Double diffusive convection in a rotating system     

Akira Masuda 《Journal of Oceanography》1978,34(1):8-16

Linear instability theory of double diffusive convection is generalized to a rotating system. For sufficiently large rotation, rotation has a stabilizing effect, and viscosity stabilizes most of oscillatory modes but destabilizes direct modes. The following behavior is found in oscillatory modes in the case of destabilizing temperature distribution and stabilizing solute distribution. With the fixed destabilizing temperature distribution (1) the system is stable when the stabilizing solute gradient is large, (2) it becomes unstable with respect to oscillatory modes when the gradient is less than a certain value. (3) When the gradient is reduced further, the system becomes stable again. This anomalous phenomenon happens only when the Prandtle number is less than unity and larger than the ratio of the diffusivity of solute and that of temperature, under the existence of rotation.  相似文献   

A DETAILED CHEMICAL STUDY ON THE BARWISE CHONDRITE     

Noboru Nakamura  Akimasa Masuda 《Meteoritics & planetary science》1973,8(2):149-167

Six fragments of the Barwise meteorite were analyzed for REE and eleven other elements (Al, Ca, Mg, Mn, Na, K, Cr, Fe, Co, Ni and Ba). In addition, two fragments were analyzed for Si and Mg. The chondrite-normalized REE patterns of six fragments studied show interesting systematic variations. Three fragments with relatively high La abundances show a negative Ce anomaly. Since the meteorite in question is a find, it could be suspected that the observed REE fractionations are due to terrestrial contamination. To examine this point, a soil sample from the find site was also analyzed for REE and major chemical elements. It is considered that several facts, especially, the relationships between La and SiO₂ and between SiO₂ and MgO, suggest the pre-terrestrial fractionation rather than the terrestrial contamination. Unexpectedly, it is shown that the REE fractionation observed in the investigated fragments correlates with the metal-silicate and the Fe-Co-Ni fractionations. In this connection, large metal grains were investigated for Fe, Co and Ni contents. A suggestion is presented that this chondrite was formed through the melting of the surface of a planetesimal and the subsequent collision, although the possibility of terrestrial contamination might not be ruled out.  相似文献   

EXPERIMENTAL STUDIES ON BEHAVIORS OF MAJOR AND MINOR LITHOPHILE ELEMENTS IN VAPORIZATION UNDER EVACUATED CONDITION     

Akimasa Masuda  Tsuyoshi Tanaka 《Meteoritics & planetary science》1979,14(1):13-28

In order to investigate the volatilities of major and minor lithophile elements, evaporation experiments by electron bombardment were carried out employing basaltic rock powder. The elements studied included Al, Fe, Ca, Mg, Mn, Na, K, Rb, Ba and REE. The source crucible was heated to about 2300 °K, and the vaporized material was collected at different distances from the source. The enrichment factors of studied elements in the material collected on the condensation plate were calculated relative to the starting material. Patterns of REE removed during flights between varying distances were also evaluated.  相似文献   

An asteroseismic study of the β Cephei star 12 Lacertae: multisite spectroscopic observations, mode identification and seismic modelling     

M. Desmet  M. Briquet †  A. Thoul ‡  W. Zima  P. De Cat  G. Handler  I. Ilyin  E. Kambe  J. Krzesinski  H. Lehmann  S. Masuda  P. Mathias  D. E. Mkrtichian  J. Telting  K. Uytterhoeven  S. L. S. Yang  C. Aerts 《Monthly notices of the Royal Astronomical Society》2009,396(3):1460-1472

We present the results of a spectroscopic multisite campaign for the β Cephei star 12 (DD) Lacertae. Our study is based on more than thousand high-resolution high S/N spectra gathered with eight different telescopes in a time span of 11 months. In addition, we make use of numerous archival spectroscopic measurements. We confirm 10 independent frequencies recently discovered from photometry, as well as harmonics and combination frequencies. In particular, the slowly pulsating B-stars (SPB)-like g -mode with frequency 0.3428 d⁻¹ reported before is detected in our spectroscopy. We identify the four main modes as  (ℓ₁, m ₁) = (1, 1), (ℓ₂, m ₂) = (0, 0), (ℓ₃, m ₃) = (1, 0)  and  (ℓ₄, m ₄) = (2, 1)  for   f ₁= 5.178 964 d⁻¹, f ₂= 5.334 224 d⁻¹, f ₃= 5.066 316 d⁻¹  and   f ₄= 5.490 133 d⁻¹  , respectively. Our seismic modelling shows that f ₂ is likely the radial first overtone and that the core overshooting parameter  α_ov  is lower than 0.4 local pressure scale heights.  相似文献   

MOA-cam3: a wide-field mosaic CCD camera for a gravitational microlensing survey in New Zealand     

T. Sako  T. Sekiguchi  M. Sasaki  K. Okajima  F. Abe  I. A. Bond  J. B. Hearnshaw  Y. Itow  K. Kamiya  P. M. Kilmartin  K. Masuda  Y. Matsubara  Y. Muraki  N. J. Rattenbury  D. J. Sullivan  T. Sumi  P. Tristram  T. Yanagisawa  P. C. M. Yock 《Experimental Astronomy》2008,22(1-2):51-66

We have developed a wide-field mosaic CCD camera, MOA-cam3, mounted at the prime focus of the Microlensing Observations in Astrophysics (MOA) 1.8-m telescope. The camera consists of ten E2V CCD4482 chips, each having 2k×4k pixels, and covers a 2.2 deg² field of view with a single exposure. The optical system is well optimized to realize uniform image quality over this wide field. The chips are constantly cooled by a cryocooler at ??80° C, at which temperature dark current noise is negligible for a typical 1–3 min exposure. The CCD output charge is converted to a 16-bit digital signal by the GenIII system (Astronomical Research Cameras Inc.) and readout is within 25 s. Readout noise of 2–3 ADU (rms) is also negligible. We prepared a wide-band red filter for an effective microlensing survey and also Bessell V, I filters for standard astronomical studies. Microlensing studies have entered into a new era, which requires more statistics, and more rapid alerts to catch exotic light curves. Our new system is a powerful tool to realize both these requirements.  相似文献   

Iron–bentonite interactions in the Kawasaki bentonite deposit,Zao area,Japan     

Keisuke Fukushi  Tomonori Sugiura  Tomoaki Morishita  Yoshio Takahashi  Noriko Hasebe  Hiroshi Ito 《Applied Geochemistry》2010

Greenish veins occurring in brecciated bentonite were found in the Kawasaki bentonite deposit of the Zao region in Miyagi Prefecture, Japan. Their occurrence possibly indicates the interaction of bentonite with Fe-rich hydrothermal solutions. In order to prove the hypothesis and understand the long-term mineralogical and petrographic evolution of bentonite during such interactions, the greenish veins and the surrounding altered bentonite were analyzed using X-ray fluorescence (XRF), scanning electron microscopy (SEM), X-ray diffraction (XRD), electron probe micro-analysis (EPMA), scanning transmission electron microscopy with energy dispersed spectroscopy (STEM-EDS) and micro X-ray absorption near-edge structure (XANES). The greenish veins resulting from hydrothermal solution are composed of mixed-layer minerals consisting of smectite and glauconite (glaucony), pyrite and opal. The occurrences indicate that glaucony and pyrite formed almost simultaneously from hydrothermal solution prior to opal precipitation. The mineral assemblages of the greenish veins and their surroundings indicate that the hydrothermal activity had most likely taken place at a temperature of less than 100 °C and that the pH and Eh conditions of the reacted solution were neutral to alkaline pH and reducing. The unaltered bentonite is composed mainly of Al smectite and opal. These minerals coexist as a mixture within the resolution level of the microprobe analyses. On the other hand, the bentonite in contact with the greenish veins consists of discrete opal grains and dioctahedral Al smectite containing Fe and was altered mineralogically and petrographically by the hydrothermal activity. Both the clay minerals and the opal were formed by dissolution and subsequent precipitation from the interaction of the original bentonite with the hydrothermal solution.  相似文献   

EXAFS study on the cause of enrichment of heavy REEs on bacterial cell surfaces     

Yoshio Takahashi  Mika Yamamoto  Kazuya Tanaka 《Geochimica et cosmochimica acta》2010,74(19):5443-5796

Rare earth element (REE) pattern is a unique geochemical tracer and has been measured for various natural materials. Among these, the REE distribution pattern between bacteria and water exhibits anomalous enrichment in the heavy REE (HREE) part, which can act as a signature of bacteria-related materials in natural samples. In this study, the REE binding site on the cell surface of a Gram-positive bacterium (Bacillus subtilis) responsible for HREE enrichment has been identified using extended X-ray absorption fine structure (EXAFS) coupled with a study of the variation in REE distribution patterns. The EXAFS data showed that the HREEs form complexes with multiple phosphate site (including phosphoester site) with a larger coordination number (CN) at lower REE-bacteria ratios ([REE]/[bac]), while light and middle REEs form complexes to the phosphate site with a lower CN. The fraction coordinated to carboxylate increased for all REEs with increasing [REE]/[bac] ratio. On the other hand, the enrichment of HREE in the REE distribution patterns of the bacteria was less marked with increasing [REE]/[bac] ratio. This result is consistent with the EXAFS data, because the REE pattern of surface complex with multiple phosphate in a reference material exhibits a monotonous increase for heavier REE, while phosphate surface complex with a low CN and a carboxylate site reach a maximum around Sm and Eu. Based on these results, it is clear that the REE are primarily bound to the phosphate site and subsequently to the carboxylate site on the bacterial cell surface.Regarding the pH dependence in the range (3 < pH < 7), both the EXAFS and REE pattern data indicate that the fraction of REE-carboxylate increased as the pH increases. The results above obtained for B. subtilis were also valid for Escherichia coli, a Gram-negative bacterium, showing that similar phosphate and carboxylate sites are also available in the cell walls of E. coli, or other Gram negative bacteria. In all our results, the variation in REE patterns correlated with the binding site indicated by EXAFS, showing that the REE pattern itself reflects the binding site of the REE at the bacterial surface for various parameters (pH and [REE]/[bac] ratio). Thus, the REE patterns can be used to estimate the binding sites for lower [REE]/[bac] ratios where spectroscopic techniques cannot be applied.The average bond length between the REE and oxygen was compared for various REE sorbed on bacteria, showing that the bond length for HREE (Er to Lu) was much shorter than those extrapolated from the trend between La and Dy, because of the selective binding of the HREE as the multiple phosphate surface complexes. Our results are consistent with the selective enrichment of the HREE at the bacterial cell surfaces, considering that chemical species with a shorter bond length are more stable. Thus, it is clear that the HREE enrichment at the bacterial cell surfaces is caused by the formation of the multiple phosphate surface complexes. Based on these results, it is suggested that materials having such phosphate sites such as bacteria and bacteria-related materials can induce anomalous HREE enrichment in natural systems.  相似文献   

Occurrence of arsenic (V) in forearc mantle serpentinites based on X-ray absorption spectroscopy study     

Keiko Hattori  Yoshio Takahashi  Bo Johanson 《Geochimica et cosmochimica acta》2005,69(23):5585-5596

We examined As concentration, mineralogical site, and oxidation state in the serpentinites associated with the Tso Morari eclogitic rocks in the Indus suture zone, northwest Himalaya, to examine how highly fluid-soluble elements like As are transferred from slabs to arc magmas in subduction zones. The serpentinite samples represent hydrated peridotites at the base of the mantle wedge beneath Eurasia, and were exhumed from a depth of ∼100 km during subduction of the Indian continental margin. The bulk serpentinite samples contain total As concentrations ranging from 6 to 275 ppm. Arsenic in the samples is most likely present with magnetite and antigorite, since electron probe analysis yielded up to 90 ppm As in these minerals. X-ray absorption near-edge structure spectra indicate that As in serpentinites is mostly As(V) and that the neighboring atoms of As are O, although there are minute grains of sulfides and arsenides. The ratio of As(V) to total As is greater in samples with higher As contents, suggesting that the major source of As was oxidized As(V), introduced to the mantle wedge. Arsenic(V), originally adsorbed on Fe-oxides in slabs and overlying sediments, was most likely liberated during their subduction and incorporated subsequently in the overlying mantle wedge. Our data constrain the introduction of As into the mantle wedge at relatively shallow levels, much shallower than 25 km. Arsenic incorporated in the serpentinites was transported to deeper levels by mantle flow downward along the subduction zone, to be subsequently exhumed together with eclogitic rocks.  相似文献   

Scattering attenuation, dispersion and reflection of SH waves in two-dimensional elastic media with densely distributed cracks     

Yoshio Murai 《Geophysical Journal International》2007,168(1):211-223

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An atomic level study of rhenium and radiogenic osmium in molybdenite   总被引：1，自引：0，他引：1  

Yoshio Takahashi  Tomoya Uruga  Hajime Tanida  Keiko H. Hattori 《Geochimica et cosmochimica acta》2007,71(21):5180-5190

Local atomic structures of Re and radiogenic Os in molybdenite from the Onganja mine, Namibia, were examined using X-ray absorption fine structure (XAFS). Rhenium L_III-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) show that the oxidation state of Re, the interatomic distances between Re and the neighboring atoms, and the coordination number of Re to S are very similar to those of Mo in molybdenite. The results confirm that Re is present as Re(IV) in the Mo site in molybdenite.Measurement of L_III-edge XANES and EXAFS of a minor concentration (8.55 ppm) of radiogenic Os was accomplished in fluorescence mode by removing the interfering X-rays from Re and other elements using a crystal analyzer system. The data indicate that the oxidation state of radiogenic Os is Os(III) and Os(IV) and clearly different from Os(II) in natural sulfide minerals, such as OsS₂ (erlichmanite). XANES data also suggest that radiogenic Os does not form a secondary Os phase, such as OsS₂ or Os metal, in molybdenite.EXAFS of radiogenic Os was successfully simulated assuming that Os is present in the Mo site in molybdenite. The data are consistent with the XANES data; Os does not form Os phases in molybdenite. The EXAFS simulation showed that the interatomic distance between Os and S is 2.27 Å, which is 0.12 Å smaller than the distances of Re-S and Mo-S (2.39 Å) in molybdenite. Similar valences and ionic sizes of Re and Mo in molybdenite support the fact that large amounts of Re can be incorporated into the Mo site as has been observed in previous studies, whereas the different properties of Os compared to Mo and Re suggested here support much lower abundance of common Os in molybdenite. This makes molybdenite an ideal mineral for the Re-Os geochronometer as shown in many studies. However, the shorter distance between radiogenic Os and S compared to those of Re-S and Mo-S in molybdenite suggests that the radiogenic Os has a smaller ionic size than Re(IV) and Mo(IV). Furthermore, Os may be partly present as Os(III). Smaller and lower charge Os can diffuse faster than larger and higher charge Re in molybdenite at a given set of conditions. Hence, our study provides an atomic-level explanation for the high mobility of Os compared to Re, which has been suggested by earlier workers using laser ablation ICP-MS.  相似文献