Trace element concentrations in the isotopically unique Allende inclusion,EK 1-4-1     

Hiroshi Nagasawa  Douglas P. Blanchard  Hiroshi Shimizu  Akimasa Masuda 《Geochimica et cosmochimica acta》1982,46(9):1669-1673

Concentrations of rare-earth elements (REE), Sc, Fe, Co, Cr, Na and Ir in the bulk sample and mineral separates of the isotopically unique Allende inclusion, EK 1-4-1, were determined by instrumental neutron activation analysis. REE concentrations were also determined by mass-spectrometric isotope dilution for two density separates.The inclusion showed enrichment of light REE over heavy REE with a positive Yb anomaly, thus showing a tendency to resemble group II fine-grained inclusions in REE abundances, although EK 1-4-1 is a coarse-grained inclusion. High Cr concentrations also indicate group II affinity. However, high Ir (6 ppm) and Sc (105 ppm), and low FeO (1.80%), and Co (13.8 ppm) concentrations in the bulk sample and low Na concentrations in mineral separates show group I affinity.Between melilite and pyroxene fractions, the same samples in which mass-fractionated O isotope ratios were observed (Clayton and Mayeda, 1977), REE, Sc, Co and Fe showed distributions which are substantially different from those observed for “ordinary” Allende type B inclusions. These two minerals do not appear to be in equilibrium with respect to trace element distributions.The results indicate that the isotopically unique EK 1-4-1 is also unusual in its elemental abundances and distributions.  相似文献   

Comparison of reductive accumulation of Re and Os in seawater-sediment systems   总被引：2，自引：0，他引：2  

Yoshiro Yamashita  Hiromitsu Haba  Hiroshi Shimizu 《Geochimica et cosmochimica acta》2007,71(14):3458-3475

In order to understand the fractionation of Re and Os in marine environments, their removal from artificial seawater to Tokyo Bay sediments is studied using a multitracer technique. The chemical processes of the removal of Re and Os are also estimated based on their speciation analyses by X-ray absorption fine structure (XAFS) spectroscopy. The partitioning experiments, which use the multitracer technique, provide information on Re and Os regarding (i) their distributions between artificial seawater-sediment systems, (ii) their complexation with humic acid, and (iii) their carriers in sediments. In addition, XAFS spectroscopy provides direct information on the chemical states of Re and Os in the sediments.In an artificial seawater-sediment system containing a multitracer, Re is removed from the artificial seawater only under a reducing environment. The speciation of Re by X-ray absorption near-edge structure (XANES) suggests that the majority of Re remains as in the artificial seawater even under highly reducing conditions, during laboratory time scale (about 2 weeks). Moreover, XANES simulation shows that some Re exists at a lower oxidation state, such as ReO₂, in the reducing sediment. These results can be explained by the slow kinetics of the reaction which is similar to those suggested by previous geochemical studies.In contrast, Os is readily removed from the artificial seawater into sediments under various redox conditions. Even under oxic conditions, a large fraction of Os is removed from the artificial seawater to sediments without organic matter. Based on the Os XANES study, it is confirmed that the oxidation states of Os incorporated in the reducing sediment and oxic sediment are trivalent and tetravalent, respectively. Sequential extraction suggests that the main carrier of Os in the organic-rich sediment is either ferromanganese oxides or organic matter, and that the Os in these two fractions may correspond to hydrolyzed insoluble Os species and Os species interacting with organic matter, at lower valence, respectively. The results of distribution study of Os in the absence and presence of humic acid (HA) also imply that Os assumes more than one chemical species, and a small fraction of Os may interact with HA in the experimental system. Meanwhile, extended X-ray absorption fine structure (EXAFS) confirms that the first neighboring atom of Os in the reducing sediment is oxygen. If Os(VIII) is the main dissolved species in seawater, as is expected thermodynamically, reductive removal may control the enrichment of Os in the sediment. Osmium, which is removed as Os(IV), is reduced further to Os(III) by a diagenetic process and may be complexed with organic matter in the reducing sediment.The results of the removal behaviors of Re and Os obtained in the current study show that Re can be removed from the artificial seawater only under highly reducing conditions within 2 weeks, but Os removal from the artificial seawater can be found under various redox conditions. Thus, a high ¹⁸⁷Re/¹⁸⁸Os ratio can occur only in reducing sediments, such as black shales. The high¹⁸⁷Re/¹⁸⁸Os ratio, in turn, makes black shales suitable for Re-Os dating. In contrast, authigenic sediments (and minerals) under oxic environments can enrich Os, but since Re is not distributed to the sediments under oxic conditions, this will cause a much lower ¹⁸⁷Re/¹⁸⁸Os ratio than that of seawater. The Os isotope system of these materials can be used as a paleo-marine environmental tracer since the ¹⁸⁷Os/¹⁸⁸Os ratio cannot grow significantly due to its extremely low ¹⁸⁷Re/¹⁸⁸Os ratio.  相似文献   

Overview of the 1990–1995 eruption at Unzen Volcano     

Setsuya Nakada  Hiroshi Shimizu  Kazuya Ohta 《Journal of Volcanology and Geothermal Research》1999,89(1-4)

Following 198 years of dormancy, a small phreatic eruption started at the summit of Unzen Volcano (Mt. Fugen) in November 1990. A swarm of volcano-tectonic (VT) earthquakes had begun below the western flank of the volcano a year before this eruption, and isolated tremor occurred below the summit shortly before it. The focus of VT events had migrated eastward to the summit and became shallower. Following a period of phreatic activity, phreatomagmatic eruptions began in February 1991, became larger with time, and developed into a dacite dome eruption in May 1991 that lasted approximately 4 years. The emergence of the dome followed inflation, demagnetization and a swarm of high-frequency (HF) earthquakes in the crater area. After the dome appeared, activity of the VT earthquakes and the summit HF events was replaced largely by low-frequency (LF) earthquakes. Magma was discharged nearly continuously through the period of dome growth, and the rate decreased roughly with time. The lava dome grew in an unstable form on the shoulder of Mt. Fugen, with repeating partial collapses. The growth was exogenous when the lava effusion rate was high, and endogenous when low. A total of 13 lobes grew as a result of exogenous growth. Vigorous swarms of LF earthquakes occurred just prior to each lobe extrusion. Endogenous growth was accompanied by strong deformation of the crater floor and HF and LF earthquakes. By repeated exogenous and endogenous growth, a large dome was formed over the crater. Pyroclastic flows frequently descended to the northeast, east, and southeast, and their deposits extensively covered the eastern slope and flank of Mt. Fugen. Major pyroclastic flows took place when the lava effusion rate was high. Small vulcanian explosions were limited in the initial stage of dome growth. One of them occurred following collapse of the dome. The total volume of magma erupted was 2.1×10⁸ m³ (dense-rock-equivalent); about a half of this volume remained as a lava dome at the summit (1.2 km long, 0.8 km wide and 230–540 m high). The eruption finished with extrusion of a spine at the endogenous dome top. Several monitoring results convinced us that the eruption had come to an end: the minimal levels of both seismicity and rockfalls, no discharge of magma, the minimal SO₂ flux, and cessation of subsidence of the western flank of the volcano. The dome started slow deformation and cooling after the halt of magma effusion in February 1995.  相似文献   

A general Lagrangian tracking methodology for riverine flow and transport     

Jonathan Nelson  Yasuyuki Shimizu  Tomoko Kyuka  Scott Charlton 《地球表面变化过程与地形》2023,48(1):87-103

This article presents a new public domain tool for generalized Lagrangian particle tracking in rivers. The approach can be applied with a variety of two- and three-dimensional flow solvers. Particle advection by the flow is incorporated using flow fields from the chosen solver assuming particles follow the Reynolds-averaged flow, although some other simple passive and active particle behaviors are also treated. Turbulence effects are treated using a random walk algorithm with spatial step lengths randomly chosen from Gaussian distributions characterized by the diffusivity from the flow solver. Our work extends this concept to a general framework that is solver and coordinate system independent to allow easy comparisons between differing flow treatments. To better treat problems where detailed information is required in specific regions, the approach includes novel cloning and colligation algorithms which enhance local resolution at modest computational expense. We also provide tools for computing local concentrations and total exposure over a user-specified time interval. Several examples of predictions are provided to illustrate applications of the technique, including examination of the role of curvature-driven secondary flows, storage in lateral separation eddies, treatment of larval drift, treatment of fuel spill dispersion, river-floodplain connections, and sedimentation in floodplain ponds by tie channel connections. We also demonstrate that the model can reproduce analytically derived concentration profiles for simple diffusivities. These examples show that the Lagrangian particle tracking approach and the extensions proposed here are broadly applicable and viable for treating difficult river problems with multiple temporal and spatial scales. The examples also illustrate the utility of the cloning/colligation extensions and show how these can decrease the computational effort required on problems where high local resolution is required. Enhancement of the tools and even broader applicability can be achieved through the inclusion of multiple particle populations and particle–particle interactions.  相似文献