exterior coating which appears to be secondary diagenetic calcite. Phosphatic pellets account for upwards of 80% of the sediment mass in some cores. Pellets concentrate in specific size classes, generally between 125 and 500 μm in diameter, and occur within a poorly sorted sediment.  相似文献   

Photoadaptation of carboxylating enzymes and photosynthesis during a spring bloom     

John Clegg Smith  Trevor Platt  William G. Harrison 《Progress in Oceanography》1983,12(4):425-459

Properties of the light saturation curve of photosynthesis and ribulose-1,5-bisphosphate carboxylase (RuBPC) activity are shown to change qualitatively in a natural population of marine phytoplankton during a spring bloom. Evidence is presented to show that these changes constitute photoadapative responses to increasing irradiance. As irradiance increased during the bloom, both the level of light-saturated photosynthesis (P_m) and the initial slope of the light saturation curve (α = photosynthetic efficiency) increased whether those parameters were normalized to chlorophyll a concentration (P_m^b, α^b) or to cell numbers (P_m^c, α^c). The magnitudes of these changes were such that I_k (= P_m/α, the photoadaptation parameter) did not change, but I_m, the light intensity at which photosynthesis becomes saturated, increased. RuBPC activity, both chlorophyll a (RuBPC^b) and cell number normalized (RuBPC^c), also increased during the bloom. We suggest that these adaptations were achieved by simultaneously increasing the number of photosynthetic units, proportionately decreasing the photosynthetic unit size, and increasing both the concentrations of the enzymes of the dark reactions and possibly also of photosynthetic electron transport components.We also observed diminished levels of photoinhibition in the high light adapted cells late in the bloom and have suggested that this was a consequence of the same suite of physiological changes.In situ carbon fixation per cell increased during the bloom whereas no change occurred in this parameter when normalized to chlorophyll a concentration. Although these photoadaptive responses thus permitted carbon to be fixed in situ more rapidly per cell, at a constant efficiency with respect to investment of energy in the photosynthetic apparatus, they did not result in a change in growth rate. Based on consideratios of the role of time scale in physiological adaptation, however, it is suggested that the observed alterations in photosynthesis with increasing irradiance might permit a cell to more rapidly fill an energy quota for division, possibly an advantage in a mixing environment in which energy is patchily distributed, both spatially and temporalyy.Phosphoenolpyruvate carboxylase activity when normalized to chlorophyll a (PEPC^b) did not change during the bloom while chlorophyll a normalized dark carbon fixation decreased sharply and was quantitatively small compared to PEPC^b. On this basis and considering that RuBPC^b increased during the bloom, it is suggested that, although PEPC may be involved in dark carbon fixation, its most important quantitative role is probably an indirect one in light dependent photosynthesis.We have also considered the relevance of laboratory results on photoadaptation to interpretations of field studies and have suggested that batch culture studies must be treated with caution but that turbidistat and semi-continuous methods provide reasonable simulations of natural conditions.  相似文献