Bioaccumulation of nitroarenes in bivalves at Osaka Bay, Japan     

Uno S  Tanaka H  Miki S  Kokushi E  Ito K  Yamamoto M  Koyama J 《Marine pollution bulletin》2011,63(5-12):477-481

This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels.  相似文献   

Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting   总被引：2，自引：0，他引：2  

Shoji Arai  Hidenobu Okamura  Kazuyuki Kadoshima  Chima Tanaka  Kenji Suzuki  Satoko Ishimaru 《Island Arc》2011,20(1):125-137

We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.  相似文献   

Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH₄-CO₂ fluxes     

G. Etiope  R. NakadaK. Tanaka  N. Yoshida 《Applied Geochemistry》2011,26(3):348-359

Methane and CO₂ emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (δ¹³C_CH4 from −32.9‰ to −36.2‰), likely associated with oil, and enrichments of ¹³C in CO₂ (δ¹³C_CO2 up to +28.3‰) and propane (δ¹³C_C3H8 up to −8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 10¹-10⁴ g m⁻² d⁻¹ in macro-seeps, and up to 446 g m⁻² d⁻¹ from diffuse seepage. Positive CH₄ fluxes from dry soil were widespread throughout the investigated areas. Total CH₄ emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton a⁻¹, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO₂ fluxes were directly proportional to CH₄ fluxes, and the volumetric ratios between CH₄ flux and CO₂ flux were similar to the compositional CH₄/CO₂ volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the “Bernard ratio” C₁/(C₂ + C₃)) is inversely proportional to gas migration fluxes. The CH₄ “emission factor” (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global “emission-factor” data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH₄ emission from mud volcanoes may be significantly underestimated.  相似文献   

Breaking pattern and critical breaking condition of Japanese pine trees on coastal sand dunes in huge tsunami caused by Great East Japan Earthquake     

Norio Tanaka  Junji Yagisawa  Satoshi Yasuda 《Natural Hazards》2013,65(1):423-442

Coastal vegetation is widely recognized to reduce tsunami damage to people and buildings, and it has been studied recently because it requires relatively little capital investment compared with artificial measures, provides human-friendly beach fronts, and enhances inter-relationships with other ecological systems. However, the tsunami caused by the Great East Japan Earthquake at 14:46 JST on March 11, 2011, with a magnitude of 9.0 and epicenter 129?km east of Sendai, broke most of the sea wall (tsunami gates, large embankments) and caused catastrophic damage to coastal forests in the Tohoku and Kanto districts of Japan. A field survey was conducted to elucidate the critical breaking condition of Japanese coastal pine trees. Tree-trunk breakage was observed when the sea embankment was washed out or when there was no sea embankment and the tree was under strong inertia force or impact force by debris. Even though the trunk bending and breaking phenomena are different, statistical analysis showed that the critical diameters for trunk bending and trunk breaking were not very different. The overturning phenomenon is a little more complex than trunk breaking because the resistive force is a function of the substrate and root anchorage. An equation to determine the critical diameters for trunk bending, trunk breaking, and overturning was derived as a function of tsunami water depth, soil-root strength, and the hydrodynamic parameter (H _D ) formulated by Froude number, drag coefficient, and the ratio of impact force to drag force considering the physical mechanisms to resist the tsunami. Trunk bending and breaking were closely related to tsunami water depth and the hydrodynamic parameter (H _D ), but tree overturning was found to be more site specific, and the root-soil strength greatly affected the critical value. The proposed critical diameter equation and its coefficient are useful for the design of an inland forest of pine trees that can trap large trees, cars, debris, etc., to its breaking limit. The trapping function should be utilized more in the future designs of inland forests, if possible, on embankments.  相似文献   

Ecosystem Responses of the Subtropical Kaneohe Bay,Hawaii, to Climate Change: A Nitrogen Cycle Modeling Approach     

Katsumasa Tanaka  Michael W. Guidry  Nicolas Gruber 《Aquatic Geochemistry》2013,19(5-6):569-590

The global coastal zone is characterized by high biological productivity and serves as an important channel through which materials are transferred from land to the open ocean, yet little is known how it will be affected by climate change. Here, we use Kaneohe Bay, Hawaii, a semi-enclosed subtropical embayment partially surrounded by a mountainous watershed and fed by river runoff as an example to explore the potential impact of climate change on the pelagic and benthic cycling of nitrogen. We employ a nine-compartment nitrogen cycle biogeochemical box model and perturb it with a set of four idealized climate scenarios. We find that hydrological changes play a dominant role in determining the ecosystem structure, while temperature changes are more important for the trophic state and stability of the ecosystem. The ecosystem stability against storm events does not significantly change under any scenario. The system remains autotrophic in the future; however, it becomes significantly less autotrophic under drier climate, while it turns slightly more autotrophic under wetter climate. These findings may have implications for other high island watershed and coastal ecosystems in the tropics and subtropics.  相似文献   

Geometry of the Nojima Fault at Nojima-Hirabayashi, Japan – II. Microstructures and their Implications for Permeability and Strength     

Diane E. Moore  David A. Lockner  Hisao Ito  Riuji Ikeda  Hidemi Tanaka  Kentaro Omura 《Pure and Applied Geophysics》2009,166(10-11):1669-1691

Samples of damage-zone granodiorite and fault core from two drillholes into the active, strike-slip Nojima fault zone display microstructures and alteration features that explain their measured present-day strengths and permeabilities and provide insight on the evolution of these properties in the fault zone. The least deformed damage-zone rocks contain two sets of nearly perpendicular (60–90° angles), roughly vertical fractures that are concentrated in quartz-rich areas, with one set typically dominating over the other. With increasing intensity of deformation, which corresponds generally to increasing proximity to the core, zones of heavily fragmented rock, termed microbreccia zones, develop between prominent fractures of both sets. Granodiorite adjoining intersecting microbreccia zones in the active fault strands has been repeatedly fractured and locally brecciated, accompanied by the generation of millimeter-scale voids that are partly filled with secondary minerals. Minor shear bands overprint some of the heavily deformed areas, and small-scale shear zones form from the pairing of closely spaced shear bands. Strength and permeability measurements were made on core collected from the fault within a year after a major (Kobe) earthquake. Measured strengths of the samples decrease regularly with increasing fracturing and fragmentation, such that the gouge of the fault core and completely brecciated samples from the damage zone are the weakest. Permeability increases with increasing disruption, generally reaching a peak in heavily fractured but still more or less cohesive rock at the scale of the laboratory samples. Complete loss of cohesion, as in the gouge or the interiors of large microbreccia zones, is accompanied by a reduction of permeability by 1-2 orders of magnitude below the peak values. The core samples show abundant evidence of hydrothermal alteration and mineral precipitation. Permeability is thus expected to decrease and strength to increase somewhat in active fault strands between earthquakes, as mineral deposits progressively seal fractures and fill pore spaces.  相似文献   

Effect of open gap in coastal forest on tsunami run-up—investigations by experiment and numerical simulation     

Nguyen Ba Thuy  Katsutoshi Tanimoto  Norio Tanaka  Kenji Harada  Kosuke Iimura 《Ocean Engineering》2009,36(15-16):1258-1269

The objective of this study is to investigate the effects of an open gap, such as a road, in a coastal forest on tsunami run-up. A numerical model based on two-dimensional nonlinear long-wave equations was developed to account for the effects of drag and turbulence induced shear forces due to the presence of vegetation. Experiments were conducted on a forest simulated with vertical cylinders by changing the gap width. The numerical model was validated in good agreement with the experimental results. The numerical model was then applied to a wide forest of Pandanus odoratissimus, a tree species that is a dominant coastal vegetation on a sand dune in South and Southeast Asia. The effect of vertical stand characteristics of P. odoratissimus with aerial roots was considered on the drag resistance. A straight open gap perpendicular to the shoreline was used to investigate the effect of gap width. As the gap width increases, the flow velocity at the end of the open gap first increases, reaches a maximum, and then decreases, while the run-up height increases monotonously. The maximum velocity in the present condition is 1.7 times the maximum velocity without a coastal forest. The effects of different gap arrangements in the forest on tsunami run-up were also investigated in this paper. The flow velocity at the end of an open gap can be reduced by a staggered arrangement.  相似文献   

Optical properties of the red tide in Isahaya Bay,southwestern Japan: Influence of chlorophyll a concentration     

Hiroaki Sasaki  Akihiko Tanaka  Mitsunori Iwataki  Yasuharu Touke  Eko Siswanto  Chun Knee Tan  Joji Ishizaka 《Journal of Oceanography》2008,64(4):511-523

Remote sensing reflectance [R _rs(λ)] and absorption coefficients of red tides were measured in Isahaya Bay, southwestern Japan, to investigate differences in the optical properties of red tide and non-red tide waters. We defined colored areas of the sea surface, visualized from shipboard, as “red tides”. Peaks of the R _rs(λ) spectra of non-red tide waters were at 565 nm, while those of red tides shifted to longer wavelengths (589 nm). The spectral shape of R _rs(λ) was close to that of the reciprocal of the total absorption coefficient [1/a(λ)], implying that the R _rs(λ) peak is determined by absorption. Absorption coefficients of phytoplankton [a _ph(λ)], non-pigment particles and colored dissolved organic matter increased with increasing chlorophyll a concentration (Chl a), and those coefficients were correlated with Chl a for both red tide and non-red tide waters. Using these relationships between absorption coefficients and Chl a, variation in the spectrum of 1/a(λ) as a function of Chl a was calculated. The peak of 1/a(λ) shifted to longer wavelengths with increasing Chl a. Furthermore, the relative contribution of a _ph(λ) to the total absorption in red tide water was significantly higher than in non-red tide water in the wavelength range 550–600 nm, including the peak. Our results show that the variation of a _ph(λ) with Chl a dominates the behavior of the R _rs(λ) peak, and utilization of R _rs(λ) peaks at 589 and 565 nm may be useful to discriminate between red tide and non-red tide waters by remote sensing.  相似文献   

High-energy observations of solar flares     

Katsuo Tanaka 《Astrophysics and Space Science》1986,118(1-2):101-113

Extensive observations of solar flares made in high energy bands during the maximum of the present solar cycle are discussed with a special reference to the results from HINOTORI, and with attention to the relevant flare models. The hard X-ray (HXR) images from HINOTORI showed mostly coronal emission at 20–25 keV suggesting that the HXR is emitted from multiple coronal loops, consistent with the non-thermal electron beam model in a high density corona. The thermal HXR model seems to be inconsistent with some observations. Three types of flares which have been classified from the Hinotori results are described, along with newly discovered hot thermal component of 30–40 million K which contributes thermal HXR emission. A summary is given for the characteristics of the energy release in an impulsive burst; and an empirical model is described, which explains simultaneous energy releases in multiple loops and successive movements of the release site as suggested from the HXR morphology. The discovery of large blue-shifted hot plasma from the soft X-ray line spectrum leads to some quantitative arguments for the evaporating flare model. An electron-heated flare atmosphere appears to explain various observations consistently.Invited paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.  相似文献   

On the fine structure of the ground-based vlf chorus as an indicator of the wave-particle interaction processes in the magnetospheric plasma     

S.S. Sazhin  M. Hayakawa  Y. Tanaka 《Planetary and Space Science》1985,33(4):385-386

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