Coupled silicon–oxygen isotope fractionation traces Archaean silicification     

K. Abraham  A. Hofmann  S.F. Foley  D. Cardinal  C. Harris  M.G. Barth  L. André 《Earth and Planetary Science Letters》2011,301(1-2):222-230

Silica alteration zones and cherts are a conspicuous feature of Archaean greenstone belts worldwide and provide evidence of extensive mobilisation of silica in the marine environment of the early Earth. In order to understand the process(es) of silicification we measured the silicon and oxygen isotope composition of sections of variably silicified basalts and overlying bedded cherts from the Theespruit, Hooggenoeg and Kromberg Formations of the Barberton Greenstone Belt, South Africa.The δ³⁰Si and δ¹⁸O values of bulk rock increase with increasing amount of silicification from unsilicified basalts (?0.64‰ < δ³⁰Si < ?0.01‰ and + 8.6‰ < δ¹⁸O < + 11.9‰) to silicified basalts (δ³⁰Si and δ¹⁸O values as high as + 0.81‰ and + 15.6‰, respectively). Cherts generally have positive isotope ratios (+ 0.21‰ < δ³⁰Si < + 1.05‰ and + 10.9 < δ¹⁸O < + 17.1), except two cherts, which have negative δ³⁰Si values, but high δ¹⁸O (up to + 19.5‰).The pronounced positive correlations between δ³⁰Si, δ¹⁸O and SiO₂ imply that the isotope variation is driven by the silicification process which coevally introduced both ¹⁸O and ³⁰Si into the basalts. The oxygen isotope variation in the basalts from about 8.6‰ to 15.6‰ is likely to represent temperature-dependent isotope fractionation during alteration. Our proposed model for the observed silicon isotope variation relies on a temperature-controlled basalt dissolution vs. silica deposition process.  相似文献   

Land–sea carbon and nutrient fluxes and coastal ocean CO2 exchange and acidification: Past,present, and future     

Fred T. Mackenzie  Andreas J. Andersson  Rolf S. Arvidson  Michael W. Guidry  Abraham Lerman 《Applied Geochemistry》2011

Epochs of changing atmospheric CO₂ and seawater CO₂–carbonic acid system chemistry and acidification have occurred during the Phanerozoic at various time scales. On the longer geologic time scale, as sea level rose and fell and continental free board decreased and increased, respectively, the riverine fluxes of Ca, Mg, DIC, and total alkalinity to the coastal ocean varied and helped regulate the C chemistry of seawater, but nevertheless there were major epochs of ocean acidification (OA). On the shorter glacial–interglacial time scale from the Last Glacial Maximum (LGM) to late preindustrial time, riverine fluxes of DIC, total alkalinity, and N and P nutrients increased and along with rising sea level, atmospheric PCO₂ and temperature led, among other changes, to a slightly deceasing pH of coastal and open ocean waters, and to increasing net ecosystem calcification and decreasing net heterotrophy in coastal ocean waters. From late preindustrial time to the present and projected into the 21st century, human activities, such as fossil fuel and land-use emissions of CO₂ to the atmosphere, increasing application of N and P nutrient subsidies and combustion N to the landscape, and sewage discharges of C, N, P have led, and will continue to lead, to significant modifications of coastal ocean waters. The changes include a rapid decline in pH and carbonate saturation state (modern problem of ocean acidification), a shift toward dissolution of carbonate substrates exceeding production, potentially leading to the “demise” of the coral reefs, reversal of the direction of the sea-to-air flux of CO₂ and enhanced biological production and burial of organic C, a small sink of anthropogenic CO₂, accompanied by a continuous trend toward increasing autotrophy in coastal waters.  相似文献   

Artificial Neural Networks: A Solution to the Ambiguity in Prediction of Engineering Properties of Fine-Grained Soils   总被引：1，自引：1，他引：0  

Viji K. Varghese  Shemy S. Babu  R. Bijukumar  Sobha Cyrus  Benny Mathews Abraham 《Geotechnical and Geological Engineering》2013,31(4):1187-1205

Determination of soaked california bearing ratio (CBR) and compaction characteristics of soils in the laboratory require considerable time and effort. To make a preliminary assessment of the suitability of soils required for a project, prediction models for these engineering properties on the basis of laboratory tests—which are quick to perform, less time consuming and cheap—such as the tests for index properties of soils, are preferable. Nevertheless researchers hold divergent views regarding the most influential parameters to be taken into account for prediction of soaked CBR and compaction characteristics of fine-grained soils. This could be due to the complex behaviour of soils—which, by their very nature, exhibit extreme variability. However this disagreement is a matter of concern as it affects the dependability of prediction models. This study therefore analyses the ability of artificial neural networks and multiple regression to handle different influential parameters simultaneously so as to make accurate predictions on soaked CBR and compaction characteristics of fine-grained soils. The results of simple regression analyses included in this study indicate that optimum moisture content (OMC) and maximum dry density (MDD) of fine-grained soils bear better correlation with soaked CBR of fine-grained soils than plastic limit and liquid limit. Simple regression analyses also indicate that plastic limit has stronger correlation with compaction characteristics of fine-grained soils than liquid limit. On the basis of these correlations obtained using simple regression analyses, neural network prediction models and multiple regression prediction models—with varying number of input parameters are developed. The results reveal that neural network models have more ability to utilize relatively less influential parameters than multiple regression models. The study establishes that in the case of neural network models, the relatively less powerful parameters—liquid limit and plastic limit can also be used effectively along with MDD and OMC for better prediction of soaked CBR of fine-grained soils. Also with the inclusion of less significant parameter—liquid limit along with plastic limit the predictions on compaction characteristics of fine-grained soils using neural network analysis improves considerably. Thus in the case of neural network analysis, the use of relatively less influential input parameters along with stronger parameters is definitely beneficial, unlike conventional statistical methods—for which, the consequence of this approach is unpredictable—giving sometimes not so favourable results. Very weak input parameters alone need to be avoided for neural network analysis. Consequently, when there is ambiguity regarding the most influential input parameters, neural network analysis is quite useful as all such influential parameters can be taken to consideration simultaneously, which will only improve the performance of neural network models. As soils by their very nature, exhibit extreme complexity, it is necessary to include maximum number of influential parameters—as can be determined easily using simple laboratory tests—in the prediction models for soil properties, so as to improve the reliability of these models—for which, use of neural networks is more desirable.  相似文献   

Global Nitrogen Cycle: Pre-Anthropocene Mass and Isotope Fluxes and the Effects of Human Perturbations     

Young Ji Joo  Darcy Dan Li  Abraham Lerman 《Aquatic Geochemistry》2013,19(5-6):477-500

We present a nitrogen cycle model for pre-industrial times based on an extensive literature database. The model consists of 18 reservoirs in the domains of the atmosphere, land, and ocean. The biotic reservoirs on land and in the ocean (N-fixing plants, non-N-fixing plants, and marine biota) interact with atmospheric N₂ and dissolved inorganic nitrogen (DIN, consisting of N₂, NO₃ ^?, and NH₄ ⁺) in the ocean and soil waters. Marine DIN is taken up by marine biota and transformed from ocean particulate organic matter to dissolved organic nitrogen and the ocean sediment. The atmosphere, the largest nitrogen reservoir, supplies N₂ to the system by N fixation, deposition, and dissolution, and these input fluxes are balanced by denitrification and volatilization back to the atmosphere. The land and ocean domains are linked by river transport, which carries both dissolved and particulate nitrogen to the oceanic coastal zone. The isotope–mass balances of the N reservoirs are calculated from the isotopic composition of the reservoirs and the fractionation factors accompanying the fluxes between the reservoirs based on reported values from different natural conditions. The model sensitivity was tested for different biouptake rates and was run with various human perturbations, including fertilization, nitrous oxide emissions, population-related sewage disposal, land-use changes, and temperature-dependent rate kinetics. The new N mass–isotope cycle model provides the basis for assessment of the impact of artificial fertilization between 1700 and 2050. The perturbation experiments in this study suggest that land-use change is the key factor altering the N mass cycle since industrialization.  相似文献   

The origin and evolution of Saturn’s 2011–2012 stratospheric vortex     

Leigh N. Fletcher  B.E. Hesman  R.K. Achterberg  P.G.J. Irwin  G. Bjoraker  N. Gorius  J. Hurley  J. Sinclair  G.S. Orton  J. Legarreta  E. García-Melendo  A. Sánchez-Lavega  P.L. Read  A.A. Simon-Miller  F.M. Flasar 《Icarus》2012,221(2):560-586

The planet-encircling springtime storm in Saturn’s troposphere (December 2010–July 2011, Fletcher, L.N. et al. [2011]. Science 332, 1413–1414; Sánchez-Lavega, A. et al. [2011]. Nature 475, 71–74; Fischer, G. et al. [2011]. Nature 475, 75–77) produced dramatic perturbations to stratospheric temperatures, winds and composition at mbar pressures that persisted long after the tropospheric disturbance had abated. Thermal infrared (IR) spectroscopy from the Cassini Composite Infrared Spectrometer (CIRS), supported by ground-based IR imaging from the VISIR instrument on the Very Large Telescope and the MIRSI instrument on NASA’s IRTF, is used to track the evolution of a large, hot stratospheric anticyclone between January 2011 and March 2012. The evolutionary sequence can be divided into three phases: (I) the formation and intensification of two distinct warm airmasses near 0.5 mbar between 25 and 35°N (B1 and B2) between January–April 2011, moving westward with different zonal velocities, B1 residing directly above the convective tropospheric storm head; (II) the merging of the warm airmasses to form the large single ‘stratospheric beacon’ near 40°N (B0) between April and June 2011, disassociated from the storm head and at a higher pressure (2 mbar) than the original beacons, a downward shift of 1.4 scale heights (approximately 85 km) post-merger; and (III) the mature phase characterised by slow cooling (0.11 ± 0.01 K/day) and longitudinal shrinkage of the anticyclone since July 2011. Peak temperatures of 221.6 ± 1.4 K at 2 mbar were measured on May 5th 2011 immediately after the merger, some 80 K warmer than the quiescent surroundings. From July 2011 to the time of writing, B0 remained as a long-lived stable stratospheric phenomenon at 2 mbar, moving west with a near-constant velocity of 2.70 ± 0.04 deg/day (?24.5 ± 0.4 m/s at 40°N relative to System III longitudes). No perturbations to visible clouds and hazes were detected during this period.With no direct tracers of motion in the stratosphere, we use thermal windshear calculations to estimate clockwise peripheral velocities of 200–400 m/s at 2 mbar around B0. The peripheral velocities of the two original airmasses were smaller (70–140 m/s). In August 2011, the size of the vortex as defined by the peripheral collar was 65° longitude (50,000 km in diameter) and 25° latitude. Stratospheric acetylene (C₂H₂) was uniformly enhanced by a factor of three within the vortex, whereas ethane (C₂H₆) remained unaffected. The passage of B0 generated a new band of warm stratospheric emission at 0.5 mbar at its northern edge, and there are hints of warm stratospheric structures associated with the beacons at higher altitudes (p < 0.1 mbar) than can be reliably observed by CIRS nadir spectroscopy. Analysis of the zonal windshear suggests that Rossby wave perturbations from the convective storm could have propagated vertically into the stratosphere at this point in Saturn’s seasonal cycle, one possible source of energy for the formation of these stratospheric anticyclones.  相似文献   

Vegetation structure controls on snow and soil moisture in restored ponderosa pine forests     

Frances C. O'Donnell  Jonathon Donager  Temuulen Sankey  Sharon Masek Lopez  Abraham E. Springer 《水文研究》2021,35(11):e14432

Thinning of semi-arid forests to reduce wildfire risk is believed to improve forest health by increasing soil moisture. Increased snowpack, reduced transpiration and reduced rainfall interception are frequently cited mechanisms by which reduced canopy density may increase soil moisture. However, the relative importance of these factors has not been rigorously evaluated in field studies. We measured snow depth, snow water equivalent (SWE) and the spatial and temporal variation in soil moisture at four experimental paired treatment-control thinning sites in high elevation ponderosa pine forest northern Arizona, USA. We compared snow and soil moisture measurements with forest structure metrics derived from aerial imagery and 3-dimensional lidar data to determine the relationship between vegetation structure, snow and soil moisture throughout the annual hydrologic cycle. Soil moisture was consistently and significantly higher in thinned forest plots, even though the treatments were performed 8–11 years before this study. However, we did not find evidence that SWE was higher in thinned forests across a range of snow conditions. Regression tree analysis of soil moisture and vegetation structure data provided some evidence that localized differences in transpiration and interception of precipitation influence the spatial pattern of soil moisture at points in the annual hydrologic cycle when the system is becoming increasingly water limited. However, vegetation structure explained a relatively low amount of the spatial variance (R² < 0.23) in soil moisture. Continuous measurements of soil moisture in depth profiles showed stronger attenuation of soil moisture peaks in thinned sites, suggesting differences in infiltration dynamics may explain the difference in soil moisture between treatments as opposed to overlying vegetation alone. Our results show limited support for commonly cited relationships between vegetation structure, snow and soil moisture and indicate that future research is needed to understand how reduction in tree density alters soil hydraulic properties.  相似文献   

Hypervelocity stars from the Andromeda galaxy     

Blake D. Sherwin  Abraham Loeb  Ryan M. O'Leary 《Monthly notices of the Royal Astronomical Society》2008,386(3):1179-1191

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Dynamical constraints on the Local Group from the CMB and 2MRS dipoles     

Abraham Loeb  Ramesh Narayan 《Monthly notices of the Royal Astronomical Society》2008,386(4):2221-2226

We place constraints on the dynamics of the Local Group (LG) by comparing the dipole of the cosmic microwave background (CMB) with the peculiar velocity induced by the Two Micron All-Sky Redshift Survey galaxy sample. The analysis is limited by the lack of surveyed galaxies behind the zone of avoidance (ZoA). We therefore allow for a component of the LG velocity due to unknown mass concentrations behind the ZoA, as well as for an unknown transverse velocity of the Milky Way relative to the Andromeda galaxy. We infer extra motion along the direction of the Galactic Centre (where Galactic confusion and dust obscuration peaks) at the 95 per cent significance level. With a future survey of the ZoA it might be possible to constrain the transverse velocity of the Milky Way relative to Andromeda.  相似文献   

Numerical study on basin-edge effects in the seismic response of the Gubbio valley,Central Italy     

Jetson R. Abraham  Chiara Smerzini  Roberto Paolucci  Carlo G. Lai 《Bulletin of Earthquake Engineering》2016,14(6):1437-1459

The Gubbio basin in Central Italy is a intermountain basin of extensional tectonic origin, typical of Central and Southern Apennines, characterized by moderate seismicity. The strongest recorded event within the area is a magnitude 5.7 earthquake which occurred on 29 April 1984 along the Gubbio fault, bordering the eastern side of the basin. The main objective of this study is to analyze the features of earthquake ground motion as related to basin-edge effects, by performing physics-based numerical simulations of the 1984 earthquake through a high-performance spectral element code. The simulated ground motions are found in reasonable agreement with the recorded motions when using the kinematic source model developed by Ameri et al. (Bull Seismol Soc Am 99:647–663, 2009), with a rise-time equal to 1 s and a nucleation point located in the middle of the fault. Pronounced differences were noted between records from the basin and adjacent sites at outcropping bedrock, owing to both the strong impedance contrast between soft alluvial sites and bedrock formations (lithostratigraphic amplification), as well as lateral discontinuities related to the 2D/3D geometry of the basin (generation of surface waves). Since the fault was located beneath the basin, 1D amplification effects were found to be more relevant than those associated with the generation of surface waves from the basin edge. Finally, an envelope delay spectrum was computed for the simulated ground motions, showing that surface waves are excited in the frequency band of 0.2–0.8 Hz with a significant increase of ground motion duration within the basin.  相似文献   

The 21-cm power spectrum after reionization     

J. Stuart B. Wyithe  Abraham Loeb 《Monthly notices of the Royal Astronomical Society》2009,397(4):1926-1934

We discuss the 21-cm power spectrum (PS) following the completion of reionization. In contrast to the reionization era, this PS is proportional to the PS of mass density fluctuations, with only a small modulation due to fluctuations in the ionization field on scales larger than the mean-free-path of ionizing photons. We derive the form of this modulation, and demonstrate that its effect on the 21-cm PS will be smaller than 1 per cent for physically plausible models of damped Lyα systems. In contrast to the 21-cm PS observed prior to reionization, in which H  ii regions dominate the ionization structure, the simplicity of the 21-cm PS after reionization will enhance its utility as a cosmological probe by removing the need to separate the PS into physical and astrophysical components. As a demonstration, we consider the Alcock–Paczynski test and show that the next generation of low-frequency arrays could measure the angular distortion of the PS at the per cent level for   z ∼ 3–5  .  相似文献