Petrogenesis of the Dar al Gani (DaG) 1.1 Ma ejection-paired olivine-phyric shergottites and implications for ~470 Ma Martian volcanism     

Tarryn Aucamp  Geoffrey H. Howarth  Chad J. Peel  Gelu Costin  James M. D. Day  Petrus le Roux  James M. Scott  Ansgar Greshake  Rainer Bartoschewitz 《Meteoritics & planetary science》2023,58(11):1654-1676

The Dar al Gani (DaG) olivine-phyric shergottites share mineralogical and geochemical characteristics, which confirm that these meteorites are derived from a single source. Bulk trace elements (La/Yb—0.12), in situ maskelynite ⁸⁷Sr/⁸⁶Sr (~0.7014) and redox estimates (FMQ ~ −2) indicate derivation from a depleted, reduced mantle reservoir; identical to all ~470 Ma shergottites ejected at 1.1 Ma. The DaG shergottites have been variably affected by terrestrial alteration, which precipitated carbonate along fractures and modified bulk-rock fluid mobile (e.g., Ba) elements. Nonetheless, sufficient data are available to construct a multi-stage formation model for the DaG shergottites and other 1.1 Ma ejection-paired shergottites that erupted at ~470 Ma. First, partial melting of a depleted mantle source occurred at 1540 ± 20°C and 1.2 ± 0.1 GPa, equivalent to > ~100 km depth. Then, initial crystallization in a staging chamber at ~85 km depth at the crust–mantle boundary took place, followed by magma evolution and variable incorporation of antecrystic olivine ± orthopyroxene. Subsequently, crystallization of olivine phenocrysts and re-equilibration of olivine antecrysts occurred within an ascending magma. Finally, magmas with variable crystal loads erupted at the surface, where varied cooling rates produced a range of groundmass textures. This model is similar to picritic flood basalt magmas erupted on Earth.  相似文献   

A reappraisal of the metamorphic history of EH3 and EL3 enstatite chondrites     

Eric Quirico  Michèle Bourot-denise  Gilles Montagnac 《Geochimica et cosmochimica acta》2011,75(11):3088-3102

The thermal history of a series of EH3 and EL3 chondrites has been investigated by studying the degree of structural order of the organic matter (OM) located and characterized in matrix areas by Raman micro-spectroscopy. By comparison with unequilibrated ordinary chondrites (UOCs) and CO and CV carbonaceous chondrites, the following petrologic types have been assigned to various E chondrites: Sahara 97096 and Allan Hills 84206: 3.1-3.4; Allan Hills 85170 and Parsa: 3.5; Allan Hills 85119: 3.7; Qingzhen, MacAlpine Hills 88136 and MacAlpine Hills 88184: 3.6-3.7. The petrologic type of Qingzhen is consistent with the abundance of the P3 noble gas component, a sensitive tracer of the grade of thermal metamorphism. The petrologic types are qualitatively consistent with the abundance of fine-grained matrix for the whole series. No significant effects of shock processes on the structure of OM were observed. However such processes certainly compete with thermal metamorphism and the possibility of an effect cannot be fully discarded, in particular in the less metamorphosed objects. The OM precursors accreted by the EH3 and EL3 parent bodies appear to be fairly similar to those of UOCs and CO and CV carbonaceous chondrites. Raman data however show some slight structural differences that could be partly accounted for by shock processes. The metamorphic history of EH3 and EL3 chondrites has often been described as complex, in particular regarding the combined action of shock and thermal metamorphism. Because OM maturity is mostly controlled by the temperature of peak metamorphism, it is possible to distinguish between the contributions of long duration thermal processes and that of shock processes. Comparison of the petrologic types with the closure temperatures previously derived from opaque mineral assemblages has revealed that the thermal history of EH3 and EL3 chondrites is consistent with a simple asteroidal onion shell model. Thermal metamorphism in enstatite chondrites appears to be fairly similar to that which takes place in other chondrite classes. The complex features recorded by mineralogy and petrology and widely reported in the literature appear to be mostly controlled by shock processes.  相似文献   

Sources of fluids and gases expelled at cold seeps offshore Georgia, eastern Black Sea   总被引：1，自引：0，他引：1  

Anja Reitz  Thomas Pape  Mark Schmidt  Florian Scholz  Giovanni Aloisi  Stephan M. Weise 《Geochimica et cosmochimica acta》2011,75(11):3250-46

Four seep sites located within an ∼20 km² area offshore Georgia (Batumi seep area, Pechori Mound, Iberia Mound, and Colkheti Seep) show characteristic differences with respect to element concentrations, and oxygen, hydrogen, strontium, and chlorine isotope signatures in pore waters, as well as impregnation of sediments with petroleum and hydrocarbon potential. All seep sites have active gas seepage, near surface authigenic carbonates and gas hydrates. Cokheti Seep, Iberia Mound, and Pechori Mound are characterized by oil-stained sediments and gas seepage decoupled from deep fluid advection and bottom water intrusion induced by gas bubble release. Pechori Mound is further characterized by deep fluid advection of lower salinity pore fluids. The Pechori Mound pore fluids are altered by mineral/water reactions at elevated temperatures (between 60 and 110 °C) indicated by heavier oxygen and lighter chlorine isotope values, distinct Li and B enrichment, and K depletion. Strontium isotope ratios indicate that fluids originate from late Oligocene strata. This finding is supported by the occurrence of hydrocarbon impregnations within the sediments. Furthermore, light hydrocarbons and high molecular weight impregnates indicate a predominant thermogenic origin for the gas and oil at Pechori Mound, Iberia Mound, and Colkheti Seep. C₁₅₊ hydrocarbons at the oil seeps are allochtonous, whereas those at the Batumi seep area are autochthonous. The presence of oleanane, an angiosperm biomarker, suggests that the hydrocarbon source rocks belong to the Maikopian Formation. In summary, all investigated seep sites show a high hydrocarbon potential and hydrocarbons of Iberia Mound, Colkheti Seep, and Pechori Mound are predominantly of thermogenic origin. However, only at the latter seep site advection of deep pore fluids is indicated.  相似文献   

Magnetic classification of stony meteorites: 1. Ordinary chondrites     

Pierre ROCHETTE  Leonardo SAGNOTTI  Michle BOUROT‐DENISE  Guy CONSOLMAGNO  Luigi FOLCO  Jrme GATTACCECA  Maria Luisa OSETE  Lauri PESONEN 《Meteoritics & planetary science》2003,38(2):251-268

Abstract— We present a database of magnetic susceptibility measurements on 971 ordinary chondrites. It demonstrates that this parameter can be successfully used to characterize and classify ordinary chondrite meteorites. In ordinary chondrites, this rapid and non‐destructive measurement essentially determines the amount of metal in the sample, which occurs in a very narrow range for each chondrite class (though terrestrial weathering can result in a variable decrease in susceptibility, especially in finds). This technique is particularly useful not only for a rapid classification of new meteorites, but also as a check against curation errors in large collections (i.e., unweathered meteorites, the measured susceptibility of which lies outside the expected range, may well be misclassified or misidentified samples). Magnetic remanence, related to magnetic field measurements around asteroids, is also discussed.  相似文献   

New OSL dating of UK loess: indications of two phases of Late Glacial dust accretion in SE England and climate implications     

Michèle L. Clarke  Antoni E. Milodowski  Jon E. Bouch  Melanie J. Leng  Kevin J. Northmore 《第四纪科学杂志》2007,22(4):361-371

Windblown dust deposits or loess, locally known in the UK as brickearth, blanket many parts of southern England outside the limits of the British and Irish Ice Sheet. The best‐studied loess exposures occur in Kent, southeast England, where the deposits are believed to be Late Glacial in age. New sedimentological evidence is presented for phases of accretion with two distinct units, a calcareous brickearth exhibiting periglacial cryoturbation and a non‐calcareous, massive brickearth. Optically stimulated luminescence (OSL) dating has been applied to chemically isolated modal quartz silts to derive a chronology for sediment accretion and to better understand the palaeoclimatic significance of these deposits. © British Geological Survey/Natural Environment Research Council copyright 2007. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.  相似文献   

Organic matter and metamorphic history of CO chondrites     

Lydie Bonal  Michèle Bourot-Denise  Gilles Montagnac 《Geochimica et cosmochimica acta》2007,71(6):1605-1623

The metamorphic grades of a series of eight CO3 chondrites (ALHA77307, Colony, Kainsaz, Felix, Lancé, Ornans, Warrenton and Isna) have been quantified. The method used was based on the structural grade of the organic matter trapped in the matrix, which is irreversibly transformed by thermal metamorphism. The maturation of the organic matter is independent with respect to the mineralogical context and aqueous alteration. This metamorphic tracer is thus valid whatever the chemical class of chondrites. Moreover, it is sensitive to the peak metamorphic temperature.The structural grade of the organic matter was used along with other metamorphic tracers such as petrography of opaque minerals, Fa and Fs silicate composition in type I chondrules, presolar grains and noble gas (P3 component) abundance. The deduced metamorphic hierarchy and the attributed petrographic types are the following: ALHA77307 (3.03) < Colony (3.1) < Kainsaz (3.6) < Felix (3.6 (1)) < Ornans (3.6 (2)) < Lancé (3.6 (3)) < Warrenton (3.7 (1)) < Isna (3.7 (2)).For most metamorphosed objects, the peak metamorphic temperature can be estimated using a geothermometer calibrated with terrestrial metasediments [Beyssac O., Goffe B., Chopin C., and Rouzaud J. N. (2002) Raman spectrum of carbonaceous material in metasediments: a new geothermometer. J. Metamorph. Geol., 20, 859-871]. A value of 330 °C was obtained for Allende (CV chondrite), Warrenton and Isna, consistent with temperatures estimated from Fe diffusion [Weinbruch S., Armstrong J., and Palme H. (1994). Constraints on the thermal history of the Allende parent body as derive from olivine-spinel thermometry and Fe/Mg interdiffusion in olivine. Geochim. Cosmochim. Acta58(2), 1019-1030.], from the Ni content in sulfide-metal assemblages [Zanda B., Bourot-Denise M., and Hewins R. (1995) Condensate sulfide and its metamorphic transformations in primitive chondrites. Meteorit. Planet. Sci.30, A605.] and from the d₀₀₂ interlayer spacing in poorly graphitized carbon [Rietmeijer, F., and MacKinnon, I. (1985) Poorly graphitized carbon as a new cosmothermometer for primitive extraterrestrial materials. Nature, 315, 733-736]. The trapped noble gas and C content appear to be sensitive but not precise metamorphic tracers, indicating that the “Ornans paradox” does not exist. Major problems with the current petrologic types derived from Induced ThermoLuminescence are pointed out.  相似文献   

Metasomatism of the Pan-African lithospheric mantle beneath the Damara Belt,Namibia, by the Tristan mantle plume: geochemical evidence from mantle xenoliths     

Anton?le?RoexEmail author  Cornelia?Class 《Contributions to Mineralogy and Petrology》2014,168(2):1046

In situ trace element analyses of constituent minerals in mantle xenoliths occurring in an alnöite diatreme and in nephelinite plugs emplaced within the central zone of the Damara Belt have been determined by laser ablation ICP-MS. Primitive mantle-normalized trace element patterns of clinopyroxene and amphibole indicate the presence of both depleted MORB-like mantle and variably enriched mantle beneath this region. Clinopyroxenes showing geochemical depletion have low La/Sm_n ratios (0.02–0.2), whereas those showing variable enrichment have La/Sm_n ranging up to 3.8 and La/Yb_n to 9.1. The most enriched clinopyroxenes coexist with amphibole showing similar REE patterns (La/Sm_n = 1.3–4.1; La/Yb_n = 4.5–9). Primitive mantle-normalized trace element patterns allow further groups to be distinguished amongst the variably enriched clinopyroxenes: one having strong relative depletion in Rb–Ba, Ta–Nb and relative enrichment in Th–U; another with similar characteristics but with additional strong relative depletion in Zr–Hf; and one showing no significant anomalies. Amphiboles show similar normalized trace element patterns to co-existing clinopyroxene. Clinopyroxene and amphiboles showing LREE_N enrichment have high Sr and low Nd isotope ratios compared to clinopyroxene with LREE-depleted patterns. Numerical simulation of melt percolation through the mantle via reactive porous flow is used to show that the chromatographic affect associated with such a melt migration process is able to account for the fractionation seen in La–Ce–Nd in cryptically metasomatized clinopyroxenes in Type 1 xenoliths, where melt–matrix interactions occur near the percolation front, whereas REE patterns in clinopyroxenes proximal to the source of metasomatic melt/fluid match those found in modally metasomatized Type 2 xenoliths. The strong fractionation between Rb–Ba, Th–U and Ta–Nb shown by some cryptically metasomatized xenoliths can be also accounted for by reactive porous flow, provided amphibole crystallizes from the percolating melt/fluid close to its source. The presence of amphibole in vein-like structures in some xenoliths is consistent with this interpretation. The strong depletion in Zr–Hf in clinopyroxene and amphibole in some xenoliths cannot be accounted for by melt migration processes and requires metasomatism by a separate carbonate-rich melt/fluid. When taken together with published isotope data on these same xenoliths, the source of metasomatic enrichment of the previously depleted (MORB-like) sub-Damaran lithospheric mantle is attributed to the upwelling Tristan plume head at the time of continental breakup.  相似文献   

A mineralogical and geochemical study of polymict eucrite discovered in Sahara of southwest Algeria     

Abdelmadjid Seddiki  Bertrand Moine  Jean Yves Cottin  Jérôme Bascou  Marguerite Godard  François Faure  Michèle Bourot-Denise  Nacera Remaci 《Arabian Journal of Geosciences》2013,6(9):3175-3184

NWA2268 is a polymict eucrite discovered in the Sahara, at southwest Algeria, close to the region of Tindouf. This meteorite weighs 65 g and presents a thin black fusion crust. The rock is fine- to medium-grained breccia and contains mineral fragments of plagioclases, pyroxenes, spinel, olivine and silica. The rock contains some basaltic fragments with sub-ophitic or cumulative textures, constituted by plagioclases and exsolved pigeonite. Pyroxferroite grains are present and locally destabilised in an association of hedenbergite, fayalite and silica. It also presents unequilibrated eucritic clast with heterogeneous pyroxenes and plagioclases compositions. Pyroxenes in the all of the other clasts have equilibrated composition, with exolved pigeonites with augite lamellaes. This polymict eucrite contains also partially devitrified glass that represents impact melts linked to impact event. None recrystallization of this glass confirms a lack of post-brecciation metamorphism. Diogenitic fragments are less abundant than 10 %. The oxygen isotopic composition of NWA2268 is Δ¹⁷O (?0.43). This meteorite is interpreted as belonging to the HED group attributed to the 4-Vesta asteroid.  相似文献   

A methodological approach of fluvial dynamics oriented towards hydrosystem management: case study of the Loire and Allier rivers     

Emmanuèle Gautier  Hervé Piégay  Patrick Bertaina 《Geodinamica Acta》2013,26(1):29-43

Abstract

This study was conducted as part of the European LIFE Loire Nature program for the conservation and management of a 110-km-long section of the Loire and Allier rivers, an area renowned for its ecological richness. The methodological approach is based on statistical analysis (bivariate and multivariate analyses) of hydro-geomorphologic and biogeographical variables, complemented by reach typology and mapping. The main results show, on the one hand, the great spatial variability of fluvial mosaic complexity along the river continuum and on the other hand, some independence between the riparian forest characteristics and the channel forms. The fluvial pattern (e.g. anabranching) and the forest establishment along the Loire river register specific features. © 2000 Éditions scientifiques et médicales Elsevier SAS  相似文献   

双重介质水平井产量递减分析方法     

罗二辉  胡永乐  王磊  曹晨 《现代地质》2013,27(6):1440

水平井开发特殊类型油气藏有其独到优势,针对双重孔隙介质水平井复杂渗流,以Warren-Root双重介质模型为基础,建立了水平井三维不稳定渗流模型,采用Laplace变换、有限Fourier余弦变换及叠加积分等方法对模型进行求解,获得定产条件下无量纲井底压力解,再利用Duhamel褶积原理将定产条件压力解变换为井底定压条件下的产量解;通过重新定义无量纲量建立McCray型产量积分平均递减方程,结合Stehfest数值反演,获得无量纲产量积分平均递减曲线及其导数曲线图版。计算结果表明,产量积分平均导数曲线上出现双重介质特有的“凹子”, 应用该类图版拟合生产数据可方便进行产量预测及储层动态参数求取。  相似文献