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We have investigated spatial and spectral associations between mineral species and organic matter in the Tagish Lake meteorite. Synchrotron‐based infrared microspectroscopy allowed us to spatially locate specific organic and inorganic compounds within multiple Tagish Lake grains with high spatial resolution. Generated two‐dimensional infrared maps present strong spatial association between aliphatic C‐H and OH in phyllosilicates in Tagish Lake grains. These observations indicate possible roles of phyllosilicates for the formation, evolution, and preservation of organic matter. Infared spectra of all studied Tagish Lake grains show a strong carbonate band, which also shows a weak but positive correlation with organic matter in some grains. However, intergrain correlation was not observed between carbonates and organics, which is likely due to the difference of carbonate occurrence, e.g., presence of larger grains or intergrowth of carbonates on phyllosilicates. Possible scenarios further explaining the observed associations of organics with phyllosilicates and carbonates are presented.  相似文献   
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The objective of this study is to clarify the effect of ulvoid (Ulva spp.) accumulation on the structure and function of an eelgrass bed by the coast of Iwakuni, Seto Inland Sea, Japan. We monitored eelgrass shoot density and volume of ulvoid accumulation in the study site and evaluated effects of the accumulated ulvoid canopy on the percent survival, seedling density, growth rates, photosynthetic photon flux density (PPFD) and carbon contents of eelgrass. Eelgrass shoot density decreased by the accumulation of ulvoid. Also, seedling density decreased by the increase in the ulvoid volumes. Shoot density, seedling density and leaf elongation were negatively correlated with ulvoid volume. Carbon contents in eelgrass decreased by the accumulation of ulvoid (canopy height: 25cm). These results suggest that accumulation of ulvoid bloom has significant negative impacts on the structure and function of eelgrass bed, i.e. decreases in vegetative shoot density, seedling density, shoot height and growth rate.  相似文献   
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Intracellular partitioning of trace metals is critical to metal tolerance in aquatic organisms and may also influence metal trophic transfer in ecosystems. In this study, we tested the relevance of metal (Cd, Cu, Pb, and Zn) intracellular partitioning in prey as an indicator of metal trophic availability to benthic forage fish, mummichogs (Fundulus heteroclitus), in chronically metal-polluted salt marshes in New York, USA. Two common prey of mummichogs in the study area, Palaemonetes pugio and Nereis acuminata, generally stored increasingly higher proportions of non-essential metals (particularly Pb) in insoluble (less trophically available) cellular components, as the whole body burdens increased. In contrast, intracellular partitioning of essential metals (Cu and Zn) in invertebrate prey varied relatively little among sites. Differential Cd and Pb intracellular partitioning patterns within P. pugio among sites were significantly associated with Cd and Pb whole body burdens in mummichogs, respectively (i.e., prey-driven bioreduction of metals), while bioaccumulation of Cu and Zn in mummichogs was similar among populations. The findings in this study suggest that metal intracellular partitioning within prey may be partially responsible for metal trophic availability to a predator in metal-polluted habitats, while there was also evidence that some predator-dependent processes may offset differential trophic availabilities from prey.  相似文献   
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An extended cloud-clustering method to assess the seasonal variation of clouds is applied to five CMIP5 models. The seasonal variation of the total cloud radiative effect (CRE) is dominated by variations in the relative frequency of occurrence of the different cloud regimes. Seasonal variations of the CRE within the individual regimes contribute much less. This is the case for both observations, models and model errors. The error in the seasonal variation of cloud regimes, and its breakdown into mean amplitude and time varying components, are quantified with a new metric. The seasonal variation of the CRE of the cloud regimes is relatively well simulated by the models in the tropics, but less well in the extra-tropics. The stratocumulus regime has the largest seasonal variation of shortwave CRE in the tropics, despite having a small magnitude in the climatological mean. Most of the models capture the temporal variation of the CRE reasonably well, with the main differences between models coming from the variation in amplitude. In the extra-tropics, most models fail to correctly represent both the amplitude and time variation of the CRE of congestus, frontal and stratocumulus regimes. The annual mean climatology of the CRE and its amplitude in the seasonal variation are both underestimated for the anvil regime in the tropics, the cirrus regime and the congestus regime in the extra-tropics. The models in this study that best capture the seasonal variation of the cloud regimes tend to have higher climate sensitivities.  相似文献   
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How do we understand national climate change politics in the United States? Using a methodological innovation in network analysis, this paper analyzes discussions about the issue within the US Congress. Through this analysis, the ideological relationships among speakers providing Congressional testimony on the issue of climate change are mapped. For the first time, issue stances of actors are systematically aggregated in order to measure coalitions and consensus among political actors in American climate politics in a relational way. Our findings show how consensus formed around the economic implications of regulating greenhouse gases and the policy instrument that should do the regulating. The paper is separated into three sections. First, we review the ways scholars have looked at climate change policymaking in the United States, paying particular attention to those who have looked at the issue within the US Congress. Next, we present analysis of statements made during Congressional hearings on climate change over a four-year period. Our analysis demonstrates how a polarized ideological actor space in the 109th Congress transforms into a more consensual actor landscape in the 110th Congress, which is significantly less guided by partisan differences. This paper concludes by discussing how these findings help us understand shifting positions within American climate politics and the implications of these findings.  相似文献   
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Synchrotron‐based Fourier transform infrared spectroscopy and Raman spectroscopy are applied with submicrometer spatial resolution to multiple grains of Sutter's Mill meteorite, a regolith breccia with CM1 and CM2 lithologies. The Raman and infrared active functional groups reveal the nature and distribution of organic and mineral components and confirm that SM12 reached higher metamorphism temperatures than SM2. The spatial distributions of carbonates and organic matter are negatively correlated. The spatial distributions of aliphatic organic matter and OH relative to the distributions of silicates in SM2 differ from those in SM12, supporting a hypothesis that the parent body of Sutter's Mill is a combination of multiple bodies with different origins. The high aliphatic CH2/CH3 ratios determined from band intensities for SM2 and SM12 grains are similar to those of IDPs and less altered carbonaceous chondrites, and they are significantly higher than those in other CM chondrites and diffuse ISM objects.  相似文献   
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Exploring for groundwater in crystalline rocks in semiarid areas is a challenge because of their complex hydrogeology and low potential yields. An integrated approach was applied in central western Mozambique, in an area covered by Precambrian crystalline basement rocks. The approach combined a digital elevation model (DEM), remote sensing, and a ground-based geophysical survey. The aim was to identify groundwater zones with high potential and to identify geological structures controlling that potential. Lineaments were extracted from the DEM that had been enhanced using an adaptive-tilt, multi-directional, shading technique and a non-filtering technique to characterize the regional fracture system. The shallowness and amount of stored groundwater in the fracture zones was assessed using vegetation indices derived from Landsat 8 OLI images. Then, 14 transient electromagnetic (TEM) survey profiles were taken in different geological settings across continuous lineaments that were considered to be aligned along inferred faults. In the central lineament zones, the TEM soundings gave resistivity values of less than 300 Ωm at a depth of 20–80 m. The values varied with location. Conversely, values greater than 400 Ωm were observed at the sites away from the central zones. This contrast is probably caused by the differences in permeability and degree of weathering along the fractured zones. These differences could be key factors in determining groundwater occurrence. By integrating five water-related factors (lineament density, slope, geology, vegetation index, and proximity to lineaments), high groundwater potential zones were located in the vicinity of the lineaments. In these zones, vegetation remains active regardless of the season.  相似文献   
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