Silicon and iron isotopes in components of enstatite chondrites: Implications for metal–silicate–sulfide fractionation in the solar nebula     

Jinia Sikdar  Harry Becker  Jan A. Schuessler 《Meteoritics & planetary science》2023,58(7):978-1001

Silicon and iron isotope compositions of different physically separated components of enstatite chondrites (EC) were determined in this study to understand the role of nebular and planetary scale events in fractionating Si and Fe isotopes of the terrestrial planet-forming region. We found that the metal–sulfide nodules of EC are strongly enriched in light Si isotopes (δ³⁰Si ≥ −5.61 ± 0.12‰, 2SD), whereas the δ³⁰Si values of angular metal grains, magnetic, slightly magnetic, and non-magnetic fractions become progressively heavier, correlating with their Mg# (Mg/(Mg+Fe)). White mineral phases, composed primarily of SiO₂ polymorphs, display the heaviest δ³⁰Si of up to +0.23 ± 0.10‰. The data indicate a key role of metal–silicate partitioning on the Si isotope composition of EC. The overall lighter δ³⁰Si of bulk EC compared to other planetary materials can be explained by the enrichment of light Si isotopes in EC metals along with the loss of isotopically heavier forsterite-rich silicates from the EC-forming region. In contrast to the large Si isotope heterogeneity, the average Fe isotope composition (δ⁵⁶Fe) of EC components was found to vary from −0.30 ± 0.08‰ to +0.20 ± 0.04‰. A positive correlation between δ⁵⁶Fe and Ni/S in the components suggests that the metals are enriched in heavy Fe isotopes whereas sulfides are the principal hosts of light Fe isotopes in the non-magnetic fractions of EC. Our combined Si and Fe isotope data in different EC components reflect an inverse correlation between δ³⁰Si and δ⁵⁶Fe, which illustrates that partitioning of Si and Fe among metal, silicate, and sulfidic phases has significantly fractionated Si and Fe isotopes under reduced conditions. Such isotope partitioning must have occurred before the diverse components were mixed to form the EC parent body. Evaluation of diffusion coefficients of Si and Fe in the metal and non-metallic phases suggests that the Si isotope compositions of the silicate fractions of EC largely preserve information of their nebular processing. On the other hand, the Fe isotopes might have undergone partial or complete re-equilibration during parent body metamorphism. The relatively uniform δ⁵⁶Fe among different types of bulk chondrites and the Earth, despite Fe isotope differences among their components, demonstrates that the chondrite parent bodies were not formed by random mixing of chondritic components from different locations in the disk. Instead, the chondrite components mostly originated in the same nebular reservoir and Si and Fe isotopes were fractionated either due to gas–solid interactions and associated changes in physicochemical environment of the nebular reservoir and/or during parent body processing. The heavier Si isotope composition of the bulk silicate Earth may require accretion of chondritic and/or isotopically heavier EC silicates along with cumulation of refractory forsterite-rich heavier silicates lost from the EC-forming region to form the silicate reservoir of the Earth.  相似文献   

Chronology of latest Pleistocene mountain glaciation in the western Wasatch Mountains, Utah, U.S.A.     

Benjamin J.C. Laabs  David W. Marchetti  Jeffrey S. Munroe  Kurt A. Refsnider  John C. Gosse  Elliott W. Lips  Richard A. Becker  David M. Mickelson  Brad S. Singer 《Quaternary Research》2011,76(2):272-284

Understanding the timing of mountain glacier and paleolake expansion and retraction in the Great Basin region of the western United States has important implications for regional-scale climate change during the last Pleistocene glaciation. The relative timing of mountain glacier maxima and the well-studied Lake Bonneville highstand has been unclear, however, owing to poor chronological limits on glacial deposits. Here, this problem is addressed by applying terrestrial cosmogenic ¹⁰Be exposure dating to a classic set of terminal moraines in Little Cottonwood and American Fork Canyons in the western Wasatch Mountains. The exposure ages indicate that the main phase of deglaciation began at 15.7 ± 1.3 ka in both canyons. This update to the glacial chronology of the western Wasatch Mountains can be reconciled with previous stratigraphic observations of glacial and paleolake deposits in this area, and indicates that the start of deglaciation occurred during or at the end of the Lake Bonneville hydrologic maximum. The glacial chronology reported here is consistent with the growing body of data suggesting that mountain glaciers in the western U.S. began retreating as many as 4 ka after the start of northern hemisphere deglaciation (at ca. 19 ka).  相似文献   

Connectivity clues from short-term variability in settlement and geochemical tags of mytilid mussels     

F. Joel Fodrie  Bonnie J. Becker  Lisa A. Levin  Kristen Gruenthal  Pat A. McMillan 《Journal of Sea Research》2011,65(1):141-150

The use of geochemical tags in calcified structures of fish and invertebrates is an exciting tool for investigating larval population connectivity. Tag evaluation over relatively short intervals (weeks) may detect environmental and ecological variability at a temporal scale highly relevant to larval transport and settlement. We collected newly settled mussels (Mytilus californianus and M. galloprovincialis) weekly during winter/spring of 2002 along the coast of San Diego, CA, USA, at sites on the exposed coast (SIO) and in a protected coastal bay (HI), to investigate temporal patterns of geochemical tags in mussel shells. Analyses of post-settlement shell via LA-ICP-MS revealed statistically significant temporal variability for all elements we examined (Mg, Mn, Cu, Sr, Cd, Ba, Pb and U). Despite this, our ability to distinguish multielemental signatures between sites was largely conserved. Throughout our 13-week study, SIO and HI mussels could be chemically distinguished from one another in 78–87% of all cases. Settlement varied between 2 and 27 settlers gram-byssus^?1 week^?1 at SIO and HI, and both sites were characterized by 2–3 weeks with “high” settlement. Geochemical tags recorded in early larval shell of newly settled mussels differed between “high” and “low” settlement weeks at both sites (MANOVA), driven by Mg and Sr at SIO (p = 0.013) and Sr, Cd, Ba and Pb at HI (p < 0.001). These data imply that shifts in larval sources or transport corridors were responsible for observed settlement variation, rather than increased larval production. In particular, increased settlement at HI was observed concurrent with the appearance of geochemical tags (e.g., elevated Cd), suggesting that those larvae were retained in upwelled water near the mouth of the bay. Such shifts may reflect short-term changes in connectivity among sites due to altered transport corridors, and influence the demography of local populations.  相似文献   

Contemporary state of stress and neotectonic deformation in the Carpathian-Pannonian region     

Arnfried Becker 《地学学报》1993,5(4):375-388

The Carpathian-Pannonian region has been characterized by a two-stage tectonic evolution since the beginning of the Neogene. During early and mid-Miocene the lateral eastward escape of the Pannonian Fragment caused thrusting and folding in the Outer Carpathian Mountains, south- and westward directed subduction of the Eurasian lithosphere, calc-alkaline volcanism along the Inner Carpathian bend, and localized fault-controlled subsidence of basins in the Pannonian region. This style of tectonic deformation ceased by the end of the mid-Miocene. The neotectonic stage began in the late Miocene. It is characterized by differential regional subsidence with maximum rates in the west and east and minimum rates in the centre of the Pannonian Basin. Further characteristics of the central Pannonian Basin are the anomalous high heat flow values, the thin crust and lithosphere. The neotectonic stress field has been determined by in situ stress measurements, the analyses of borehole breakouts and fault-plane solutions of earthquakes. In situ stress measurements by the doorstopper and triaxial strain cell methods indicate high compressional stresses in the western Pannonian Basin with its maximum in WNW-ESE to NW-SE direction. In contrast to its western part, the central Pannonian Basin shows tensional stresses near the Earth's surface with maximum tension in the same WNW-ESE direction. Borehole breakout data indicate a general WNW-ESE orientation of maximum horizontal stress in the western part of the Pannonian Basin and in the eastern part as well, whereas in the central Pannonian Basin this direction is the preferred azimuth of minimum horizontal stress. It is suggested that the neotectonic deformations and stresses in the Carpathian-Pannonian region have a sublithospheric origin. Asthenospheric convection with an upwelling mantle flow below the centre of the Pannonian Basin and downwelling flows along the cold lithospheric roots below the eastern Carpathians and the Alps seems to be most plausible. Accordingly, the relative uplift of the central Pannonian Basin, the high heat flow and also the tensional stresses are explained as the surface expression of an upstreaming branch of a localized convection cell below the Pannonian Basin.  相似文献   

Exact solution for the Green's function describing time-dependent thermal Comptonization     

Peter A. Becker 《Monthly notices of the Royal Astronomical Society》2003,343(1):215-240

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Results from the Geoacoustic Inversion Techniques Workshop using modal inverse methods     

Becker  K.M. Rajan  S.D. Frisk  G.V. 《Oceanic Engineering, IEEE Journal of》2003,28(3):331-341

This paper presents the results of a perturbative inverse approach applied to the range-dependent acoustic data provided as part of the Geoacoustic Inversion Techniques Workshop. The method is based on the Hankel transform relationship between complex-pressure field data measured on a horizontal array and the depth-dependent Green's function for a horizontally stratified medium. The input data to the inversion algorithm are discrete values of horizontal wavenumbers estimated for locally range-independent subapertures of the acoustic data. Inversion results are presented with emphasis placed on inverting for compressional wave speed as a function of both range and depth in the bottom.  相似文献   

Effect of various surface-height-distribution properties on acoustic backscattering statistics     

Becker  K.M. 《Oceanic Engineering, IEEE Journal of》2004,29(2):246-259

A problem of interest to underwater acousticians is understanding the relationship between ocean-bottom characteristics and acoustic backscattering statistics. This experimental work focused on examining surface roughness characteristics that cause backscattering strength statistics to deviate from the Rayleigh distribution. Several different scattering surfaces with known height distributions were designed for this study. The surfaces were modeled using a technique that allowed for different height-distribution functions and correlation lengths to be prescribed. Isotropic and anisotropic surfaces were fabricated having both Gaussian and non-Gaussian surface-height distributions. Many independent backscattering measurements were made for different aspects of each surface using a computer-controlled transducer-positioning system. Acoustic backscattering statistics were non-Rayleigh for the anisotropic surfaces when combining measurements from different aspects. Mean scattering strength was found to be dependent on both the surface-height distribution and correlation length. In addition, backscattering strength showed a dependence on the surface-height power distribution.  相似文献   

Shocked plagioclase signatures in Thermal Emission Spectrometer data of Mars     

Jeffrey R. Johnson  Matthew I. Staid  Kris Becker 《Icarus》2006,180(1):60-74

The extensive impact cratering record on Mars combined with evidence from SNC meteorites suggests that a significant fraction of the surface is composed of materials subjected to variable shock pressures. Pressure-induced structural changes in minerals during high-pressure shock events alter their thermal infrared spectral emission features, particularly for feldspars, in a predictable fashion. To understand the degree to which the distribution and magnitude of shock effects influence martian surface mineralogy, we used standard spectral mineral libraries supplemented by laboratory spectra of experimentally shocked bytownite feldspar [Johnson, J.R., Hörz, F., Christensen, P., Lucey, P.G., 2002b. J. Geophys. Res. 107 (E10), doi:10.1029/2001JE001517] to deconvolve Thermal Emission Spectrometer (TES) data from six relatively large (>50 km) impact craters on Mars. We used both TES orbital data and TES mosaics (emission phase function sequences) to study local and regional areas near the craters, and compared the differences between models using single TES detector data and 3×2 detector-averaged data. Inclusion of shocked feldspar spectra in the deconvolution models consistently improved the rms errors compared to models in which the spectra were not used, and resulted in modeled shocked feldspar abundances of >15% in some regions. However, the magnitudes of model rms error improvements were within the noise equivalent rms errors for the TES instrument [Hamilton V., personal communication]. This suggests that while shocked feldspars may be a component of the regions studied, their presence cannot be conclusively demonstrated in the TES data analyzed here. If the distributions of shocked feldspars suggested by the models are real, the lack of spatial correlation to crater materials may reflect extensive aeolian mixing of martian regolith materials composed of variably shocked impact ejecta from both local and distant sources.  相似文献   

Inundation of a low-lying urban atoll island: Majuro,Marshall Islands     

Ford  Murray  Merrifield  Mark A.  Becker  Janet M. 《Natural Hazards》2018,91(3):1273-1297

Natural Hazards - Majuro is a low-lying island perched on a coral atoll in the central Pacific Ocean and is home to nearly 28,000 people. Considered highly vulnerable to the impacts of marine...  相似文献   

When a hazard occurs where it is not expected: risk judgments about different regions after the Christchurch earthquakes   总被引：1，自引：1，他引：0  

John McClure  David Johnston  Liv Henrich  Taciano L. Milfont  Julia Becker 《Natural Hazards》2015,75(1):635-652

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